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D.A. Grisafe

Publications and source records attributed to D.A. Grisafe.

3 recordsLinked to original sources

Preserving Native American petroglyphs on porous sandstone

A new method of chemical treatment is proposed to improve the durability of soft, porous sandstones onto which Native American petroglyphs have been carved. Cores of Dakota Sandstone from the Faris Cave site, located along the Smoky Hill River in Ellsworth County, Kansas, were treated with ethyl silicate dissolved in a lightweight ketone carrier, and some cores were subsequently treated with a combination of ethyl silicate and silane using the same solvent. Measurement of the resulting physical properties, when compared to untreated cores, indicate the treatments substantially increased the compressive strength and freeze-thaw resistance of the stone without discoloring the stone or completely sealing the pore system. The treatment increases the durability of the stone and provides a method for preserving the petroglyphs at the site. After treating test panels at the site, the petroglyphs were treated in like manner.

Plains Anthropologist↗

Potential preservation of native American petroglyphs at Steamboat Butte, Montana, using ethyl silicate solution treatments

Samples of the Tongue River Sandstone, collected from the top of Steamboat Butte in central Montana, were treated with an ethyl silicate solution. The samples showed a large increase in compressive strength and freeze-thaw resistance, relative to untreated samples, and indicates the treatment(s) significantly consolidate(s) the stone, thus providing a method to increase the lifetime of the petroglyphs carved onto the stone.

Plains Anthropologist↗

Leaching characteristics of a high-calcium fly ash as a function of pH: A potential source of selenium toxicity

Using a modified extraction procedure, the effect of pH on the leaching of selected elements from Ca-rich (Type C) power plant fly ash was studied. Continuous additions of acetic acid were used to maintain pH values of fly ash slurries at 4.0, 6.0 and 8.0 for 24 h and an additional set was leached at its natural pH (average 11.8) value. Analyses for Se, As, Ca, Cd, Cr, Fe, Na and Pb showed that the highest concentrations occur in the leachate at pH 4.0 and decline with increasing pH. Concentrations of Cr and Fe increased slightly between neutral and high pH. Arsenic, Cd, Cr, Pb and Se concentrations exceeded the Environmental Protection Agency's toxicity criteria at pH 4.0. Selenium was above its toxicity level at pH values near 7 but the other elements were below their respective toxicity levels near neutral pH. Because recent studies show adverse effects of Se on aquatic life at far lower concentrations than the current Environmental Protection Agency's standard, high-Ca, power plant fly ashes represent a potentially hazardous pollutant to surface and subsurface waters.

Applied Geochemistry↗