Geology Reports⌕ Search

Geology topics

D. L. Butler

Publications and source records attributed to D. L. Butler.

16 recordsLinked to original sources

Effects of piping irrigation laterals on selenium and salt loads, Montrose Arroyo Basin, western Colorado

Selenium and salinity are water-quality issues in the Upper Colorado River Basin. Certain water bodies in the lower Gunnison River Basin, including the lower Gunnison River and the Uncompahgre River, exceed the State standard for selenium of 5 micrograms per liter. Remediation methods to reduce selenium and salt loading in the lower Gunnison River Basin were examined. A demonstration project in Montrose Arroyo, located in the Uncompahgre River Basin near Montrose, was done during 1998-2000 to determine the effects on selenium and salt loads in Montrose Arroyo from replacing 8.5 miles of open-ditch irrigation laterals with 7.5 miles of pipe. The participants in the project were the National Irrigation Water Quality Program, the Colorado River Basin Salinity Control Program, the Uncompahgre Valley Water Users Association, and the U.S. Geological Survey. The placing of five laterals in pipe significantly decreased selenium loads in Montrose Arroyo. The selenium load at the outflow monitoring site was about 194 pounds per year less (28-percent decrease) in the period after the laterals were placed in pipe. More than 90 percent of the decrease in selenium load was attributed to a decrease in ground-water load. Salt loads also decreased because of the lateral project, but by a smaller percentage than the selenium loads. The salt load at the outflow site on Montrose Arroyo was about 1,980 tons per year less in the post-project period than in the pre-project period. All of the effects of the demonstration project on selenium and salt loads probably were not measured by this study because some of the lateral leakage that was eliminated had not necessarily discharged to Montrose Arroyo upstream from the monitoring sites. A greater decrease in selenium loads relative to salt loads may have been partially the result of decreases in selenium concentrations in ground water in some areas.

Colorado↗

Field screening of water, soil, bottom sediment, and biota associated with irrigation drainage in the Dolores Project and the Mancos River Basin, southwestern Colorado, 1994

A reconnaissance investigation for the National Irrigation Water Quality Program in 1990 indicated elevated selenium concentrations in some water and biota samples collected in the Dolores Project in southwestern Colorado. High selenium concentrations also were indicated in bird samples collected in the Mancos Project in 1989. In 1994, field screenings were done in parts of the Dolores Project and Mancos River Basin to collect additional selenium data associated with irrigation inthose areas. Selenium is mobilized from soils in newly irrigated areas of the Dolores Project called the Dove Creek area, which includes newly (since 1987) irrigated land north of Cortez and south of Dove Creek.Selenium was detected in 18 of 20stream samples, and the maximum concentration was 12micrograms per liter. The Dove Creek area is unique compared to other study areas of the National Irrigation Water Quality Program becauseselenium concentrations probably are indicative of initial leaching conditions in a newly irrigated area.Selenium concentrations in nine shallow soil samples from the Dove Creek area ranged from 0.13 to 0.20 micrograms per gram. Selenium concentrations in bottom sediment from six ponds were less than the level of concern for fish and wildlife of 4 micrograms per gram. Many biota samples collected in the Dove Creek area had elevated selenium concentrations when compared to various guidelines and effect levels,although selenium concentrations in water, soil, and bottom sediment were relatively low. Selenium concentrations in 12 of 14 aquatic-invertebratesamples from ponds exceeded 3 micrograms per gram dry weight, a dietary guideline for protection of fish and wildlife. The mean seleniumconcentration of 10.3 micrograms per gram dry weight in aquatic bird eggs exceeded the guideline for reduced hatchability of 8 micrograms per gramdry weight. Two ponds in the Dove Creek area had a high selenium hazard rating based on a new protocol for assessing selenium hazard in theenvironment; however, waterfowl were reproducing at the two ponds. Three tributary streams of Mc Elmo Creek that drain irrigated areas of the Montezuma Valley south of the creek were sampled in 1994. Mud Creek probably is the largest source of selenium to Mc Elmo Creek. Most biota samples from Mud Creek had elevated selenium concentrations when compared to guidelines for dietary items and freshwater fish. Selenium concentrations in water samples collected in the Mancos River Basin upstream from Navajo Wash, which includes the Mancos Project, ranged from less than 1 to 10 micrograms per liter. Mud Creek contributed about 74 percent of the selenium load to the upper Mancos River in March 1994.Selenium concentrations were much higher in Navajo Wash; a sample collected in March had 97 micrograms per liter of selenium. Bottom-sediment samples from two ponds in the Mancos Projectexceeded the concentration of concern of 4 micrograms per gram. The highest selenium concentrations in biota samples from streams in the Mancos River Basin were for samples from Navajo Wash. Mostconcentrations in biota in the upper Mancos River Basin were less than guidelines. Mean selenium concentrations in eggs from aquatic birds collected at three ponds in the Mancos Project slightly exceed the guideline associated with reduced hatchability.Five bird livers had a mean selenium concentration of 32.6 micrograms per gram dry weight, whichslightly exceeded the mean concentration of 30 micrograms per gram dry weight that is associated with reproductive impairment. Two of the pondshad a high selenium hazard rating; however, mallard reproduction was observed in 1994 at one of the ponds that had a high selenium-hazard rating.

Colorado↗

Trend analysis of selected water-quality data associated with salinity-control projects in the Grand Valley, in the lower Gunnison River basin, and at Meeker Dome, western Colorado

To decrease salt loading to the Colorado River from irrigated agriculture, salinity-control projects have been under construction since 1979 by the Bureau of Reclamation and the U.S. Department of Agriculture in the Grand Valley and since 1988 in the lower Gunnison River Basin of western Colorado. In 1980, a salinity-control project was initiated at Meeker Dome, which involved plugging three abandoned oil wells that were discharging saline water to the White River. Trend analysis was used to determine if the salinity-control projects had affected salinity in the Colorado and White Rivers. The mean annual dissolved-solids load in the Colorado River near the Colorado-Utah State line for water years 1970-93 was about 3.32 million tons. About 46 percent of that load was from the Colorado River upstream from the Grand Valley and about 38 percent was from the Gunnison River. About 16 percent of the dissolved-solids load in the Colorado River near the State line was discharged from the Grand Valley, and most of the Grand Valley dissolved-solids load was from irrigation-induced sources. Monotonic trend analysis of dissolved-solids and major-ion data for the Colorado and Gunnison Rivers was used for determining if salinity-control projects had affected salinity (dissolved solids) in the Colorado River. Data collected in water years 1970-93 at gaging stations on the Colorado River-one near Cameo and the other near the Colorado-Utah State line, and at the station on the Gunnison River near Grand Junction-were analyzed for trends. A computerized procedure developed by the U.S. Geological Survey that uses the nonparametric seasonal Kendall test with adjustment for streamflow was used for trend analysis of periodic and monthly data, and linear regression was used for trend analysis of annual data. Three time periods were tested, including periods that were concurrent with work on salinity-control projects. Many of the trends in unadjusted concentration and load data were not statistically significant. There were downward trends in flow-adjusted dissolved-solids and major-ion concentrations and in monthly dissolved-solids loads for all three stations in the 1970's, prior to the salinity-control projects. The two stations on the Colorado River also had significant downward trends in flow-adjusted concentrations and loads for water years 1986-93. The cumulative effects of salinity-control projects in the Grand Valley and in the lower Gunnison River Basin on salinity in the Colorado River would have become more substantial after the mid-1980's. Part of the decrease in dissolved solids in the Colorado River near the State line probably was related to salinity-control projects; however, there apparently are other factors that are affecting dissolved solids in the upper Colorado River in addition to salinity-control projects. A significant decrease in chloride and sodium concentrations in the White River downstream from Meeker Dome indicated that the well plugging in 1981 was successful in stopping much of the discharge of saline water from the wells. Chloride and sodium concentrations have not changed in the White River at Meeker or downstream from Meeker during water years 1982-95, indicating that the well plugging has remained intact.

Colorado↗

Detailed study of selenium and other constituents in water, bottom sediment, soil, alfalfa, and biota associated with irrigation drainage in the Uncompahgre Project area and in the Grand Valley, west-central Colorado, 1991-93

In 1985, the U.S. Department of the Interior began a program to study the effects of irrigation drainage in the Western United States. These studies were done to determine whether irrigation drainage was causing problems related to human health, water quality, and fish and wildlife resources. Results of a study in 1991-93 of irrigation drainage associated with the Uncompahgre Project area, located in the lower Gunnison River Basin, and of the Grand Valley, located along the Colorado River, are described in this report. The focus of the report is on the sources, distribution, movement, and fate of selenium in the hydrologic and biological systems and the effects on biota. Generally, other trace- constituent concentrations in water and biota were not elevated or were not at levels of concern. Soils in the Uncompahgre Project area that primarily were derived from Mancos Shale contained the highest concentrations of total and watrer-extractable selenium. Only 5 of 128 alfalfa samples had selenium concentrations that exceeded a recommended dietary limit for livestock. Selenium data for soil and alfalfa indicate that irrigation might be mobilizing and redistributing selenium in the Uncompahgre Project area. Distribution of dissolved selenium in ground water is affected by the aqueous geochemical environment of the shallow ground- water system. Selenium concentrations were as high as 1,300 micrograms per liter in water from shallow wells. The highest concentrations of dissolved selenium were in water from wells completed in alluvium overlying the Mancos Shale of Cretaceous age; selenium concentrations were lower in water from wells completed in Mancos Shale residuum. Selenium in the study area could be mobilized by oxidation of reduced selenium, desorption from aquifer sediments, ion exchange, and dissolution. Infiltration of irrigation water and, perhaps nitrate, provide oxidizing conditions for mobilization of selenium from alluvium and shale residuum and for transport to streams and irrigation drains that are tributary to the Gunnison, Uncompahgre, and Colorado Rivers. Selenium concentrations in about 64 percent of water samples collected from the lower Gunnison River and about 50 percent of samples from the Colorado River near the Colorado-Utah State line exceeded the U.S. Environmental Protection Agency criterion of 5 micrograms per liter for protection of aquatic life. Almost all selenium concentrations in samples collected during the nonirrigation season from Mancos Shale areas exceeded the aquatic-life criterion. The maximum selenium concentrations in surface-water samples were 600 micrograms per liter in the Uncompahgre Project area and 380 micrograms per liter in the Grand Valley. Irrigation drainage from the Uncompahgre Project and the Grand Valley might account for as much as 75 percent of the selenium load in the Colorado River near the Colorado-Utah State line. The primary source areas of selenium were the eastern side of the Uncompahgre Project and the western one-half of the Grand Valley, where there is extensive irrigation on soils derived from Mancos Shale. The largest mean selenium loads from tributary drainages were 14.0 pounds per day from Loutsenhizer Arroyo in the Uncompahgre Project and 12.8 pounds per day from Reed Wash in the Grand Valley. Positive correlations between selenium loads and dissolved-solids loads could indicate that salinity-control projects designed to decrease dissolved-solids loads also could decrease selenium loads from the irrigated areas. Selenium concentrations in irrigation drainage in the Grand Valley were much higher than concentrations predicted by simple evaporative concentration of irrigation source water. Selenium probably is removed from pond water by chemical and biological processes and incorporated into bottom sediment. The maximum selenium concentration in bottom sediment was 47 micrograms per gram from a pond on the eastern side of the Uncompahgre Project.

Water-Resources Investigations Report↗

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Dolores Project area, southwestern Colorado and southeastern Utah, 1990-91

Water, bottom-sediment, and biota samples were collected in 1990-91 to identify water-quality problems associated with irrigation drainage in the Dolores Project area. Concentrations of cadmium, mercury, and selenium in some water samples exceeded aquatic-life criteria. Selenium was associated with irrigaton drainage from the Dolores Project, but other trace elements may be transported into the area in the irrigation water supply. Selenium concentrations exceeded the chronic aquatic-life criterion in water samples from lower McElmo Creek and Navajo Wash, which drain the Montezuma Valley, from newly irrigated areas, and from the Mancos River. The maximum selenium con- centration in water was 88 micrograms per liter from Navajo Wash. Concentrations of herbicides in water were less than concentrations harmful to aquatic life. Selenium concentrations in four bottom-sediment samples exceeded the baseline concentrations for soils in the Western United States. The largest selenium concentrations in biota were in samples from Navajo Wash, from newly irrigated areas north of the Montezuma Valley, and from the Mancos River basin. Selenium concentrations in aquatic-invertebrate samples from the newly irrigated areas exceeded a guideline for food items consumed by fish and wildlife. Selenium concen- trations in whole-body suckers were larger in the San Juan River downstream from the Dolores Project than upstream from the project at Four Corners. Selenium concentrations in fathead minnow samples from two sites were at adverse-effect levels. Mercury concentrations in warm-water game fish in reservoirs in the study area may be of concern to human health. Some concentrations of other trace elements exceeded background concentrations, but the concentrations were not toxicologically significant or the toxicologic significance is not known.

Water-Resources Investigations Report↗

Physical, chemical, and biological data for detailed study of irrigation drainage in the Uncompahgre Project area and in the Grand Valley, west-central Colorado, 1991-92

Because of concerns about potential effects of irrigation drainage on fish and wildlife resources and on human health, the U.S. Department of the Interior initiated a program in 1985 to assess water-quality problems associated with Federal irrigation projects in the Western United States. Physical, chemical, and biological data were collected for a detailed study of irrigation drainage in the Uncompahgre Project area and in the Grand Valley, west-central Colorado, during 1991-92. This report lists onsite measurements and concen- trations of major constituents, trace elements, and stable isotopes for surface-water- and ground-water-sampling sites. Insecticide data collected in the Grand Valley are presented. Ranges of specific-conductance measurements and dissolved- oxygen concentrations for selected wells and a daily record of water-level altitude and specific conduc- tance for a well in the Grand Valley are presented. The report presents historical water-level and dissolved-solids data for two wells in the Grand Valley. Concentrations of trace elements, major constituents, total carbon, and organic carbon in bottom-sediment, bedrock, and in aquifer-sediment samples and semiquantitative data on clay and bulk mineralogy of samples of the Mancos Shale are presented. The report contains selenium-speciation data for selected water and bottom-sediment samples and selected aquifer-test results. Biological samples collected in the Uncompahgre Project area and in the Grand Valley included aquatic plants, aquatic invertebrates, fish, birds, and bird eggs. The report lists concentrations of trace elements in biological samples collected in 1991-92. A limited number of biological samples were analyzed for pesticides, PCB's, and polycyclic aromatic hydrocarbons.

Open-File Report↗

Reconnaissance investigation of water quality, bottom sediment, and biota associated with irrigation drainage in the Pine River Project area, Southern Ute Indian Reservation, southwestern Colorado and northwestern New Mexico, 1988-89

During 1988-89, water, bottom sediment, biota, soil, and plants were sampled for a reconnaissance investigation of the Pine River Project area in southwestern Colorado. Irrigation drainage does not seem to be a major source of dissolved solids in streams. Concentrations of manganese, mercury, and selenium exceeded drinking-water regulations in some streams. The maximum selenium concentration in a stream sample was 94 microg/L in Rock Creek. Irrigation drainage and natural groundwater are sources of some trace elements to streams. Water from a well in a nonirrigated area had 4,800 microg/L of selenium. Selenium concentrations in soil on the Oxford Tract were greater in areas previously or presently irrigated than in areas never irrigated. Some forage plants on the Oxford Tract had large selenium concentrations, including 180 mg/km in alfalfa. Most fish samples had selenium concentrations greater than the National Contaminant Biomonitoring Program 85th percentile. Selenium concentrations in aquatic plants, aquatic inverte- brates, and small mammals may be of concern to fish and wildlife because of possible food-chain bioconcentration. Selenium concentrations in bird samples indicate selenium contamination of biota on the Oxford Tract. Mallard breasts had selenium concentrations exceeding a guideline for human consumption. The maximum selenium concentration in biota was 50 microg/g dry weight in a bird liver from the Oxford Tract. In some fish samples, arsenic, cadmium, copper, and zinc exceeded background concentrations, but concentrations were not toxic. Mercury concentrations in 16 fish samples exceeded the background concentration. Ten mercury concentrations in fish exceeded a guideline for mercury in food for consumption by pregnant women.

Colorado↗

Sediment discharge in Rock Creek and the effect of sedimentation rate on the proposed Rock Creek Reservoir, northwestern Colorado

Sediment data collected from 1976 to 1985 and stream discharge data collected from 1952 to 1980 at gaging station 09060500, Rock Creek near Toponas, Colorado, were used to determine total sediment discharge into the proposed Rock Creek Reservoir. Suspended sediment discharge and bedload discharge were related to stream discharge by using logarithmic regression relations. Mean annual suspended sediment discharge was estimated to be 309 tons/yr, and mean annual bedload discharge was estimated to be 428 tons/yr in Rock Creek at the Toponas gaging station for the 1953 through 1980 water years. The mean annual total sediment discharge into the proposed reservoir was estimated to be 768 tons/yr, which includes 10% addition to the suspended sediment discharge calculated for the Toponas gaging station to account for suspended sediment discharge from Horse Creek. This rate of mean annual total sediment discharge would decrease the long-term water storage capacity of the proposed reservoir by < 1% after 100 years. Suspended sediment discharge/unit-drainage-basin area at gaging station 09060550, Rock Creek at Crater, located about 5 mi downstream for the proposed reservoir site, was equivalent to suspended-sediment discharge/unit-drainage-basin area at the Toponas gaging station during 1985. Long-term sediment data collection at the Crater gaging station could be used for detecting changes in suspended sediment discharge in Rock Creek at the proposed reservoir site. (Author 's abstract)

Water-Resources Investigations Report↗

Sediment discharge in the Colorado River near De Beque, Colorado

A study was conducted to determine annual-sediment discharge at the site of a proposed reservoir on the Colorado River at Una, located 3 miles upstream from De Beque, Colorado. Eleven suspended sediment samples were collected during 1984 at the De Beque bridge. These data were combined with suspended sediment data collected for the Colorado River at two nearby streamflow gaging stations to define relations between suspended-sediment discharge and stream discharge. Best results were obtained when the data were separated into two periods, March through October, and November through February. The data for March through October were separated into two periods: (1) Rising stream-stage period, which includes data collected prior to the data of the annual peak-stream discharge, and (2) falling stream-stage period, which includes data collected after the date of the annual peak-stream discharge. Nine bedload samples were collected during 1984 to determine the contribution of bedload sediment discharge to total sediment discharge. Bedload accounted for < 2% of total sediment discharge. The best relations describing bedload sediment discharge were obtained when the bedload data were separated into two periods: (1) Data collected prior to the date of the annual peak-stream discharge, and (2) data collected after the date of the annual peak-stream discharge. Mean annual sediment discharge in the Colorado River at the proposed Una reservoir site was estimated to be 1,065,000 tons/year for October 1966 through September 1984. Water storage capacity of the proposed reservoir would decrease about 30% after 100 years at this sediment discharge rate. (USGS)

Water-Resources Investigations Report↗

General surface- and ground-water quality in a coal-resource area near Durango, southwestern Colorado

A general description of surface and groundwater quality in a coal-resource area near Durango, southwestern Colorado is given. Dissolved-solids concentrations were less than 1,000 mg/l in streams, except in the Alkali Gulch, Basin Creek, and Carbon Junction Canyon drainage basins. Median concentrations of dissolved boron, iron, manganese, and zinc were less than 35 microg/l; median concentrations of dissolved lead and selenium were less than 1 microg/l.

Colorado↗

Discharge and water quality of springs in Roan and Parachute Creek basins, northwestern Colorado, 1981-83

This report is a compilation and interpretation of discharge, water-quality, and radiochemical data collected at springs in the oil-shale regions of Roan and Parachute Creek basins, Colorado, from 1981 to 1983. Springs located on upland plateaus and ridges are mixed-cation bicarbonate water types with 216 to 713 milligrams per liter dissolved solids. Calcite and dolomite dissolution are dominant chemical reactions in upland springs. Springs located in the canyons contain greater concentrations of sodium and sulfate and have 388 to 3,970 milligrams per liter dissolved solids. Gypsum dissolution is an important chemical reaction in canyon spring water. The only trace constituents with mean concentration greater than 10 micrograms per liter in the study area were barium, boron, lithium and strontium. None of the canyon springs investigated represent discharge from the lower aquifer in the Green River Formation. Analysis of chemical and discharge data for streams in the Roan Creek drainage showed evidence of lower-aquifer discharge into the canyons. Springs located near an oil-shale mine or processing plant could be used for monitoring groundwater quality and quantity. Bicarbonate, fluoride, arsenic, boron, lithium, mercury, ammonia, and organic carbon may be chemical indicators of mine or process-water contamination of shallow aquifers near an oil-shale plant or mine.

Colorado↗