Geology topics
Publications and source records attributed to Colin A. Doolan.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean conventional resources of 12 million barrels of oil and 184 billion cubic feet of gas in the Buda Limestone of Texas.
Lithium (Li), classified as a critical mineral and key in energy storage applications because of its high energy density, faces unprecedented demand. This has driven interest in unconventional sources of Li, especially brines from sedimentary basins. Accordingly, the spatial distribution of basinal brinehosted Li resources across North America is becoming better defined, including the Williston Basin underlying Saskatchewan, Canada. This has led to growing investment and exploration by industry throughout the 2020s; however, despite this interest, the Li potential of basinal brines of the Williston Basin in North Dakota remain underexplored. This work presents the results from the 2025 joint brine sampling campaign between the North Dakota Geological Survey, the United States Geological Survey (USGS), and The University of Texas at Austin. Twenty-seven fluid samples were collected from producing oil and water source wells from eight stratigraphic intervals across western North Dakota and analyzed for major cation and anion concentrations. Similar to southeastern Saskatchewan, the highest Li concentrations were identified in the Devonian Duperow Formation, with concentrations up to 179 mg/L being observed in a well commingled between the Duperow and Red River Formations. Some samples from the overlying Birdbear Formation exceeded 75 mg/L, whereas Li concentrations were lower in the Madison Group (33-44 mg/L) and the Three Forks (50 mg/L), Dawson Bay (43 mg/L), Winnipegosis (23 mg/L), and Red River (40.0 mg/L) Formations. This work indicates Li resource potential exists across the Williston Basin and advances our understanding of the Li distribution in basinal brines which could provide a new domestic source of this critical mineral.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated undiscovered, technically recoverable mean resources of 5 million barrels of oil and 25 billion cubic feet of gas in conventional reservoirs and 361 million barrels of oil and 10,978 billion cubic feet of gas in continuous reservoirs in the Western Gulf Basin Province of the U.S. Gulf Coast region.
The Maverick Basin of south Texas is currently undergoing active exploration and production of gas and oil from tight sandstone reservoirs. The most productive tight sandstones in the basin are in the Upper Cretaceous San Miguel, Olmos, and Escondido Formations. These units are second only to the Eagle Ford Shale in terms of cumulative production volumes. The structural history of the Maverick Basin, from rifting to subsidence to exhumation, has had a profound effect on the characteristics of these reservoirs and the petroleum resources contained therein. This U.S. Geological Survey review of the production history of these strata reflects a recent shift from conventional production to horizontal drilling (unconventional) that exploits low permeability reservoirs in previously overlooked areas of existing oil and gas fields in southern Texas, typically outside of established field boundaries. To investigate the physical properties of the Maverick Basin hydrocarbon accumulations, this case study compiled American Petroleum Institute (API) gravity measurements and calculated cumulative gas/oil ratios (GOR) for thousands of producing wells from the San Miguel, Olmos, and Escondido Formations. Maps were generated from the compiled well production data to show the spatial heterogeneity of API gravity and GOR values for the three formations within the Maverick Basin and immediately outside the basin to the northeast. Within the Maverick Basin, the spatial patterns of API gravity values indicate lighter oils downdip towards the southern basin edge. GOR values indicative of wet and dry gases within the basin are seen interspersed, with values that correspond to black and heavy oils. Differences in the spatial patterns of the petroleum properties within the Maverick Basin are interpreted as effects of Eocene basin inversion caused by Laramide orogenic deformation, and the resulting reservoir exhumation of basin strata. East of the Maverick Basin, spatial distributions of API gravity and GOR values show progressively heavier oils updip to the northwest, grading to dry gases downdip to the southeast, which correlates to the oil and gas windows of the underlying Eagle Ford Shale. Correlation of API gravity and GOR values from the San Miguel, Olmos, and Escondido Formations with thermal maturity data from the Eagle Ford Shale suggests that the Eagle Ford Shale is the petroleum source, and that petroleum migration was approximately vertical for areas to the east of the Maverick Basin. The discontinuity of API gravity and GOR properties within the Maverick Basin implies a complex petroleum charge history, possibly involving the remigration of petroleum and the addition of petroleum from other source intervals in Mexico, to the southwest. Depressurization of exhumed, overpressured reservoirs of the San Miguel, Olmos, and Escondido Formations can explain the intermittent occurrence of gas production throughout the southern Maverick Basin by exsolution of gas from formation brines and the resulting dry gas flushing of hydrocarbon-charged reservoirs. The introduction of dry gas through flushing can, in turn, explain why the patterns of API gravity and GOR values are so dissimilar in the Maverick Basin. This process has implications for possible future production of unconventional resources from undiscovered tight-gas reservoirs in strata of the San Miguel, Olmos, and Escondido Formations, and a different approach to petroleum exploration may be needed in the Maverick Basin relative to exploration techniques applied in other basins within the northern Gulf of Mexico.
Global demand for lithium, the primary component of lithium-ion batteries, greatly exceeds known supplies, and this imbalance is expected to increase as the world transitions away from fossil fuel energy sources. High concentrations of lithium in brines have been observed in the Smackover Formation in southern Arkansas (>400 milligrams per liter). We used published and newly collected brine lithium concentration data to train a random forest machine-learning model using geologic, geochemical, and temperature explanatory variables and create a map of predicted lithium concentrations in Smackover Formation brines across southern Arkansas. Using these predicted lithium maps with reservoir parameters and geologic information, we calculated that there are 5.1 to 19 million tons of lithium in Smackover Formation brines in southern Arkansas, which represents 35 to 136% of the current US lithium resource estimate. Based on these calculations, in 2022, 5000 tons of dissolved lithium were brought to the surface within brines as waste streams of the oil, gas, and bromine industries.
In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources available if current carbon dioxide enhanced oil recovery (CO 2 -EOR) technologies were applied to amenable oil reservoirs underlying the onshore and State waters areas of the conterminous United States. The assessment also includes estimates of the mass of CO 2 that could be stored (retained) as a result of CO 2 -EOR activities. The USGS assessment team evaluated more than 3,500 oil reservoirs that were miscible to injected CO 2 . The assessed reservoirs are in 185 previously defined USGS plays in 33 petroleum provinces of 7 national regions. The assessment team estimated that the technically recoverable oil associated with CO 2 -EOR ranges from approximately 25,000 million barrels (MMbbl) at the P 5 percentile to as much as 32,000 MMbbl at the P 95 percentile, with a mean of 29,000 MMbbl. The associated CO 2 retention ranges from approximately 7,400 million metric tons (Mt) at the P 5 percentile to as much as 9,500 Mt at the P 95 percentile, with a mean of 8,400 Mt. The West Texas and Eastern New Mexico region and the Gulf Coast region together contain 60 percent of the mean assessed CO 2 -EOR oil potential and 61 percent of the mean assessed CO 2 retention. Other regions with significant resource potential include the Midcontinent region and Rocky Mountains and Northern Great Plains region.
Introduction In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources that might be produced by using current carbon dioxide enhanced oil recovery (CO 2 -EOR) technologies in amenable conventional oil reservoirs underlying the onshore and State waters areas of the conterminous United States. The assessment also includes estimates of the mass of CO 2 that could be stored (retained) in the assessed oil reservoirs following the application of the CO 2 -EOR process. The USGS assessment team evaluated more than 3,500 oil reservoirs that were miscible to injected CO 2 . The assessed reservoirs are in 185 previously defined USGS plays in 33 petroleum provinces of 7 national regions. The team estimated that the total technically recoverable oil resulting from the application of the CO 2 -EOR process ranges from approximately 25,000 million barrels (MMbbl) at the P 5 percentile to as much as 32,000 MMbbl at the P 95 percentile, with a mean of 29,000 MMbbl. The associated CO 2 retention ranges from approximately 7,400 million metric tons (Mt) at the P 5 percentile to as much as 9,500 Mt at the P 95 percentile, with a mean of 8,400 Mt. The results are summarized in this fact sheet and are provided in more detail in the companion data release and circular. The West Texas and Eastern New Mexico region (primarily its Permian Basin) and the Gulf Coast region together contain 60 percent of the mean assessed CO 2 -EOR oil potential and 61 percent of the mean assessed CO 2 retention. Other regions with significant resource potential include the Midcontinent region and the Rocky Mountains and Northern Great Plains region.
In 2020, the U.S. Geological Survey (USGS) completed a probabilistic assessment of the volume of technically recoverable oil resources that could be produced using current carbon dioxide enhanced oil recovery (CO2-EOR) technologies in amenable conventional oil reservoirs underlying onshore and State-owned offshore waters (herein after, onshore and State waters areas) of the conterminous United States. Our assessment also includes estimates of the mass of CO2 that could be stored (retained) in the assessed oil reservoirs following the application of the CO2-EOR process. The USGS assessment team evaluated more than 3,500 oil reservoirs that were amenable to miscible CO2 injection. The assessed reservoirs are located in 185 plays previously defined by a USGS National Oil and Gas Assessment in 33 petroleum provinces of seven national regions. The team estimated that the total technically recoverable oil resulting from the application of the CO2-EOR process ranges from approximately 25,000 million barrels (MMbbl) at the P5 probability percentile to as much as 32,000 MMbbl at the P95 probability percentile, with a mean of 29,000 MMbbl. The associated CO2 retention ranges from approximately 7,400 million metric tons (Mt) at the P5 percentile to as much as 9,500 Mt at the P95 percentile, with a mean of 8,400 Mt.
Tracing produced water origins from wells hydraulically fractured with freshwater-based fluids is sometimes predicated on assumptions that (1) each geological formation contains compositionally unique brine and (2) produced water from recently hydraulically fractured wells resembles fresher meteoric water more so than produced water from older wells. These assumptions are not valid in Williston Basin oil wells sampled in this study. Although distinct average 228 Ra/ 226 Ra ratios were found in water produced from the Bakken and Three Forks Formations, average δ 2 H, δ 18 O, specific gravity, and conductivity were similar but exhibited significant variability across five oil fields within each formation. Furthermore, initial produced water (“flowback”) was operationally defined based on the presence of glycol ether compounds and water from wells that had produced <56% of the amount of fluids injected and sampled within 160 days of fracturing. Flowback unexpectedly exhibited higher temperature, specific gravity, conductivity, δ 2 H, and δ 18 O, but lower oxidation–reduction potential and δ 11 B, relative to the wells thought to be producing formation brines (from wells with a produced-to-injected water ratio [PIWR] > 0.84 and sampled more than 316 days after fracturing). As such, establishing an overall geochemical and isotopic signature of produced water compositions based solely on chemical similarity to meteoric water and formation without the consideration of well treatments, well completion depth, or lateral location across the basin could be misleading if these signatures are assumed to be applicable across the entire basin. These findings have implications for using produced water compositions to understand the interbasin fluid flow and trace sources of hydraulic fracturing fluids.
The Utica and Marcellus Shale Plays in the Appalachian Basin are the fourth and first largest natural gas producing plays in the United States, respectively. Hydrocarbon production generates large volumes of brine (“produced water”) that must be disposed of, treated, or reused. Though Marcellus brines have been studied extensively, there are few studies from the Utica Shale Play. This study presents new brine chemical analyses from 16 Utica Shale Play wells in Ohio and Pennsylvania. Results from Na–Cl–Br systematics and stable and radiogenic isotopes suggest that the Utica Shale Play brines are likely residual pore water concentrated beyond halite saturation during the formation of the Ordovician Beekmantown evaporative sequence. The narrow range of chemistry for the Utica Shale Play produced waters (e.g., total dissolved solids = 214–283 g/L) over both time and space implies a consistent composition for disposal and reuse planning. The amount of salt produced annually from the Utica Shale Play is equivalent to 3.4% of the annual U.S. halite production. Utica Shale Play brines have radium activities 580 times the EPA maximum contaminant level and are supersaturated with respect to barite, indicating the potential for surface and aqueous radium hazards if not properly disposed of.
Waters co-produced during petroleum extraction are the largest waste stream from oil and gas development. Reuse or disposal of these waters is difficult due to their high salinities and the sheer volumes generated. Produced waters may also contain valuable mineral commodities. While an understanding of produced water trace element composition is required for evaluating the associated resource and waste potential of these materials, measuring trace elements in brines is challenging due to the dilution requirements of typical methods. Alternatively, inductively coupled plasma-optical emission spectrometry (ICP-OES) has shown promise as being capable of direct measurements of trace elements within produced waters with minimal dilution. Here we evaluate direct ICP-OES trace element quantification in produced waters for 17 trace elements (As, Al, Ba, Be, Cd, Cr, Co, Cu, Hg, Mo, Ni, Pb, Rb, Sb, U, V, and Zn) within 15 produced waters from five U.S. continuous reservoirs. The ICP-OES results are compared against trace element levels determined using inductively coupled plasma-mass spectrometry from the same samples. Our results demonstrate the potential for direct analysis of high salinity waters using ICP-OES with minimal dilution and provide trace element concentrations in waters from several important U.S. petroleum-generating reservoirs where available data is sparse.
The lower Eagle Ford Group (LEFG) is one of the most productive continuous hydrocarbon plays in the United States but few associated produced waters data and minimal interpretation have been published. This effort focuses on results from compositional and isotopic data from 39 produced water samples collected from horizontal wells producing from the LEFG in south central Texas. The depth of the LEFG increases by approximately 1 km across the study area, from northwest (2.9 km) to southeast (3.9 km). Associated increases in calculated reservoir temperature (125-165 C), development of reservoir over-pressuring (400-800 bars total pressure), and increased thermal maturity (heavy oil to gas condensate) also occur along this trend. Produced water salinity starts at nearly 100 g/L in the shallowest samples and decreases linearly with depth to <35 g/L. Comparison of Br/Cl and ⁸⁷Sr/⁸⁶Sr data between LEFG produced waters and the Louann salt, suggests that halite recycling is the mechanism behind salinity greater than seawater. Decreasing salinity with depth and thermal maturity in the Gulf Coast Basin have previously been shown to be a result of release of inter-layer water during smectite to illite conversion. The produced water samples show increasing 18O and decreasing 2H with depth, which is attributed temperature-dependent isotope fractionation of O and H exchange between seawater and clays and calcite with increasing temperature. Multiple sources of data indicate that the waters in the LEFG are not connate, but rather entered the unit prior to smectite-illite conversion. Presence of allochthonous water in many major tight oil and shale gas plays in the U.S., including the LEFG, suggests there is unknown mechanism allowing for water advection into low permeability reservoirs.
The organic composition of produced waters (flowback and formation waters) from the middle member of the Bakken Formation and the Three Forks Formation in the Williston Basin, North Dakota were examined to aid in the remediation of surface contamination and help develop treatment methods for produced-water recycling. Twelve produced water samples were collected from the Bakken and Three Forks Formations and analyzed for non-purgeable dissolved organic carbon (NPDOC), acetate, and extractable hydrocarbons. NPDOC and acetate concentrations from sampled wells from ranged from 33-190 milligrams per liter (mg/L) and 16-40 mg/L, respectively. Concentrations of individual extractable hydrocarbon compounds ranged from less than 1 to greater than 400 micrograms per liter (µg/L), and included polycyclic aromatic hydrocarbons (PAHs), phenolic compounds, glycol ethers, and cyclic ketones. While the limited number of samples, varying well production age, and lack of knowledge of on-going well treatments complicate conclusions, this report aids adds to the limited knowledge of organics in produced waters from the Bakken and Three Forks Formations.
The U.S. Geological Survey (USGS) is preparing a national resource assessment of the potential hydrocarbons recoverable after injection of carbon dioxide (CO2) into conventional oil reservoirs in the United States. The implementation of CO2-enhanced oil recovery (CO2-EOR) techniques can increase hydrocarbon production, and lead to incidental retention of CO2 in reservoir pore space allowing long-term storage of anthropogenic CO2. A Comprehensive Resource Database (CRD) containing proprietary data on location, geologic, petrophysical, and reservoir parameters, plus production and well counts for major oil and gas reservoirs in onshore areas and State waters of the conterminous United States and Alaska, was developed to support the USGS assessment. Residual oil zones (ROZs) also can provide potential pore space for long-term storage of anthropogenic CO2. However, ROZs are not included in the upcoming USGS national CO2-EOR assessment because assessment methods for ROZs still are being developed. Additional ROZ CO2-EOR and CO2 retention data and reservoir simulations are needed to calibrate national ROZ assessment estimates.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean undiscovered, technically recoverable conventional resources of 100 million barrels of oil and 16.5 trillion cubic feet of gas in the downdip Paleogene formations in onshore lands and State waters of the U.S. Gulf Coast region.
Using a geology-based assessment methodology, the U.S. Geological Survey estimated mean undiscovered, technically recoverable continuous resources that total 464 million barrels of oil and 4.08 trillion cubic feet of gas in the Lower Mississippian Sunbury Shale and Middle Devonian–Lower Mississippian Chattanooga Shale of the Appalachian Basin Province.
The 2007 Energy Independence and Security Act (Public Law 110–140) directs the U.S. Geological Survey (USGS) to conduct a national assessment of potential geologic storage resources for carbon dioxide (CO2). The methodology used by the USGS for the national CO2 assessment follows up on previous USGS work. The methodology is non-economic and intended to be used at regional to subbasinal scales. This report identifies and contains geologic descriptions of 14 storage assessment units (SAUs) in Ordovician to Upper Cretaceous sedimentary rocks within the Greater Green River Basin (GGRB) of Wyoming, Colorado, and Utah, and eight SAUs in Ordovician to Upper Cretaceous sedimentary rocks within the Wyoming-Idaho-Utah Thrust Belt (WIUTB). The GGRB and WIUTB are contiguous with nearly identical geologic units; however, the GGRB is larger in size, whereas the WIUTB is more structurally complex. This report focuses on the characteristics, specified in the methodology, that influence the potential CO2 storage resource in the SAUs. Specific descriptions of the SAU boundaries, as well as their sealing and reservoir units, are included. Properties for each SAU, such as depth to top, gross thickness, porosity, permeability, groundwater quality, and structural reservoir traps, are typically provided to illustrate geologic factors critical to the assessment. This geologic information was employed, as specified in the USGS methodology, to calculate a probabilistic distribution of potential storage resources in each SAU. Figures in this report show SAU boundaries and cell maps of well penetrations through sealing units into the top of the storage formations. The cell maps show the number of penetrating wells within one square mile and are derived from interpretations of variably attributed well data and a digital compilation that is known not to include all drilling.
This report presents fourteen storage assessment units (SAUs) from the Alaska North Slope and two SAUs from the Kandik Basin of Alaska. The Alaska North Slope is a broad, north-dipping coastal plain that is underlain by a thick succession of sedimentary rocks that accumulated steadily throughout much of the Phanerozoic during three major tectonic sequences: the Mississippian through Triassic Ellesmerian sequence, the Jurassic through Lower Cretaceous Beaufortian sequence, and the Cretaceous and Tertiary Brookian sequence. Stratigraphic packages associated with all three of these tectonic sequences are suited to geologic carbon dioxide (CO 2 ) sequestration. The lower part of the Ellesmerian sequence contains five potential SAUs, two of which have reservoirs within the Endicott Group and three of which have reservoirs within the Lisburne Group. Another potential SAU has sandstone-prone reservoir units interbedded with the upper part of the Ellesmerian Shublik Formation and the Beaufortian Kingak Shale. The Brookian sequence contains eight potential SAUs that have reservoirs that are defined by the various Cretaceous and Tertiary deltaic topset strata of the Colville foreland basin as well as associated slope aprons and submarine turbidite fan complexes. In east-central Alaska, Kandik Basin is an extension of cratonic North America and straddles the border between Alaska and Canada. The basin contains a section of Neoproterozoic to Mesozoic rocks, which have been multiply deformed during the Phanerozoic. Paleozoic strata within the basin appear to be suited to geologic CO 2 sequestration. We defined two SAUs within this interval, which are the Upper Devonian and Mississippian Nation River Formation SAU and the Lower Permian to Lower Cretaceous Step Conglomerate and Tahkandit Limestone SAU. For each SAU in both of the basins, we discuss the areal distribution of suitable CO 2 sequestration reservoir rock. We also characterize the overlying sealing unit and describe the geologic characteristics that influence the potential CO 2 storage volume and reservoir performance. These characteristics include reservoir depth, gross thickness, net thickness, porosity, permeability, and groundwater salinity. Case-by-case strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are presented. Although assessment results are not contained in this report, the geologic information included herein was employed to calculate the potential storage volume in the various SAUs. Lastly, in this report, we present the rationale for not conducting assessment work in fifteen sedimentary basins distributed across the Alaskan interior and within Alaskan State waters.