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D.E. Rice

Publications and source records attributed to D.E. Rice.

7 recordsLinked to original sources

Variation in aluminum, iron, and particle concentrations in oxic ground-water samples collected by use of tangential-flow ultrafiltration with low-flow sampling

Particulates that move with ground water and those that are artificially mobilized during well purging could be incorporated into water samples during collection and could cause trace-element concentrations to vary in unfiltered samples, and possibly in filtered samples (typically 0.45-um (micron) pore size) as well, depending on the particle-size fractions present. Therefore, measured concentrations may not be representative of those in the aquifer. Ground water may contain particles of various sizes and shapes that are broadly classified as colloids, which do not settle from water, and particulates, which do. In order to investigate variations in trace-element concentrations in ground-water samples as a function of particle concentrations and particle-size fractions, the U.S. Geological Survey, in cooperation with the U.S. Air Force, collected samples from five wells completed in the unconfined, oxic Kirkwood-Cohansey aquifer system of the New Jersey Coastal Plain. Samples were collected by purging with a portable pump at low flow (0.2-0.5 liters per minute and minimal drawdown, ideally less than 0.5 foot). Unfiltered samples were collected in the following sequence: (1) within the first few minutes of pumping, (2) after initial turbidity declined and about one to two casing volumes of water had been purged, and (3) after turbidity values had stabilized at less than 1 to 5 Nephelometric Turbidity Units. Filtered samples were split concurrently through (1) a 0.45-um pore size capsule filter, (2) a 0.45-um pore size capsule filter and a 0.0029-um pore size tangential-flow filter in sequence, and (3), in selected cases, a 0.45-um and a 0.05-um pore size capsule filter in sequence. Filtered samples were collected concurrently with the unfiltered sample that was collected when turbidity values stabilized. Quality-assurance samples consisted of sequential duplicates (about 25 percent) and equipment blanks. Concentrations of particles were determined by light scattering.

New Jersey↗

Age dating of shallow groundwater with chlorofluorocarbons, tritium/helium: 3, and flow path analysis, southern New Jersey coastal plain

Groundwater age dating through the combination of transient tracer methods (chlorofluorocarbons (CFCs) and tritium/helium 3 ( 3 H/ 3 He)) and groundwater flow path analysis is useful for investigating groundwater travel times, flow patterns, and recharge rates, as demonstrated by this study of the homogeneous shallow, unconfined Kirkwood-Cohansey aquifer system in the southern New Jersey coastal plain. Water samples for age dating were collected from three sets of nested observation wells (10 wells) with 1.5-m-long screens located near groundwater divides. Three steady state finite difference groundwater flow models were calibrated by adjusting horizontal and vertical hydraulic conductivities to match measured heads and head differences (range, 0.002–0.23 m) among the nested wells, with a uniform recharge rate of 0.46 m per year and porosities of 0.35 (sand) and 0.45 (silt) that were assumed constant for all model simulations and travel time calculations. The simulated groundwater travel times increase with depth in the aquifer, ranging from about 1.5 to 6.5 years for the shallow wells (screen bottoms 3–4 m below the water table), from about 10 to 25 years for the medium-depth wells (screen bottoms 8–19 m below the water table), and from about 30 to more than 40 years for the deep wells (screen bottoms 24–26 m below the water table). Apparent groundwater ages based on CFC- and 3 H/ 3 He-dating techniques and model-based travel times could not be statistically differentiated, and all were strongly correlated with depth. Confinement of 3He was high because of the rapid vertical flow velocity (of the order of 1 m/yr), resulting in clear delineation of groundwater travel times based on the 3 H/ 3 He-dating technique. The correspondence between the 3 H/ 3 He and CFC ages indicates that dispersion has had a minimal effect on the tracer-based ages of water in this aquifer. Differences between the tracer-based apparent ages for seven of the 10 samples were smaller than the error values. A slight bias toward older apparent ages, found not to be statistically significant, was noted for the 3 H/ 3 He-dating technique relative to the CFC-dating technique. This result may be caused by enrichment of local air in CFC-Il and CFC-12 from urban and industrial sources in the northeastern United States and minor contamination from sampling equipment. The demonstrated validity of the combined tracer-dating techniques to determine the age of water in the Kirkwood-Cohansey aquifer system indicates that groundwater flow models can be refined when apparent ages based on 3 H/ 3 He- and CFC- dating are used as calibration targets.

New Jersey↗

Hydrogeology and simulation of ground-water flow, Picatinny Arsenal and vicinity, Morris County, New Jersey

Ground-water flow in glacial sediments and bedrock at Picatinny Arsenal, N.J., was simulated by use of a three-dimensional finite-difference ground- water-flow model. The modeled area includes a 4.3-square-mile area that extends from Picatinny Lake to the Rockaway River. Most of the study area is bounded by the natural hydrologic boundaries of the ground-water system. eophysical logs, lithologic logs, particle-size data, and core data from selected wells and surface geophysical data were analyzed to define the hydrogeologic framework. Hydrogeologic sections and thickness maps define six permeable and three low-permeability layers that are represented in the model as aquifers and confining units, respectively. Hydrologic data incorporated in the model include a rate of recharge from precipitation of 22 inches per year, estimated from long-term precipitation records and estimates of evapotranspiration. Additional recharge from infiltration along valleys was estimated from measured discharge of springs along the adjacent valley walls and from estimates of runoff from upland drainage that flows to the valley floor. Horizontal and vertical hydraulic conductivities of permeable and low-permeability layers were estimated from examination of aquifer-test data, gamma-ray logs, borehole cuttings, and previously published data. Horizontal hydraulic conductivities in glacial sediments range from 10 to 380 feet per day. Vertical hydraulic conductivities of the low-permeability layers range from 0.01 to 0.7 feet per day. The model was calibrated by simulating steady-state conditions during 1989-93 and by closely matching simulated and measured ground-water levels, vertical ground-water-head differences, and streamflow gain and loss. Simulated steady-state potentiometric- surface maps produced for the six permeable layers indicate that ground water in the unconfined material within Picatinny Arsenal flows predominantly toward the center of the valley, where it discharges to Green Pond Brook. Beneath the upper confining unit, ground water flows southwestward, down the valley. Between First Street and Farley Avenue, the upper confining unit pinches out near the valley walls, resulting in a major input of water to, and causing a local potentiometric high in, the underlying aquifer layers. Ground-water-flow directions southwest of the southern arsenal boundary are predominantly to the Rockaway River.

New Jersey↗