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Dale W. Blevins

Publications and source records attributed to Dale W. Blevins.

9 recordsLinked to original sources

Pre- and post-impoundment nitrogen in the lower Missouri River

Large water-sample sets collected from 1899 through 1902, 1907, and in the early 1950s allow comparisons of pre-impoundment and post-impoundment (1969 through 2008) nitrogen concentrations in the lower Missouri River. Although urban wastes were not large enough to detectably increase annual loads of total nitrogen at the beginning of the 20th century, carcass waste, stock-yard manure, and untreated human wastes measurably increased ammonia and organic-nitrogen concentrations during low flows. Average total-nitrogen concentrations in both periods were about 2.5 mg/l, but much of the particulate-organic nitrogen, which was the dominant form of nitrogen around 1900, has been replaced by nitrate. This change in speciation was caused by the nearly 80% decrease in suspended-sediment concentrations that occurred after impoundment, modern agriculture, drainage of riparian wetlands, and sewage treatment. Nevertheless, bioavailable nitrogen has not been low enough to limit primary production in the Missouri River since the beginning of the 20th century. Nitrate concentrations have increased more rapidly from 2000 through 2008 (5 to 12% per year), thus increasing bioavailable nitrogen delivered to the Mississippi River and affecting Gulf Coast hypoxia. The increase in nitrate concentrations with distance downstream is much greater during the post-impoundment period. If strategies to decrease total-nitrogen loads focus on particulate N, substantial decreases will be difficult because particulate nitrogen is now only 23% of total nitrogen in the Missouri River. A strategy aimed at decreasing particulates also could further exacerbate land loss along the Gulf of Mexico, which has been sediment starved since Missouri River impoundment. In contrast, strategies or benchmarks aimed at decreasing nitrate loads could substantially decrease nitrogen loadings because nitrates now constitute over half of the Missouri's nitrogen input to the Mississippi. Ongoing restoration and creation of wetlands along the Missouri River could be part of such a nitrate-reduction strategy. Published 2013. This article is a U.S. Government work and is in the public domain in the USA.

Illinois;Iowa;Kansas;Missouri;Nebraska

Water-quality requirements, tolerances, and preferences of pallid sturgeon Scaphirhynchus albus in the lower Missouri River

Although numerous studies have been completed on pallid sturgeon populations and behavior, few have addressed the potential for water-quality characteristics to limit recruitment and population success of pallid sturgeon. Literature on sturgeon and water-quality data indicates recruitment of pallid sturgeon may be limited by several water-quality characteristics of the lower Missouri River including: High summer water temperatures in excess of 30 degrees Celsius, which likely are stressful to pallid sturgeon, Turbidities that are more than an order of magnitude less than the unaltered Missouri River and may no longer provide adequate cover for egg, larval, and young pallid sturgeon or for older pallid sturgeon attempting to capture prey, Dissolved oxygen that decreases to concentrations less than 2 milligrams per liter during some river rises in the late spring and summer, Food webs altered by increased light availability and hypereutrophic conditions caused by or enhanced by impoundment, bank stabilization, nonnative species, and decreased allocthanous material from the basin, Bioaccumulative contaminants, including polychlorinated biphenyls, chlordane, dichlorodiphenyltrichloroethane (DDT) and its metabolites, mercury, and synergistic contaminant cocktails that are particularly damaging to long-lived fish, and Other contaminants such as agricultural chemicals (particularly atrazine) and organic wastewater compounds that can disrupt endocrine systems of fish and limit reproduction at extremely low concentrations. Additional research could be used to characterize and quantify the requirements, tolerance, and preferences of pallid sturgeon to these water-quality characteristics, especially during the egg and larval life stages. Enhancements to existing water-sampling programs are needed to quantify the exposure of pallid sturgeon to many of these water-quality stressors.

Missouri River

Trends in suspended-sediment loads and concentrations in the Mississippi River Basin, 1950–2009

Trends in loads and concentrations of suspended sediment and suspended sand generally were downward for stations within the Mississippi River Basin during the 60-, 34-, and 12-year periods analyzed. Sediment transport in the lower Mississippi River has historically been, and continues to be, most closely correlative to sediment contributions from the Missouri River, which generally carried the largest annual suspended-sediment load of the major Mississippi River subbasins. The closure of Fort Randall Dam in the upper Missouri River in 1952 was the single largest event in the recorded historical decline of suspended-sediment loads in the Mississippi River Basin. Impoundments on tributaries and sediment reductions as a result of implementation of agricultural conservation practices throughout the basin likely account for much of the remaining Mississippi River sediment transport decline. Scour of the main-stem channel downstream from the upper Missouri River impoundments is likely the largest source of suspended sand in the lower Missouri River. The Ohio River was second to the Missouri River in terms of sediment contributions, followed by the upper Mississippi and Arkansas Rivers. Declines in sediment loads and concentrations continued through the most recent analysis period (1998–2009) at available Mississippi River Basin stations. Analyses of flow-adjusted concentrations of suspended sediment indicate the recent downward temporal changes generally can be explained by corresponding decreases in streamflows.

Mississippi River Basin

The Response of Suspended Sediment, Turbidity, and Velocity to Historical Alterations of the Missouri River

The heavy sediment load and large amounts of floating debris generated by the constantly caving banks of the Missouri River was documented in the first written description of the river by Father Jacques Marquette in 1673 as he approached the mouth of the Missouri River from the upper Mississippi River: '[We]' heard the noise of a rapid, into which we were about to run. I have seen nothing more dreadful. An accumulation of large and entire trees, branches, and floating islands, was issuing from the mouth of the river Pekitanoui (Missouri River), with such impetuosity that we could not without great danger risk passing through it. So great was its agitation that the water was so very muddy, and could not become clear.' However, large changes in suspended sediment and turbidity in the lower Missouri River below Gavins Point Dam have occurred in response to extensive structural changes that have been imposed on the Missouri River and its watershed during the last two centuries. Efforts to shape the channel, remove snags and sawyers, dredge shallows, and stabilize banks for navigation began as early as 1838 ( http://www.lewis-clark.org/ri_mo-snagboats.htm , Chittenden, 1903). However, bank stabilization efforts were sporadic and scattered in comparison to large scale changes that occurred after 1929. In the early 1930s the numerous small channels were combined into a single-fixed channel with 4,745 stone and wood-pile dikes, 3,371 dike extensions, streambank protection works on concave banks, man-made cutoffs, the closing of chutes with dikes, the removal of snags, and dredging (Keown and others, 1981). The resulting navigation channel was 6-ft (feet) deep by 200-ft wide and was expanded to 9 by 300 ft in the 1950s and early 1960s. Construction of six dams was started in 1933 and their reservoirs were filled by 1967. Three of these reservoirs are among the five largest in the United States. Nearly one-third of the Missouri River is now submerged below these massive reservoirs. Since 1967, hydrologic changes have been relatively minor. In the early 1970s, the U.S. Geological Survey (USGS) began the long-term, systematic collection of suspended-sediment and water-quality data that continues to the present (2006). Because changes in the channel configuration and hydrologic character of the river have been small compared to the changes before 1973, all samples collected after that time are referred to in this report as modern samples. These modern samples compose a large data set that are compared to samples collected before the pervasive hydrologic and channel-stabilizing changes that began in the early 1930s and to the qualitative and semiquantitative observations of the explorers in the early nineteenth century.

Circular

Hydrology and cycling of nitrogen and phosphorus in Little Bean Marsh: A remnant riparian wetland along the Missouri River in Platte County, Missouri, 1996–97

The lack of concurrent water-quality and hydrologic data on riparian wetlands in the Midwestern United States has resulted in a lack of knowledge about the water-quality functions that these wetlands provide. Therefore, Little Bean Marsh, a remnant riparian wetland along the Missouri River, was investigated in 1996 and 1997 primarily to determine the magnitude and character of selected water-quality benefits that can be produced in such a wetland and to identify critical processes that can be managed in remnant or restored riparian wetlands for amelioration of water quality. Little Bean Marsh averages 69 hectares in size, has a maximum depth of about 1 meter, and the majority of the marsh is covered by macrophytes. In 1997, 41 percent of the water received by Little Bean Marsh was from direct precipitation, 14 percent was from ground-water seepage, 30 percent from watershed runoff, and 15 percent was backflow from Bean Lake. Although, Little Bean Marsh was both a ground-water recharge and discharge area, discharge to the marsh was three times the recharge to ground water. Ground-water levels closely tracked marsh water levels indicating a strong hydraulic connection between ground water and the marsh. Reduced surface runoff and ground-water availability are stabilizing influences on marsh hydrology and probably contribute to the persistence of emergent vegetation. The rapid hydraulic connection between Little Bean Marsh and ground water indicates that the hydrologic regime of most wetlands along the lower Missouri River is largely a function of the altitude of the marsh bottom relative to the altitude of the water table. More water was lost from the marsh through evapotranspiration (59 percent) than all other pathways combined. This is partially because the transpiration process of abundant macrophytes can greatly contribute to the evapotranspiration above that lost from open water surfaces. Surface outflow accounted for 36 percent and ground-water seepage accounted for only 5 percent of the losses. Large residence times allows the marsh to greatly affect water quality before water escapes as ground-water recharge or surface outflow. The shallowness of Little Bean Marsh and ion exclusion during ice formation caused the highest specific conductances of 1,100 to 1,300 microsiemens per centimeter at 25 degrees Celsius to occur during the winter. This concentration of dissolved solutes under ice can make wetlands more vulnerable to toxic contaminants than deeper surface-water bodies. Dissolved oxygen was less than 5 mg/L (milligrams per liter) for 3 to 4 months and near 0 mg/L for about 1 month in summer. Despite depths of less than 1 meter, temperature stratification persisted more than 3 months during the summers of 1996 and 1997, preventing mixing and contributing to periods of anoxia. Shallow depths and extended periods of anoxia in the marsh limit the ability of some organisms to escape high-temperature stress. Turbidity in Little Bean Marsh usually was low for several reasons: sediment loadings from the largely flood-plain drainage were low, emergent vegetation shade out algae and shield the water from wind, and high concentrations of bivalent cations increase flocculation rates of inorganic suspended material. The high concentrations of bivalent cations was largely because of a substantial amount of ground-water seepage into the marsh. Dissolved organic nitrogen was the dominant nitrogen species in Little Bean Marsh. Denitrification and biotic uptake kept more than 62 percent of nitrate (NO3) and 43 percent of ammonium (NH4) concentrations in marsh samples less than a detection limit of 0.005 mg/L. This contrasts with the Missouri River where inorganic NO3 dominates. Consequently, artificial flood-plain drainage that bypasses riparian wetlands likely deliver substantially more biotically available inorganic nitrogen to receiving waters than surface water that has been routed through a remnant wetland. Average total nitrogen concentrations in Little Bean Marsh were substantially less than those at other Missouri River wetlands, roughly one-half the mean concentrations in the Missouri River, but roughly twice the average nitrogen values in reservoirs of the glaciated plains of Missouri. The largest concentrations of nearly all species of nitrogen and phosphorus and the most intense period of hypereutrophy coincided with a phytoplankton bloom and senescence of River Bulrush (Scirpus fluviatilis) and common cattail (Typha latifolia) in September 1997. The rapid leaching of nitrogen that occurs soon after macrophyte senescence combined with a recent destratification of the marsh probably provided nitrogen to the nitrogen-limited open-water areas and triggered a phytoplankton bloom. Despite the rarity of runoff events, surface runoff from the watershed, combined with atmospheric deposition, contributed more than seven times the 530 kg (kilograms) of nitrogen that escaped Little Bean Marsh in surface outflow during 1997. Atmospheric deposition alone was more than 530 kg. Seepage to ground water contained less than 1.5 percent of the nitrogen leaving the marsh in surface outflow. The slow decay rate of Scirpus fluviatilis and reducing conditions in bottom sediments make burial of organic nitrogen a substantial sink of nitrogen. Denitrification experiments indicate that denitrification rates were limited by NO3 in the water column. Consequently, decomposition and nitrification of NH4 and organic nitrogen are the rate limiting steps of nitrogen removal in Little Bean Marsh. The NO3-limited rates of denitrification also indicate that Little Bean Marsh has a large unused capacity for nitrogen removal. These data indicate that the vast extent of riparian marshes along the Missouri and Mississippi Rivers may have had a substantial role in limiting NO3 loads to the Gulf of Mexico before agricultural development of flood plains. Drainage and removal of riparian marshes may be a major cause of the increased NO3 loads to the Gulf of Mexico. Periods of anoxia had much larger effects on phosphorus release than the other variables. The largest concentrations of phosphorus occurred in late summer and corresponded with senescing macrophytes, periods of anoxia, and a large algal bloom in Little Bean Marsh. Low water levels prevented the escape of phosphorus in surface outflow during these periods of highest phosphorus concentrations. Dry weather in late summer is typical and probably makes the correspondence of low water levels, anoxia, and consequent low phosphorus release a common occurrence in marshes along the Missouri River. Little Bean Marsh retained more than 95 percent of the phosphorus it received. The amount of phosphorus in surface inflows to the marsh were more than one order of magnitude greater than that escaping in surface outflows. The long hydraulic residence time of the marsh and large contributions of iron from ground water (that provide many sorption sites for phosphorus) make the marsh an effective sediment and phosphorus trap.

Missouri

Effects of wastewater and combined sewer overflows on water quality in the Blue River basin, Kansas City, Missouri and Kansas, July 1998-October 2000

Samples were collected from 16 base-flow events and a minimum of 10 stormflow events between July 1998 and October 2000 to characterize the effects of wastewater and combined sewer overflows on water quality in the Blue River Basin, Kansas City, Missouri and Kansas. Waterquality effects were determined by analysis of nutrients, chloride, chemical and biochemical oxygen demand, and suspended sediment samples from three streams (Blue River, Brush Creek, and Indian Creek) in the basin as well as the determination of a suite of compounds known to be indicative of wastewater including antioxidants, caffeine, detergent metabolites, antimicrobials, and selected over-the-counter and prescription pharmaceuticals. Constituent loads were determined for both hydrologic regimes and a measure of the relative water-quality impact of selected stream reaches on the Blue River and Brush Creek was developed. Genetic fingerprint patterns of Escherichia coli bacteria from selected stream samples were compared to a data base of knownsource patterns to determine possible sources of bacteria. Water quality in the basin was affected by wastewater during both base flows and stormflows; however, there were two distinct sources that contributed to these effects. In the Blue River and Indian Creek, the nearly continuous discharge of treated wastewater effluent was the primary source of nutrients, wastewater indicator compounds, and pharmaceutical compounds detected in stream samples. Wastewater inputs into Brush Creek were largely the result of intermittent stormflow events that triggered the overflow of combined storm and sanitary sewers, and the subsequent discharge of untreated wastewater into the creek. A portion of the sediment, organic matter, and associated constituents from these events were trapped by a series of impoundments constructed along Brush Creek where they likely continued to affect water quality during base flow. Concentrations and loads of most wastewater constituents in the Blue River and Indian Creek were significantly greater than in Brush Creek, especially during base flow. However, wastewater indicator compound concentrations were sometimes greater in some Brush Creek stormflow samples. Selected stream reaches along the mid-portion of Brush Creek showed higher effects relative to other sites, primarily because these sites were in impounded reaches with the greatest density of wastewater inputs, or had relatively small drainage areas.

Kansas, Missouri

Applicability of NASQAN data for ecosystem assessments on the Missouri River

The effectiveness of ecological restoration efforts on large developed rivers is often unknown because comprehensive ecological monitoring programs are often absent. Although Eulerian water-quality monitoring programs, such as the National Stream Quality Accounting Network (NASQAN) program, are more common, they are usually not designed for ecological assessment. Therefore, this paper addresses the value of NASQAN for ecological assessments on the Missouri River and identifies potential program additions and modifications to assess certain ecological changes in physical habitat, biological structure and function, and ecotoxicity. Five additional sites: The analysis of chlorophyll, mercury, ATP, potential endocrine disruptors, total trace elements, and selected total hydrophobic organics; and the hourly measurement of dissolved oxygen, turbidity, and temperature are recommended. Hourly measurements would require an entirely new operational aspect to NASQAN. However, the presence of data loggers and satellite transmitters in the gauging stations at all NASQAN sites substantially improves the feasibility of continuous water-quality monitoring. The use of semipermeable membrane devices (SPMDs) to monitor dissolved bioaccumulating organics and trace elements, identification and enumeration of zooplankton, and characterization of the bioavailability of organic matter are also recommended. The effect of biological processes on the conservative assumptions that are used in flux and source determinations of NASQAN constituents are also evaluated. Organic carbon, organic nitrogen, dissolved phosphate, and dissolved inorganic nitrogen are the NASQAN constituents most vulnerable to biological processes and thus violation of conservative assumptions.

Hydrological Processes

Sources of coal-mine drainage and their effects on surface-water chemistry in the Claybank Creek basin and vicinity, north-central Missouri, 1983-84

Eighteen sources of drainage related to past coal-mining activity were identified in the Claybank Creek, Missouri, study area, and eight of thew were considered large enough to have detectable effects on receiving streams. However, only three sources, coal wastes at Keota and Binkley, and drainage from underground coal mines near Keota, significantly affected the chemistry of water in receiving streams. Coal wastes in the Claybank Creek basin contributed large quantities of acid drainage to receiving streams during storm runoff; pH of coal-waste runoff ranged from 2.1 to 2.8. At these small pH values, concentrations of some dissolved metals and dissolved sulfate were a few to several hundred times larger than Federal and State water-quality standards established for these constituents. Effects of acid storm runoff were detected near the mouth of North Fork Claybank Creek where the pH during a small storm was 3.9. Coal wastes in the streambeds and seepage from coal wastes also had significant effects on receiving streams during base flows. The receiving waters had pH values between 2.8 and 3.5 and concentrations of some dissolved metals and dissolved sulfate were a few to several hundred times larger than Federal and State water-quality standards. Most underground mines in the North Fork Claybank Creek basin are hydraulically connected and about 80 percent of their discharge surfaced at one site. Drainage from the underground mines contributed most of the dissolved constituents in North Fork Claybank Creek during dry weather. Underground-mine water always had a pH near 5.9, was well-buffered, had a dissolved-sulfate concentration of about 2,400 milligrams per liter, dissolved-manganese concentrations ranging from 4.0 to 5.3 milligrams per liter, and large concentrations of ferrous iron. Iron was in the ferrous state due to reducing conditions in the mines. When underground-mine drainage reached the ground surface, the ferrous iron was oxidized and precipitated to form large, orange deposits of ferric hydroxide around the site and in streambeds. Generally, drainage from strip mines had dissolved-sulfate concentrations several times larger than drainage from unmined areas. However, effects of drainage from strip mines on receiving streams were minimal when compared to the drainage from coal wastes and underground mines. No appreciable effects of mine-related drainage were detected in the water of the Claybank Creek arm of Thomas Hill Reservoir at the time of sampling because beaver bogs upstream had trapped suspended coal wastes and moderated the effects. However, the concentration of coal in the bottom material was 60 percent of the coal concentration in coal wastes at Keota, indicating that the reservoir had received these wastes during the past.

Missouri