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D. K. Mueller

Publications and source records attributed to D. K. Mueller.

13 recordsLinked to original sources
USGS2008

Distribution of algae in the San Joaquin River, California, in relation to nutrient supply, salinity and other environmental factors

1. The taxonomic composition and biomass of the phytoplankton and the taxonomic composition of the phytobenthos of the San Joaquin River and its major tributaries were examined in relation to water chemistry, habitat and flow regime. Agricultural drainage and subsurface flow contribute to a complex gradient of salinity and nutrients in this eutrophic, 'lowland type' river. 2. Because of light-limiting conditions for growth, maintenance demands of the algae exceed production during summer and autumn in the San Joaquin River where there is no inflow from tributaries. In contrast to substantial gains in concentration of inorganic nitrogen and soluble reactive phosphorus during the summer of normal-flow years, net losses of algal biomass (2-4 ??g L -1 day -1 chlorophyll a) occurred in a mid-river segment with no significant tributary inflow. However, downstream of a large tributary draining the Sierra Nevada, a substantial net gain in algal biomass (6-11 μg L -1 day -1 ) occurred in the summer, but not in the spring (loss of 1-6 μg L -1 day -1 ) or autumn (loss of 2-5 ??g L -1 day -1 ). 3. The phytoplankton was dominated in summer by 'r-selected' centric diatoms (Thalassiosirales), species both tolerant of variable salinity and widely distributed in the San Joaquin River. Pennate diatoms were proportionally more abundant (in biomass) in the winter, spring and autumn. Abundant taxa included the diatoms Cyclotella meneghiniana, Skeletonema cf. potamos, Cyclostephanos invisitatus, Thalassiosira weissflogii, Nitzschia acicularis, N. palea and N. reversa, and the chlorophytes Chlamydomonas sp. and Scenesdesmus quadricauda. Patterns in the abundance of species indicated that assembly of the phytoplankton is limited more by light and flow regime than by nutrient supply. 4. The phytobenthos was dominated by larger, more slowly reproducing pennate diatoms. Few of the abundant species are euryhaline. The diatoms Navicula recens and Nitzschia inconspicua and cyanophytes, Oscillatoria spp., were the principal late-summer benthic species upstream in the mainstem and in drainages of the San Joaquin Valley. Many of the other abundant diatoms (Amphora veneta, Bacillaria paxillifer, Navicula symmetrica, Nitzschia amphibia, N. fonticola, N. palea, Pleurosigma salinarum) of late-summer assemblages in these segments also are motile species. While many of these species also were abundant in segments downstream of confluences with rivers draining the Sierra Nevada, the relative abundance of prostrate (Cocconeis placentula var. euglypta, Navicula minima) and erect or stalked (Achnanthidium deflexum, Achnanthes lanceolata, Gomphonema kobayasii, G. parvulum var. lagenula) diatoms and Stigeoclonium sp. was greater in these lower San Joaquin River segments. 5. A weighted-averaging regression model, based on salinity and benthic-algal abundance in the San Joaquin River and segments of its major tributaries within the San Joaquin Valley, yielded a highly significant coefficient-of-determination (r 2 = 0.84) and low prediction error between salinity inferred from the species and that observed, indicating that salinity tolerance is a primary constraint on growth and assembly of the phytobenthos. The same measures of predictability indicated poor performance of a model based on inorganic nitrogen. However, with a greater representation of tributaries (including segments within the Sierra Nevada foothills) in the sample set, an inorganic nitrogen model also yielded a highly significant coefficient-of-determination (r 2 = 0.87) and low prediction error between the species-inferred and the observed concentration. As with the salinity model (r 2 = 0.94) for the enlarged data set, a systematic difference (increased deviation of residuals) existed at high inorganic nitrogen concentrations. These results indicate substantial interaction between salinity and inorganic nitrogen as constraints on the structure of benthic-algal communities of the San Joaquin River basin.

California↗
USGS2008

Efficacy of algal metrics for assessing nutrient and organic enrichment in flowing waters

1. Algal-community metrics were calculated for periphyton samples collected from 976 streams and rivers by the U.S. Geological Survey’s National Water-Quality Assessment (NAWQA) Programme during 1993–2001 to evaluate national and regional relations with water chemistry and to compare whether algal-metric values differ significantly among undeveloped and developed land-use classifications. 2. Algal metrics with significant positive correlations with nutrient concentrations included indicators of trophic condition, organic enrichment, salinity, motility and taxa richness. The relative abundance of nitrogen-fixing algae was negatively correlated with nitrogen concentrations, and the abundance of diatom species associated with high dissolved oxygen concentrations was negatively correlated with both nitrogen and phosphorus concentrations. Median algal-metric values and nutrient concentrations were significantly lower at undeveloped sites than those draining agricultural or urban catchments. 3. Total algal biovolume did not differ significantly among major river catchments or land-use classifications, and was only weakly correlated with nitrate (positive) and suspended-sediment (negative) concentrations. Estimates of periphyton chlorophyll a indicated an oligotrophic–mesotrophic boundary of about 21 mg m −2 and a mesotrophic–eutrophic boundary of about 55 mg m −2 based on upper and lower quartiles of the biovolume data distribution. 4. Although algal species tolerance to nutrient and organic enrichment is well documented, additional taxonomic and autecological research on sensitive, endemic algal species would further enhance water-quality assessments.

Freshwater Biology↗
USGS2007

Identification of solute loading sources to a surface stream

A study was performed to identify sources of solute loading to the Dirty Devil River and its major tributaries, in southeastern Utah. A primary goal was to determine the contribution of gypsum dissolution to total dissolved solids concentration, and its potential increase in the future if salinity control measures are instituted. Synoptic field data were collected during the low flow period in October 1983. Data were analyzed using the geochemistry models WATEQF and BALANCE to postulate mineral reactions leading to solute loading. Three known sources of solute loading, involving two different geochemical mechanisms, were clearly discernable. Two additional areas of possible gypsum dissolution were located.

Journal of the American Water Resources Associatio↗
USGS2007

Nutrient concentrations and yields in undeveloped stream basins of the United States

Data from 85 sites across the United States were used to estimate concentrations and yields of selected nutrients in streams draining relatively undeveloped basins. Flow-weighted concentrations during 1990-1995 were generally low with median basin concentrations of 0.020, 0.087, 0.26, 0.010, and 0.022 milligrams per liter (mg/L) for ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus, respectively. The flow-weighted concentration of nitrate exceeded 0.6 mg/L in only three basins. Total nitrogen exceeded 1 mg/L in only four basins, and total phosphorus exceeded 0.1 mg/L in only four basins. The median annual basin yield of ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus was 8.1, 26, 86, 2.8, and 8.5 kilograms per square kilometer, respectively. Concentrations and yields of nitrate tended to be highest in northeastern and mid-Atlantic coastal states and correlated well with areas of high atmospheric nitrogen deposition. Concentrations and yields of total nitrogen were highest in the southeastern part of the nation and in parts of the upper Midwest. In the northeast, nitrate was generally the predominant form of nitrogen, and in the southeast and parts of the upper Midwest, organic nitrogen was the dominant form. Concentrations of total phosphorus were generally highest in the Rocky Mountain and Central Plain states.Data from 85 sites across the United States were used to estimate concentrations and yields of selected nutrients in streams draining relatively undeveloped basins. Flow-weighted concentrations during 1990-1995 were generally low with median basin concentrations of 0.020, 0.087, 0.26, 0.010, and 0.022 milligrams per liter (mg/L) for ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus, respectively. The flow-weighted concentration of nitrate exceeded 0.6 mg/L in only three basins, Total nitrogen exceeded 1 mg/L in only four basins, and total phosphorus exceeded 0.1 mg/L in only four basins. The median annual basin yield of ammonia as N, nitrate as N, total nitrogen, orthophosphate as P, and total phosphorus was 8.1, 26, 86, 2.8, and 8.5 kilograms per square kilometer, respectively. Concentrations and yields of nitrate tended to be highest in northeastern and mid-Atlantic coastal states and correlated well with areas of high atmospheric nitrogen deposition. Concentrations and yields of total nitrogen were highest in the southeastern part of the nation and in parts of the upper Midwest. In the northeast, nitrate was generally the predominant form of nitrogen, and in the southeast and parts of the upper Midwest, organic nitrogen was the dominant form. Concentrations of total phosphorus were generally highest in the Rocky Mountain and Central Plain states.Data collected across the US from 85 streams draining relatively undeveloped basins were used to identify broad regional and national patterns in nutrient concentrations and yields. The basins of interest were selected from three USGS programs: the Hydrologic Benchmark Network, the National Water-Quality Assessment, and the Research Program. Water samples from most basins were collected on a weekly to bimonthly schedule. While the flow-weighted concentrations of nutrients varied, concentrations were low in most basins. Median flow-weighted concentrations of ammonia, nitrate, total nitrogen, orthophosphate, and total phosphorus were 0.020, 0.087, 0.26, 0.010, and 0.022 mg/l, respectively. Nitrate concentrations tended to be highest in the northeastern US, while southeastern and north-central basins had some of the highest NH3 concentrations. Flow-weighted concentrations of total P were generally highest in the Rocky Mountain and Central Plain states and in parts of the southeast.

Journal of the American Water Resources Associatio↗
USGS1997

Logistic model of nitrate in streams of the upper-midwestern United States

Nitrate in surface water can have adverse effects on aquatic life and, in drinking-water supplies, can be a risk to human health. As part of a regional study, nitrates as N (NO3-N) was analyzed in water samples collected from streams throughout 10 Midwestern states during synoptic surveys in 1989, 1990, and 1994. Data from the period immediately following crop planting at 124 sites were analyzed during logistic regression to relate discrete categories of NO3-N concentrations to characteristics of the basins upstream from the sites. The NO3-N data were divided into three categories representing probable background concentrations (<3 mg L-1), elevated concentrations (3-10 mg L-1), and concentrations that exceeded the U.S. Environmental Protection Agency maximum contaminant level (MCL) for drinking water (>10 mg L-1). Nitrate-N concentrations were positively correlated to streamflow, upstream area planted in corn (Zea mays L.), and upstream N- fertilizers application rates. Elevated NO3-N concentrations were associated with poorly drained soils and were weakly correlated with population density. Nitrate-N and streamflow data collected during 1989 and 1990 were used to calibrate the model, and data collected during 1994 were used for verification. The model correctly estimated NO3-N concentration categories for 79% of the samples in the calibration data set and 60% of the samples in the verification data set. The model was used to indicate where NO3-N concentrations might be elevated or exceed the NO3-N MCL in streams throughout the study area. The potential for elevated NO3-N concentrations was predicted to be greatest for streams in Illinois, Indiana, Iowa, and western Ohio.

Journal of Environmental Quality↗
USGS1995

Nutrients in ground water and surface water of the United States; an analysis of data through 1992

Historical data on nutrient (nitrogen and phosphorus species) concentrations in ground-and surface-water samples were compiled from 20 study units of the National Water-Quality Assessment (NAWQA) Program and 5 supplemental study areas. The resultant national retrospective data sets contained analyses of about 12,000 Found-water and more than 22,000 surface-water samples. These data were interpreted on regional and national scales by relating the distributions of nutrient concentrations to ancillary data, such as land use, soil characteristics, and hydrogeology, provided by local study-unit personnel. The information provided in this report on environmental factors that affect nutrient concentrations in ground and surface water can be used to identify areas of the Nation where the vulnerability to nutrient contamination is greatest. Nitrate was the nutrient of greatest concern in the historical ground-water data. It is the only nutrient that is regulated by a national drinking-water standard. Nitrate concentrations were significantly different in ground water affected by various land uses. Concentrations in about 16 percent of the samples collected in agricultural areas exceeded the drinking-water standard. However, the standard was exceeded in only about 1 percent of samples collected from public-supply wells. A variety of ancillary factors had significant relations to nitrate concentrations in ground water beneath agricultural areas. Concentrations generally were highest within 100 feet of the land surface. They were also higher in areas where soil and geologic characteristics promoted rapid movement of water to the aquifer. Elevated concentrations commonly occurred in areas underlain by permeable materials, such as carbonate bedrock or unconsolidated sand and gravel, and where soils are generally well drained. In areas where water movement is impeded, denitrification might lead to low concentrations of nitrate in the ground water. Low concentrations were also related to interspersion of pasture and woodland with cropland in agricultural areas. Elevated nitrate concentrations in areas of more homogeneous cropland probably were a result of intensive nitrogen fertilizer application on large tracts of land. Certain regions of the United States seemed more vulnerable to nitrate contamination of ground water in agricultural areas. Regions of greater vulnerability included parts of the Northeast, Midwest, and West Coast. The well-drained soils, typical in these regions, have little capacity to hold water and nutrients; therefore, these soils receive some of the largest applications of fertilizer and irrigation in the Nation. The agricultural land is intensively cultivated for row crops, with little interspersion of pasture and woodland. Nutrient concentrations in surface water also were generally related to land use. Nitrate concentrations were highest in samples from sites downstream from agricultural or urban areas. However, concentrations were not as high as in ground water and rarely exceeded the drinking-water standard. Elevated concentrations of nitrate in surface water of the Northeastern United States might be related to large amounts of atmospheric deposition (acid rain). High concentrations in parts of the Midwest might be related to tile drainage of agricultural fields. Ammonia and phosphorus concentrations were highest downstream from urban areas. These concentrations generally were high enough to warrant concerns about toxicity to fish and accelerated eutrophication. Recent improvements in wastewater treatment have decreased ammonia concentrations downstream from some urban areas, but the result has been an increase in nitrate concentrations. Information on environmental factors that affect water quality is useful to identify drainage basins throughout the Nation with the greatest vulnerability for nutrient contamination and to delineate areas where ground-water or surface-water contamination is most likely to oc

Water-Resources Investigations Report↗
USGS1988

Estimation of natural dissolved-solids discharge in the Upper Colorado River basin, Western United States

A statistical method was developed to estimate monthly natural dissolved-solids discharge at selected sites in the Upper Colorado River Basin. Natural dissolved-solids discharge was defined as the rate of inorganic-solute flow past a specific site that would have occurred if there had been no water-resources development in the basin upstream from the site. The method used weighted least-squares regression to fit a model of dissolved-solids discharge as a function of streamflow and several variables representing development. After the model had been calibrated for an individual site, the development variables were assigned a value of zero to yield the relation between dissolved-solids discharge and streamflow for conditions of no upstream development. Natural dissolved-solids discharge was calculated using this relation and estimates of natural streamflow provided by the U.S. Bureau of Reclamation. Limitations of the method included lack of data to verify estimates of the natural dissolved-solids discharge and to represent all the effects of development adequately. However, model statistics indicated a good fit to historical data. Also, the estimates of natural dissolved-solids-discharge had the expected monthly distribution and were consistent between upstream and downstream sites. (USGS)

Water-Resources Investigations Report↗
USGS1988

Extension of streamflow and dissolved-solids records at selected sites in the Colorado River basin, Arizona, California, Colorado, Nevada, New Mexico, Utah, and Wyoming, 1940-83

Monthly streamflow and dissolved-solids concentration were estimated for periods prior to the initiation of data collection at selected sites in the Colorado River basin. Techniques used for this record extension included simple and weighted least-squares regression. Streamflow records were extended at 5 sites and dissolved-solids records were extended at 13 sites. Records were extended back through 1941 to provide a completely concurrent data set for all sites. Standard errors were 5 to 74% for monthly streamflow and 3 to 27% for monthly, flow-weighted dissolved-solids concentration. The extended records at all sites were consistent with records from the historical period. (USGS)

Water-Resources Investigations Report↗