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Christina A. DeVera

Publications and source records attributed to Christina A. DeVera.

At least 19 recordsLinked to original sources

Stories in stone: The geoheritage significance of U.S. National Park Service stratotypes

The U.S. National Park Service stratotype inventory has systematically documented hundreds of published stratotypes across the country that represent a quintessential component of America’s geoheritage and possess significant scientific, educational, cultural, historic, and aesthetic values. As valuable geologic reference standards, stratotypes record intervals of Earth history relating to our nation’s unique geologic evolution, biological progression, cultural traditions, historical narratives, and stunning landforms. However, the general lack of awareness and knowledge regarding the scope, significance, distribution, and scale of stratotypes can result in these resources being overlooked. Consequently, stratotypes may inadvertently experience accidental alteration, damage, or destruction through both natural and anthropogenic processes. As with many American geoheritage sites, stratotypes lack specific recognition through legislation, policies, or other management strategies to ensure their preservation and protection. Through education and outreach, we hope to inform, increase awareness, and engage the public about these internationally and nationally significant geologic reference sites, unite various geoheritage communities, and promote their preservation for future generations.

Geoheritage↗

Chemostratigraphy of the Cretaceous Hue Shale in Arctic Alaska: Exploring paleoceanographic controls on trace element enrichment, organic matter accumulation, and source-rock evolution

We document chemostratigraphy in an outcrop of late Albian to early Campanian (∼103–82 Ma) marine source rocks to better understand paleoenvironmental controls on trace element (TE) enrichment and organic matter accumulation in the distal Colville foreland basin of Arctic Alaska and how those drivers are linked to arc volcanism and successions of Cretaceous oceanographic and climatic biogeochemical events. This unique, 113-m-thick section of Cretaceous Hue Shale deposited during a series of previously undocumented Arctic Cretaceous oceanic anoxic events (Lease et al., 2024) is the only known exposure of thermally immature (0.48–0.52% R o , random vitrinite reflectance) Hue Shale in Arctic Alaska. Strata comprise mainly clay-rich mudstone with elevated total organic carbon (TOC) and hydrogen index values reaching 26.3 wt% (mean = 7.5 wt%) and 689 mg hydrocarbon (HC)/g TOC (mean = 385 mg HC/g TOC), respectively. Maceral composition consists predominantly of fluorescent amorphous organic matter, with abundant brightly fluorescent alginite, including Tasmanites , acritarchs, and Leiosphaeridia . Discrete layers of volcanic ash (preserved as bentonite) are present throughout the section and provide quantitative age control based on U–Pb dates. Chemostratigraphic trends are investigated to advance our understanding of local oceanographic conditions and controls on stratigraphic and temporal heterogeneity of Brookian source rocks. Concurrent sedimentary enrichment in Mo, U, V, Pb, and Cu across the Albian–Cenomanian boundary of the exposed basal gamma-ray zone, may reflect anoxic to euxinic benthic redox conditions favoring organic matter accumulation and preservation. Fluctuating degrees of anoxia-euxinia are inferred throughout the overlying Hue Shale succession, reflected by varying patterns of TE enrichment and TE–TOC covariation. Elevated C org /P molar ratios (>250) across most of the section, with several values exceeding 690, signify that enhanced biological productivity is sustained throughout deposition. Enhanced productivity, recorded by both C org /P and excess Ba, also parallels increases in source rock richness (elevated TOC and S 2 values) during the late Albian–early Cenomanian and late Cenomanian – Turonian. Enhanced productivity and variations in oceanic circulation/stratification likely both drove changes in benthic redox conditions that favored organic carbon accumulation and preservation. Increased continental arc volcanism (e.g., Okhotsk–Chukotka volcanic belt) and High Arctic Large Igneous Province magmatic eruptions throughout the Cretaceous, inferred to have influenced nutrient cycling and local aqueous nutrient availability, also have been invoked as potential drivers of organic carbon burial and source-rock development across the sedimentary sequence. Results presented here document the organic-rich and oil-prone source-rock quality of the Hue Shale in the distal part of the Colville foreland basin and bolster the potential for a Cretaceous petroleum system beneath the eastern North Slope.

Alaska↗

U.S. Geological Survey geoheritage sites of the nation: Broadening the relevance of geologic mapping through the intersection of geology and society

Geoheritage lies at the intersection of geology and society (NASEM 2021). It is a value-laden term applied to geologically significant features and landforms to highlight the scientific, educational, cultural, economic, and aesthetic values that society places on them (Brilha 2018, GSA 2017, NPS and AGI 2015). The U.S. Geological Survey (USGS) National Cooperative Geologic Mapping Program (NCGMP) proposed the development of a geoheritage geospatial product (GGP) to broaden the relevance of geologic mapping to stakeholders within the scientific community and the public (Shelton et al. 2022). To accomplish this, the USGS Geoheritage Sites of the Nation project was initiated to design the GGP and build a geoheritage site inventory to showcase geodiversity and natural heritage throughout the United States and its territories to accompany the seamless 2D and 3D geologic map and model being developed by the NCGMP and its partners (DeVera et al. 2022). The GGP serves as an educational and outreach tool to 1) raise awareness of significant geologic sites, 2) communicate the role of geology in our natural heritage, and 3) increase accessibility and relevance of geologic mapping and geoscience topics more broadly to the public (DeVera et al. 2023b).

Conference Paper↗

Facies variation within outcrops of the Triassic Shublik Formation, northeastern Alaska

The Shublik Formation (Middle to Upper Triassic) is a heterogeneous unit that is a major hydrocarbon source rock in northern Alaska and the largest known Triassic phosphate accumulation in the world. This formation, which occurs in the subsurface and crops out within the Arctic Alaska basin, was deposited on a gently sloping ramp along the northwestern Laurentian margin. In this study, we document spatial and temporal facies variations within the Shublik and the overlying Karen Creek Sandstone (Upper Triassic) through 19 outcrop localities in the northeastern Brooks Range. New organic and inorganic geochemical data from these localities support and extend our sedimentologic and petrographic findings. The petrographic data come from an analysis of more than 900 thin sections, whereas age constraints come mainly from species of the pelecypod genera Daonella , Halobia , Eomonotis , and Monotis . Thirteen sites make up a main outcrop belt within which facies of the Shublik are spatially consistent but show marked vertical changes. Six additional outcrops located south of the main belt contain more distal facies of the Shublik that accumulated farther from land. Exposures of the Shublik Formation in its main outcrop belt are divisible into five informal lithologic units, each of which formed during a distinct transgressive to regressive sequence. The basal unit of the Shublik (Anisian? to Ladinian; Middle Triassic) is quartz siltstone to very fine grained sandstone that is locally phosphatic. The three middle units (Ladinian to middle Norian; Middle to Upper Triassic) contain various proportions of siliciclastic, carbonate, phosphatic, and organic material. The uppermost unit (middle to upper Norian; Upper Triassic) is mainly shale and mudstone. Highly phosphatic strata (10–34 percent phosphorus pentoxide) are chiefly Ladinian and lower to middle Norian. Highly phosphatic Ladinian strata have been transported, are granular, and formed during transgression and early regression. In contrast, highly phosphatic Norian strata include event beds and hardgrounds, contain displaced and in situ phosphate peloids and nodules, and cap regressive parasequences. The total organic content reaches 4.97 weight percent in the main belt and is highest in muddy beds, which are found mainly in the lower parts of the three middle units. Distal sections of the Shublik are typically finer grained, more organic-rich (total organic content as high as 6.33 weight percent), and less fossiliferous than those in the main belt. Both temporal and spatial factors shaped facies in the Shublik Formation. Shublik strata accumulated at a time of reduced tectonic activity in Arctic Alaska, resulting in diminished siliciclastic input. Marine upwelling along the northwestern Laurentian margin facilitated the development of heterozoan carbonates, as well as local concentrations of phosphatic and organic matter. Large- and small-scale eustatic cycles also affected this margin and provided further controls on Shublik facies distribution.

Alaska↗

Arctic Alaska deepwater organic carbon burial and environmental changes during the late Albian–early Campanian (103–82 Ma)

The middle Cretaceous greenhouse period experienced profound environmental change including episodes of enhanced global burial of organic carbon marked by carbon isotopic excursions (CIEs). However, the role and response of polar regions like the newly formed, partially enclosed Arctic Ocean Basin during middle Cretaceous carbon burial remains enigmatic. We present the first Arctic deepwater CIE record that characterizes conditions offshore of the Alaska margin north of 75°N paleolatitude. Organic carbon isotopes (δ 13 C org ) and 103–82 Ma ash zircon U-Pb dates from the distal Hue Shale record multiple Albian–Campanian CIEs during slow ∼3–15 m/Myr sediment accumulation rates. Average total organic carbon (TOC) increased substantially during large 2–3 ‰ CIEs of the ∼101 Ma Albian-Cenomanian boundary event (from 7 to 18 % TOC) and ∼94 Ma Cenomanian-Turonian boundary event (5 to 10 % TOC). Turonian TOC remained elevated (8–13 %) during high global sea levels and temperatures of the Cretaceous Thermal Maximum, followed by an increase from 7 to 11 % TOC during the ∼90 Ma late Turonian event 1.5 ‰ CIE. Average TOC subsequently decreased in the Coniacian–Campanian, but relative maxima occurred during subtle 0.5–1 ‰ CIEs interpreted as the ∼87 Ma late Coniacian event (increase from 4 to 7 % TOC), ∼85 Ma Horseshoe Bay event (3.5 to 4.5 % TOC), and ∼84 Ma Santonian-Campanian boundary event (3.5 to 5 % TOC). Increases in hydrogen index and productivity proxies (P, Ba, Nd) that accompanied each CIE episode with enhanced TOC suggest a strong link between marine productivity and organic carbon burial at short-term CIE timescales. However, long-term (>5–8 Myr) changes in trace metal redox (Mo, Fe, V) and salinity (B/Ga) proxies suggest shifts in prevailing environmental conditions at timescales longer than the CIEs. Late Albian–middle Turonian marine salinity occurred during euxinic (103–98 Ma) and suboxic (98–90 Ma) conditions with deposition interpreted to have occurred within and beneath an oxygen minimum zone, respectively. In contrast, late Turonian–early Campanian (90–82 Ma) freshening and restricted euxinic basin conditions may signal the start of widespread restriction known to characterize the Paleogene Arctic. Overall, these results highlight that middle Cretaceous Arctic deepwater remained a productive marine carbon sink coupled to the global carbon cycle despite evolving Arctic greenhouse conditions.

Alaska↗

Produced water geochemistry from hydraulically stimulated Niobrara Formation petroleum wells: Origin of salinity and temporal perspectives on treatment and reuse

Produced water (i.e., a mixture of returned injection fluids and geologic formation brines) represents the largest volumetric waste stream associated with petroleum production in the United States. As such, produced water has been the focus of intense study with emphasis on understanding the geologic origin of the fluids, environmental impacts of unintended or intentional release, disposal concerns, and their commodity (e.g., lithium) potential. However, produced water geochemistry from many active petroleum plays remain poorly constrained leading to knowledge gaps associated with the origin of brine salinity and parameters (e.g., radium levels) that can impact treatment, disposal, and possible reuse. Here we evaluate the major ion geochemistry, radium concentrations, and stable water isotope composition of ~120 produced water samples collected from 17 producing unconventional petroleum wells in Weld County, Colorado from the Late Cretaceous Niobrara Formation. This sample set encompasses eight produced water time series from four new wells across production days 0 to ~365 and from four established wells across production days ~1000 to ~1700. Additionally, produced water from nine other established Niobrara Formation wells were sampled at discrete time points ranging from day 458 to day 2256, as well as hydraulic fracturing input fluids. These results expand the available Niobrara Formation produced water geochemical data, previously limited to few wells sampled within the first year of production, allowing for the heterogeneity of major ions and radium to be evaluated. Furthermore, we explore the geochemical relationships between major ion ratios and stable water isotope composition to understand the origin of salinity in Niobrara Formation brines from the Denver-Julesburg Basin. These findings are discussed with perspective toward potential treatment and reuse of Niobrara produced water prior to disposal.

Colorado, Nebraska, Wyoming↗

Repetitive sampling and control threshold improve 16S rRNA results from produced waters associated with hydraulically fractured shales

Sequencing microbial DNA from deep subsurface environments is complicated by a number of issues ranging from contamination to non-reproducible results. Many samples obtained from these environments - which are of great interest due to the potential to stimulate microbial methane generation - contain low biomass. Therefore, samples from these environments are difficult to study as sequencing results can be easily impacted by contamination. In this case, the low amount of sample biomass may be effectively swamped by the contaminating DNA and generate misleading results. Additionally, performing field work in these environments can be difficult, as researchers generally have limited access to and time on site. Therefore, optimizing a sampling plan to produce the best results while collecting the greatest number of samples over a short period of time is ideal. This study aimed to recommend an adequate sampling plan for field researchers obtaining microbial biomass for 16S rRNA gene sequencing, applicable specifically to oil and gas-producing environments. Forty-nine different samples were collected by filtering specific volumes of produced water from a hydraulically fractured well producing from the Niobrara Shale. Water was collected in two different sampling events 24 hours apart. Four to five samples were collected from 11 specific volumes. These samples along with eight different blanks were submitted for analysis. DNA was extracted from each sample, and quantitative polymerase chain reaction (qPCR) and 16S rRNA Illumina MiSeq gene sequencing were performed to determine relative concentrations of biomass and microbial community composition, respectively. The qPCR results varied across sampled volumes, while no discernible trend correlated contamination to volume of water filtered. This suggests that collecting a larger volume of sample may not result in larger biomass concentrations or better representation of a sampled environment. Researchers could prioritize collecting many low volume samples over few high-volume samples. Our results suggest that there also may be variability in the concentration of microbial communities present in produced waters over short (i.e., hours) time scales, which warrants further investigation. Submission of multiple blanks is also vital to determining how contamination or low biomass effects may influence a sample set collected from an unknown environment.

Montana, Wyoming, Colorado, New Mexico, Texas, Okl↗

Compositional analysis of formation water geochemistry and microbiology of commercial and carbon dioxide-rich wells in the southwestern United States

Studies of naturally occurring subsurface carbon dioxide (CO 2 ) accumulations can provide useful information for potential CO 2 injection projects; however, the microbial communities and formation water geochemistry of most reservoirs are understudied. Formation water and microbial biomass were sampled at four CO 2 -rich reservoir sites: two within Bravo Dome, a commercial CO 2 field in New Mexico; one northwest of Bravo Dome in Colorado (Oakdale Field); and one southwest of Bravo Dome in New Mexico (Rafter “K” Ranch). Aside from the Rafter “K” Ranch site, minor differences were observed in the geochemistry of formation water collected from these sites compared to historical data. No organisms were significantly associated with Oakdale Field compared to the other three sites, nor were any hydrogeochemical or gas geochemical parameters (for example, CO 2 concentration) found to have significant associations with the microbial ecology of these four sites. Microorganisms from these sites were metabolically diverse and had the potential to (1) generate methane, (2) produce corrosive hydrogen sulfide (H 2 S), and (3) rapidly biofoul and (or) clog pore spaces by shifting microbial communities with changes in salinity or nutrient supply. This study demonstrates that high concentrations of CO 2 in subsurface reservoirs apparently have not imparted a distinct geochemical or microbiological signature on the associated formation waters and that the microorganisms in these reservoirs are metabolically diverse and could adapt to geochemical changes in the subsurface.

Colorado, New Mexico, Texas, Oklahoma↗

Carbon dioxide mineralization feasibility in the United States

Geologic carbon dioxide (CO 2 ) storage is one of many methods for stabilizing the increasing concentration of CO 2 in the Earth’s atmosphere. The injection of CO 2 in deep subsurface sedimentary reservoirs is the most commonly discussed method; however, the potential for CO 2 leakage can create long-term stability concerns. This report discusses the feasibility of an alternative form of geologic CO 2 storage: CO 2 mineralization. In this method, CO 2 reacts with rocks and minerals to form solid and stable carbonate rocks. New pilot projects and laboratory-based kinetics experiments have revealed that this method, both in situ and ex situ, may be a viable option for storage. In situ storage targets in-place rocks at the surface or subsurface. Ex situ storage targets industrial byproducts at the surface like mine tailings. Environmental risks include induced seismicity for in situ methods if pressure is not managed properly, as well as potential water and land use effects. However, there are fewer long-term CO 2 -leakage concerns for mineralization methods compared to saline storage methods and therefore potentially lower long-term monitoring costs. The costs and benefits of CO 2 mineralization are compared to those of CO 2 storage in saline reservoirs using estimates of pressure-limited dynamic storage capacity. This report highlights the regional potential of areas in the United States for in situ and ex situ storage, as well as their proximity to potential sources of CO 2 . Especially suitable targets include asbestos or other ultramafic mine tailings, in situ ultramafic rocks on the East and West Coasts, the Columbia River basalts in the Pacific Northwest, the Midcontinent Rift basalts in the midcontinent, and the basaltic Hawaiian Islands.

Scientific Investigations Report↗

Geologic framework for the national assessment of carbon dioxide storage resources—Atlantic Coastal Plain and Eastern Mesozoic Rift Basins

This chapter presents information pertinent to the geologic carbon dioxide (CO 2 ) sequestration potential within saline aquifers located in the Atlantic Coastal Plain and Eastern Mesozoic Rift Basins of the Eastern United States. The Atlantic Coastal Plain is underlain by a Jurassic to Quaternary succession of sedimentary strata that onlap westward onto strata of the Appalachian Piedmont physiographic province and generally thicken eastward toward the present-day Atlantic coastline and onto the present-day continental shelf. Although no significant petroleum discoveries have been made on the coastal plain, the deep saline aquifers of the region appear to contain porous strata (potential reservoirs, or “storage formations”) that are overlain by fine-grained, laterally continuous strata (potential seals), which are prospective CO 2 sequestration targets. For the Atlantic Coastal Plain, we identify two storage assessment units (SAUs), both of which consist of Cretaceous strata. The two SAUs are the Lower Cretaceous Composite SAU C50700101 and the Upper Cretaceous Composite SAU C50700102. The Eastern Mesozoic Rift Basins are a chain of generally southwest- to northeast-trending, elongate sedimentary basins that either underlie the Atlantic Coastal Plain or crop out within adjacent geologic provinces to the west. Similar to the Atlantic Coastal Plain, there has been no significant oil and gas production from any of the basins, although there is a proven petroleum system in several of them. At least three of these basins appear to contain potential storage formations overlain by potential seal units. Most of the other basins were not assessed because a storage and (or) seal formation could not be established in the timeframe of the assessment, often because of the paucity of subsurface data for these basins in comparison to other petroliferous basins of the United States. Thus, we present information supporting one quantitative assessment in the Newark basin, as well as information supporting two nonquantitative assessments, one for strata in the Gettysburg basin and the other for strata in the Culpeper basin. We briefly discuss six other basins within the Eastern Mesozoic Rift Basins that were not assessed. For all SAUs, we discuss the areal distribution of suitable CO 2 reservoir rock. We also describe the overlying sealing unit and the geologic characteristics that influence the potential CO 2 storage volume and reservoir characteristics. These characteristics include storage formation depth, gross thickness, net thickness, porosity, permeability, and groundwater salinity. Case-by-case strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are presented. Although assessment results are not contained in this chapter, the geologic information included herein was used to calculate the potential storage space in the SAUs.

Atlantic Coastal Plain and Eastern Mesozoic Rift B↗

Microbial community composition of a hydrocarbon reservoir 40 years after a CO2 enhanced oil recovery flood

Injecting CO 2 into depleted oil reservoirs to extract additional crude oil is a common enhanced oil recovery (CO 2 -EOR) technique. However, little is known about how in situ microbial communities may be impacted by CO 2 flooding, or if any permanent microbiological changes occur after flooding has ceased. Formation water was collected from an oil field that was flooded for CO 2 -EOR in the 1980s, including samples from areas affected by or outside of the flood region, to determine the impacts of CO 2 -EOR on reservoir microbial communities. Archaea, specifically methanogens, were more abundant than bacteria in all samples, while identified bacteria exhibited much greater diversity than the archaea. Microbial communities in CO 2 -impacted and non-impacted samples did not significantly differ (ANOSIM: Statistic R = -0.2597, significance = 0.769). However, several low abundance bacteria were found to be significantly associated with the CO 2 -affected group; very few of these species are known to metabolize CO 2 or are associated with CO 2 -rich habitats. Although this study had limitations, on a broad scale, either the CO 2 flood did not impact the microbial community composition of the target formation, or microbial communities in affected wells may have reverted back to pre-injection conditions over the ca. 40 years since the CO 2 -EOR.

Louisiana↗

Mantle and crustal gases of the Colorado Plateau: Geochemistry, sources, and migration pathways

The Colorado Plateau hosts several large accumulations of naturally occurring, non-hydrocarbon gases, including CO 2 , N 2 , and the noble gases, making it a good field location to study the fluxes of these gases within the crust and to the atmosphere. In this study, we present a compilation of 1252 published gas-composition measurements. The data reveal at least three natural gas associations in the field area, which are dominated by hydrocarbons, CO 2, and N 2 + He + Ar, respectively. Most gas accumulations of the region exhibit compositions that are intermediate between the three end members. The first non-hydrocarbon gas association is characterized by very high-purity CO 2 , in excess of 75 mol% (hereafter, %). Many of these high-purity CO 2 fields have recently been well described and interpreted as magmatic in origin. The second non-hydrocarbon gas association is less well described on the Colorado Plateau. It exhibits He concentrations on the order of 1–10%, and centered log ratio biplots show that He occurs proportionally to both N 2 and Ar. Overall ratios of N 2 to He to Ar are ≈100:10:1 and correlation in concentrations of these gases suggests that they have been sourced from the same reservoir and/or by a common process. To complement the analysis of the gas-composition data, stable isotope and noble-gas isotope measurements are compiled or newly reported from 11 representative fields (previously published data from 4 fields and new data from 7 fields). Gas sampled from the Harley Dome gas field in Utah contains nearly pure N 2 + He + Ar. The various compositional and stable and noble gas isotopic data for this gas indicate that noble gas molecule/isotope ratios are near crustal radiogenic production values and also suggest a crustal N 2 source. Across the field area, most of the high-purity N 2 + He + Ar gas accumulations are associated with the mapped surface trace of structures or sutures in the Precambrian basement and are often accumulated in lower parts of the overlying Phanerozoic sedimentary cover. The high-purity gas association mostly occurs in areas interior to the plateau that are characterized by a narrow range of elevated, moderate heat flow values (53–74 mW/m 2 ) in the ancient (1.8–1.6 Ga) basement terranes of the region. Collectively, the geochemical and geological data suggest that (1) the N 2 + He + Ar gas association is sourced from a crustal reservoir, (2) the gas association migrates preferentially along structures in the Precambrian basement, and (3) the sourcing process relates to heating of the crust. Prospecting for noble-gas accumulations may target areas with elevated Cenozoic heat flow, ancient crust, and deep crustal structures that focus gas migration. High-purity CO 2 gas may also migrate through regional basement structures, however, there is not always a clear spatial association. Rather, CO 2 accumulations are more clearly associated with zones of high heat flow (>63 mW/m 2 ) that sit above hot upper mantle and are proximal to Cenozoic volcanic rocksnear the plateau margins. These observations are consistent with previous interpretations of a magmatic gas source, which were based on geochemical measurements.

Colorado Plateau↗

Geologic framework for the national assessment of carbon dioxide storage resources—Southern Rocky Mountain Basins: Chapter M in Geologic framework for the national assessment of carbon dioxide storage resources

The U.S. Geological Survey has completed an assessment of the potential geologic carbon dioxide storage resources in the onshore areas of the United States. To provide geological context and input data sources for the resources numbers, framework documents are being prepared for all areas that were investigated as part of the national assessment. This report, chapter M, is the geologic framework document for the Uinta and Piceance, San Juan, Paradox, Raton, Eastern Great, and Black Mesa Basins, and subbasins therein of Arizona, Colorado, Idaho, Nevada, New Mexico, and Utah. In addition to a summary of the geology and petroleum resources of studied basins, the individual storage assessment units (SAUs) within the basins are described and explanations for their selection are presented. Although appendixes in the national assessment publications include the input values used to calculate the available storage resource, this framework document provides only the context and source of the input values selected by the assessment geologists. Spatial-data files of the boundaries for the SAUs, and the well-penetration density of known well bores that penetrate the SAU seal, are available for download with the release of this report.

Arizona, Colorado, Idaho, Nevada, New Mexico, Utah↗

Geologic framework for the national assessment of carbon dioxide storage resources─South Florida Basin: Chapter L in Geologic framework for the national assessment of carbon dioxide storage resources

This report presents five storage assessment units (SAUs) that have been identified as potentially suitable for geologic carbon dioxide sequestration within a 35,075-square-mile area that includes the entire onshore and State-water portions of the South Florida Basin. Platform-wide, thick successions of laterally extensive carbonates and evaporites deposited in highly cyclic depositional environments in the South Florida Basin provide several massive, porous carbonate reservoirs that are separated by evaporite seals. For each storage assessment unit identified within the basin, the areal distribution of the reservoir-seal couplet identified as suitable for geologic Carbon dioxide sequestration is presented, along with a description of the geologic characteristics that influence the potential carbon dioxide storage volume and reservoir performance. On a case-by-case basis, strategies for estimating the pore volume existing within structurally and (or) stratigraphically closed traps are also discussed. Geologic information presented in this report has been employed to calculate potential storage capacities for carbon dioxide sequestration in the storage assessment units assessed herein, although complete assessment results are not contained in this report.

Florida↗

Geologic framework for the national assessment of carbon dioxide storage resources: Permian and Palo Duro Basins and Bend Arch-Fort Worth Basin: Chapter K in Geologic framework for the national assessment of carbon dioxide storage resources

The U.S. Geological Survey has completed an assessment of the potential geologic carbon dioxide storage resource in the onshore areas of the United States. To provide geological context and input data sources for the resources numbers, framework documents are being prepared for all areas that were investigated as part of the national assessment. This report is the geologic framework document for the Permian and Palo Duro Basins, the combined Bend arch-Fort Worth Basin area, and subbasins therein of Texas, New Mexico, and Oklahoma. In addition to a summarization of the geology and petroleum resources of studied basins, the individual storage assessment units (SAUs) within the basins are described and explanations for their selection are presented. Though appendixes in the national assessment publications include the input values used to calculate the available storage resource, this framework document provides only the context and source of inputs selected by the assessment geologists. Spatial files of boundaries for the SAUs herein, as well as maps of the density of known well bores that penetrate the SAU seal, are available for download with the release of this report.

New Mexico, Oklahoma Texas↗

Atmospheric particulate matter in proximity to mountaintop coal mines: Sources and potential environmental and human health impacts

Mountaintop removal mining (MTM) is a widely used approach to surface coal mining in the US Appalachian region whereby large volumes of coal overburden are excavated using explosives, removed, and transferred to nearby drainages below MTM operations. To investigate the air quality impact of MTM, the geochemical characteristics of atmospheric particulate matter (PM) from five surface mining sites in south central West Virginia, USA, and five in-state study control sites having only underground coal mining or no coal mining whatsoever were determined and compared. Epidemiologic studies show increased rates of cancer, respiratory disease, cardiovascular disease, and overall mortality in Appalachian surface mining areas compared to Appalachian non-mining areas. In the present study, 24-h coarse (>2.5 µm) and fine (≤2.5 µm) PM samples were collected from two surface mining sites in June 2011 showed pronounced enrichment in elements having a crustal affinity (Ga, Al, Ge, Rb, La, Ce) contributed by local sources, relative to controls. Follow-up sampling in August 2011 lacked this enrichment, suggesting that PM input from local sources is intermittent. Using passive samplers, dry deposition total PM elemental fluxes calculated for three surface mining sites over multi-day intervals between May and August 2012 were 5.8 ± 1.5 times higher for crustal elements than at controls. Scanning microscopy of 2,249 particles showed that primary aluminosilicate PM was prevalent at surface mining sites compared to secondary PM at controls. Additional testing is needed to establish any link between input of lithogenic PM and disease rates in the study area.

West Virginia↗