Geology topics

Corrine Alexander

Publications and source records attributed to Corrine Alexander.

7 recordsLinked to original sources

USGS2012

Priorities for IOOS ® Data Management and Communications (DMAC)

Dramatic increases in the volume of online data and rapid advances in information technology have transformed many aspects of our society. In the coastal ocean, the amount of data is also growing dramatically due to new sensor and modeling technologies. Lagging behind this deluge of ocean data, however, is an effective framework of standards, protocols, tools and culture needed to transform the way we generate knowledge and value from ocean data. The Data Management and Communications (DMAC) sub-system was envisioned to provide such an information management capability for IOOS®, promoting standards and policies to be implemented by data providers across the IOOS enterprise. DMAC needs to build upon the successes and lessons learned during development of web service standards and promote a set of end-to-end standards and procedures for the entire ocean-data life cycle, including documentation through metadata, quality control and quality assurance, effective data discovery, and stewardship through archiving. Because information technology is constantly changing, a multiyear, top-down design and implementation plan is not workable. DMAC should start by promoting a set of protocols that are functional for specific use cases, creating a modular framework in which modules can be replaced as technologies change. In addition to promoting protocols, DMAC needs to support training, flexible online documentation, support, and social networking that enable users to share code, techniques and experiences. Through this bottom-up approach, trust and understanding will foster adoption by the community. Finally, a compliance and certification process should be developed that allows IOOS to ensure that they meet the needs of customers and other stakeholders while complying with regulatory requirements related to the data. If this approach is followed, we will enable breakthroughs in ocean data–driven technology similar to those common elsewhere in our society, fulfilling the broader mission of IOOS.

Book↗

USGS2011

Building transparent data access for ocean observatories: Coordination of U.S. IOOS DMAC with NSF's OOI Cyberinfrastructure

The NOAA-led U.S. Integrated Ocean Observing System (IOOS) and the National Science Foundation's Ocean Observatories Initiative (OOI) have been collaborating since 2007 on advanced tools and technologies that ensure open access to ocean observations and models. Initial collaboration focused on serving ocean data via cloud computing-a key component of the OOI cyberinfrastructure (CI) architecture. As the OOI transitioned from planning to execution in the Fall of 2009, an OOI/IOOS team developed a customer-based "use case" to align more closely with the emerging objectives of OOI-CI team's first software release scheduled for Summer 2011 and provide a quantitative capacity for stress-testing these tools and protocols. A requirements process was initiated with coastal modelers, focusing on improved workflows to deliver ocean observation data. Accomplishments to date include the documentation and assessment of scientific workflows for two "early adopter" modeling teams from IOOS Regional partners (Rutgers-the State University of New Jersey and University of Hawaii's School of Ocean and Earth Science and Technology) to enable full understanding of data sources and needs; generation of all-inclusive lists of the data sets required and those obtainable through IOOS; a more complete understanding of areas where IOOS can expand data access capabilities to better serve the needs of the modeling community; and development of "data set agents" (software) to facilitate data acquisition from numerous data providers and conversions of the data format to the OOI-CI canonical form. ?? 2011 MTS.

Conference Paper↗

USGS2003

Temporal and spatial distributions of contaminants in sediments of Santa Monica Bay, California

Contaminant inputs from wastewater discharge, a major source of contamination to Santa Monica Bay (SMB), have declined drastically during the last three decades as a result of improved treatment processes and better source control. To assess the concomitant temporal changes in the SMB sediments, a study was initiated in June 1997, in which 25 box cores were collected using a stratified random sampling design. Five sediment strata corresponding to the time intervals of 1890-1920, 1932-1963, 1965-1979, 1979-1989, and 1989-1997 were identified using 210Pb dating techniques. Samples from each stratum were analyzed for metals, 1,1,1-Trichloro-2,2-bis(p-chlorophenyl)ethane (DDT) and its metabolites (DDTs), polychlorinated biphenyls (PCBs), and total organic carbon (TOC). Samples from the 1965-1979, 1979-1989, and 1989-1997 strata were also analyzed for polycyclic aromatic hydrocarbons (PAHs) and linear alkylbenzenes (LABs). Sediment metal concentrations increased from 1890-1979 and were similar during the time intervals of 1965-1979, 1979-1989, and 1989-1997, although the mass emissions of trace metals from sewage inputs declined substantially during the same time period. Trace organic contamination in SMB was generally highest in sediments corresponding to deposition during the years of 1965-1979 or 1979-1989 and showed a decline in concentration in the 1989-1997 stratum. Temporal trends of contamination were greatest in sediments collected from areas near the Hyperion Treatment Plant (HTP) outfall system and on the slope of Redondo Canyon. The highest contaminant concentrations were present in sediments near the HTP 7-mile outfall in the 1965-1979 stratum. Elevated trace metal and organic concentrations were still present in the 1989-1997 stratum of most stations, suggesting that sediment contaminants have moved vertically in the sediment column since sludge discharges from the 7-mile outfall (a dominant source of contamination to the bay) ceased in 1987. The widespread distributions of DDTs and PCBs in SMB and highly confined distribution of LABs around the HTP outfall system were indicative of a dispersal mechanism remobilizing historically deposited contaminants to areas relatively remote from the point of discharge. ?? 2003 Elsevier Science Ltd. All rights reserved.

Marine Environmental Research↗

USGS1987

Oxidation of pyrite in an anoxic atmosphere

Pyrite (FeS 2 ) inclusions in coal, when heated in an oxygen deficient atmosphere (approximately 1% oxygen), become coated with magnetic Fe 3 O 4 due to oxidation. Most of the FeS 2 can thus be removed from the coal by magnetic separation to reduce the sulphur concentration. The oxidation products have been studied in greater detail by measuring the SO 2 and O 2 in the effluent gas during the heating process and by performing further magnetic measurements. At 582 K, the pyrite surface was oxidized to FeSO 4 . Significant oxidation of FeSO 4 and FeS 2 to Fe 3 O 4 was observed starting at 677 K. At about 681 K, the Fe 3 O 4 is further oxidized to α-Fe 2 O 3 . At 681 K, under isothermal conditions, the oxidation is impeded by the α-Fe 2 O 3 formed on the surfaces of the grains. If the temperature is rapidly increased, the oxygen penetrates the α-Fe 2 O 3 veneer to the FeS 2 core of the pyrite grains and oxidizes essentially the whole pyrite mass to Fe 3 O 4 before α-Fe 2 O 3 can be formed.

Fuel↗

USGS1977

Cell dimensions and antiferromagnetism of lunar and terrestrial ilmenite single crystals

X-Ray diffraction and anisotropic magnetic measurements have been made on single crystals of lunar ilmenite and on terrestrial ilmenite from Bancroft, Ontario, Canada and the Ilmen Mountains, U.S.S.R. The elongated c "> c -axis of lunar ilmenite, previously reported, is confirmed by new measurements. The shorter c "> c -axis found in terrestrial specimens is ascribed to Fe 3+ substitution for Ti 4+ in the titanium layer. Magnetic measurements on the same specimens show that, in agreement with the Ishikawa-Shirane et al . model, the initial shortening of the c "> c -axis by the above substitution of small amounts of Fe 3+ (<8%) causes an increase in Fe 2+ −Fe 2+ exchange coupling through Fe 3+ in the titanium layer that lowers the Néel transition temperature. The Weiss temperatures and other magnetic parameters confirm this model proposed by Ishikawa and Shirane et al . Additional transitions found in one of the terrestrial specimens (Bancroft) have been ascribed to a small amount of an exsolved spinel phase, possibly a solid solution phase of magnetite-ülvospinel. The spinel phase is localized in hematite-rich blebs which exsolved from the host ilmenite-rich phase.

Journal of Physics and Chemistry of Solids↗

USGS1977

Anisotropic magnetic susceptibility of erbium and ytterbium in zircon, ZrSiO4

Magnetic susceptibility measurements have been made for both Er- and Yb-doped (1̃0 3 ppm) zircon single crystals with the magnetic field perpendicular and parallel to the [001] axis. Large susceptibility anisotropies were found in both cases. Our observed anisotropies of ZrSiO 4 : Yb indicate small populations (1̃9%) of Yb ions at the axial (tetragonal) sites, as the susceptibility of ZrSiO 4 : Yb would be nearly isotropic if the Yb ions only occupied the orthorhombic sites. For Er 3+ in orthorhombic sites of zircon, our data indicate that the first excited state is paramagnetic with g x = 9 and g y 5̃ at 20 cm −1 above the ground state ( g x 0̃, g y 1̃5). The first excited state is quite similar to the ground states observed for Er 3+ in many host lattices

Journal of Physics and Chemistry of Solids↗

USGS1974

Antiferromagnetic inclusions in lunar glass

The magnetic susceptibility of 11 glass spherules from the Apollo 15, 16, and 17 fines and two specimens of a relatively large glass spherical shell were studied as a function of temperature from room temperature to liquid helium temperatures. All but one specimen showed the presence of antiferromagnetic inclusions. Closely spaced temperature measurements of the magnetic susceptibility below 77 K on five of the specimens showed antiferromagnetic temperature transitions (Néel transitions). With the exception of ilmenite in one specimen, these transitions did not correspond to any transitions in known antiferromagnetic compounds.

Earth and Planetary Science Letters↗