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Christopher Pearson

Publications and source records attributed to Christopher Pearson.

6 recordsLinked to original sources

Global performance of remote sensing-based and reanalysis-driven models to estimate open water evaporation

Evaporation plays an essential role in the water cycle, influencing local and regional climates while directly impacting water availability in lakes. However, directly measuring evaporation over water bodies remains challenging due to the high costs of installing and maintaining the required in situ instrumentation. Although several remote sensing algorithms have been providing evaporation estimates, the lack of a global validation hinders our understanding of their relative uncertainties and performances across different regions. Here, we analyze the performance of a suite of models that leverage satellite data and meteorological reanalysis to estimate evaporation over lakes worldwide. We compare 3 remote sensing-based models, 1 reanalysis-driven model and 1 ensemble approach, using in situ observations from 27 lakes representing a diverse range of geographic and climatic regions. Our results demonstrate that, overall, the ensemble outperformed any individual model in terms of accuracy, with a RMSE and a bias of 1.3 and 0.3 mm day −1 , respectively. These findings highlight the benefits of using an ensemble approach to estimate open water evaporation with satellite-based models at the global scale, leveraging the unique strengths of each model. For the individual models, differences in the representation of heat storage changes and advection effects led to lower values of RMSE and bias, depending on the location and depth of the lakes. This study sets the path for future improvement of open water evaporation algorithms globally, while remote sensing techniques are proven satisfactory to monitoring of water loss in lakes globally, an essential step toward effective large-scale water resources management.

Water Resources Research↗

Assessing the accuracy of OpenET satellite-based evapotranspiration data to support water resource and land management applications

Remotely sensed evapotranspiration (ET) data offer strong potential to support data-driven approaches for sustainable water management. However, practitioners require robust and rigorous accuracy assessments of such data. The OpenET system, which includes an ensemble of six remote sensing models, was developed to increase access to field-scale (30 m) ET data for the contiguous United States. Here we compare OpenET outputs against data from 152 in situ stations, primarily eddy covariance flux towers, deployed across the contiguous United States. Mean absolute error at cropland sites for the OpenET ensemble value is 15.8 mm per month (17% of mean observed ET), mean bias error is −5.3 mm per month (6%) and r 2 is 0.9. Results for shrublands and forested sites show higher inter-model variability and lower accuracy relative to croplands. High accuracy and multi-model convergence across croplands demonstrate the utility of a model ensemble approach, and enhance confidence among ET data practitioners, including the agricultural water resource management community.

Nature Water↗

Development of a benchmark eddy flux evapotranspiration dataset for evaluation of satellite-driven evapotranspiration models over the CONUS

A large sample of ground-based evapotranspiration (ET) measurements made in the United States, primarily from eddy covariance systems, were post-processed to produce a benchmark ET dataset. The dataset was produced primarily to support the intercomparison and evaluation of the OpenET satellite-based remote sensing ET (RSET) models and could also be used to evaluate ET data from other models and approaches. OpenET is a web-based service that makes field-delineated and pixel-level ET estimates from well-established RSET models readily available to water managers, agricultural producers, and the public. The benchmark dataset is composed of flux and meteorological data from a variety of providers covering native vegetation and agricultural settings. Flux footprint predictions were developed for each station and included static flux footprints developed based on average wind direction and speed, as well as dynamic hourly footprints that were generated with a physically based model of upwind source area. The two footprint prediction methods were rigorously compared to evaluate their relative spatial coverage. Data from all sources were post-processed in a consistent and reproducible manner including data handling, gap-filling, temporal aggregation, and energy balance closure correction. The resulting dataset included 243,048 daily and 5,284 monthly ET values from 194 stations, with all data falling between 1995 and 2021. We assessed average daily energy imbalance using 172 flux sites with a total of 193,021 days of data, finding that overall turbulent fluxes were understated by about 12% on average relative to available energy. Multiple linear regression analyses indicated that daily average latent energy flux may be typically understated slightly more than sensible heat flux. This dataset was developed to provide a consistent reference to support evaluation of RSET data being developed for a wide range of applications related to water accounting and water resources management at field to watershed scales.

continental United States↗

A synthesis of terrestrial mercury in the western United States: Spatial distribution defined by land cover and plant productivity

A synthesis of published vegetation mercury (Hg) data across 11 contiguous states in the western United States showed that aboveground biomass concentrations followed the order: leaves (26 μg kg − 1 ) ~ branches (26 μg kg − 1 ) > bark (16 μg kg − 1 ) > bole wood (1 μg kg − 1 ). No spatial trends of Hg in aboveground biomass distribution were detected, which likely is due to very sparse data coverage and different sampling protocols. Vegetation data are largely lacking for important functional vegetation types such as shrubs, herbaceous species, and grasses. Soil concentrations collected from the published literature were high in the western United States, with 12% of observations exceeding 100 μg kg − 1 , reflecting a bias toward investigations in Hg-enriched sites. In contrast, soil Hg concentrations from a randomly distributed data set (1911 sampling points; Smith et al., 2013a) averaged 24 μg kg − 1 (A-horizon) and 22 μg kg − 1 (C-horizon), and only 2.6% of data exceeded 100 μg kg − 1 . Soil Hg concentrations significantly differed among land covers, following the order: forested upland > planted/cultivated > herbaceous upland/shrubland > barren soils. Concentrations in forests were on average 2.5 times higher than in barren locations. Principal component analyses showed that soil Hg concentrations were not or weakly related to modeled dry and wet Hg deposition and proximity to mining, geothermal areas, and coal-fired power plants. Soil Hg distribution also was not closely related to other trace metals, but strongly associated with organic carbon, precipitation, canopy greenness, and foliar Hg pools of overlying vegetation. These patterns indicate that soil Hg concentrations are related to atmospheric deposition and reflect an overwhelming influence of plant productivity — driven by water availability — with productive landscapes showing high soil Hg accumulation and unproductive barren soils and shrublands showing low soil Hg values. Large expanses of low-productivity, arid ecosystems across the western U.S. result in some of the lowest soil Hg concentrations observed worldwide.

Science of the Total Environment↗

Focused ion beam and field-emission microscopy of metallic filaments in memory devices based on thin films of an ambipolar organic compound consisting of oxadiazole, carbazole, and fluorene units

We report on the mechanism of operation of organic thin film resistive memory architectures based on an ambipolar compound consisting of oxadiazole, carbazole, and fluorene units. Cross-sections of the devices have been imaged by electron microscopy both before and after applying a voltage. The micrographs reveal the growth of filaments, with diameters of 50 nm–100 nm, on the metal cathode. We suggest that these are formed by the drift of aluminium ions from the anode and are responsible for the observed switching and negative differential resistance phenomena in the memory devices.

Applied Physics Letters↗

Control of droplet morphology for inkjet-printed TIPS-pentacene transistors

We report on methods to control the morphology of droplets of 6,13-bis(triisopropyl-silylethynyl) pentacene (TIPS-PEN), which are then used in the fabrication of organic thin film transistors (OTFTs). The grain size and distribution of the TIPS-PEN were found to depend on the temperature of the droplets during drying. The performance of the OTFTs could be improved by heating the substrate and also by changing the relative positions of the inkjet-printed droplets. In our experiments, the optimum substrate temperature was 46 °C in air. Transistors with the TIPS-PEN grain boundaries parallel to the current flow between the source and drain electrodes exhibited charge carrier mobilities of 0.44 ± 0.08 cm 2 /V s.

Microelectronic Engineering↗