Geology topics
Publications and source records attributed to Charles M. Taylor.
A variety of orpiment, As 2 S 3 , containing a significant amount of thallium has been identified in the unoxidized East ore body of the Carlin gold deposit. The mineral occurs in small veinlets with barite, calcite, quartz, and realgar.
Orpiment, As 2 S 3 , containing up to 1.5 percent antimony has been recognized in carbonaceous arsenic-rich gold ores in the unoxidized East ore body of the Carlin gold deposit. Associated hydrothermal minerals include realgar (AsS) and quartz. Stibnite, commonly associated with realgar in the ores, has not been observed associated with this type of orpiment.
Cuprobismutite from Tunnel Extension Number Two mine, Ohio mining district, Utah, was chemically analyzed using the electron microprobe. Its empirical formula was determined to be Cu 20.8 Ag 0.97 Pb 0.35 Mn 0.22 Bi 26.7 Sb 0.06 Te 0.05 Se 0.55 S 50.4. The tentative conclusion is that unsubstituted cuprobismutite has the chemical formula 6Cu 2 S*6Bi 2 S 3 rather than the previously ascribed formula 6Cu 2 S*6Bi 2 S 3 and that cuprobismutite is therefore not dimorphous with emplectite.
Detailed mineralogical and chemical study of sphalerite-rich lead ores from Flat River, Mo., confirms the presence of anomalous amounts of silver in the sphalerite. Although silver is closely associated with chlorine and no silver sulfide minerals were identified, geochemical considerations indicate the silver may be in the form of discrete submicron-size grains of sulfide rather than chloride. However, the close correlation between abundance variations in silver, chlorine, cadmium, iron, and minor lead suggests the possible existence of submicron-size grains of a complex chloride or oxychloride. Results from detailed chemical study of sphalerite show: (1) chlorine is present in areas containing silver and changes in abundance of both elements are similar; (2) the mole ratio of chlorine to silver varies from approximately 3:1 to 6:1 with an approximate average of 5:1 and the total content of each element varies widely between grains and within the same grain; (3) taking total silver in any analysis and calculating the amount of chlorine required for silver chloride leaves an excess of chlorine; (4) in chlorine-deficient areas the amounts of iron and cadmium substituting for zinc in the sphalerite structure vary widely; and (5) in areas containing chlorine, changes in abundance of iron and cadmium vary directly with that of chlorine. The fine-grained dusty opaque inclusions characterize sphalerite from this area; they were identified as mainly galena with lesser amounts of pyrite and cassiterite. Galena is silver-free (<0.02 weight percent Ag) and is essentially pure lead sulfide. Other sulfides identified include pyrite, a cobalt-nickel-iron sulfide of composition Co (sub 0.55) Ni (sub 0.25) Fe (sub 0.20) S (sub 2.00), and an iron-cobalt-nickel sulfide containing 22-28 weight percent Fe, 10-15 weight percent Co, and 3-5 weight percent Ni. Anomalous amounts of tin present as cassiterite are associated with the gangue minerals quartz, potash feldspar, a kaolinite-type clay, and trace amounts of cuprite. Carbonate gangue minerals include calcite, dolomite, ankerite, magnesite, and minor amounts of cerussite. Chemical analyses were made of many minerals and physical and textural relationships examined.
During a study of hypogene manganese minerals, three silver-bearing manganese oxides were identified in "black calcite" associated with silver ores at the Aurora mine (Treasure Hill), Hamilton, Nevada. Specifically these are: (1) argentian chalcophanite (aurorite) (Ag 2 Ba,Ca,Pb,-K 2 ,Cu,Mn (super +2) )Mn 3 (super +4) O 7 . 3H 2 O; (2) argentian todorokite (Ag 2 ,K 2 ,Ca,Ba,-Na 2 ,Cu,Pb)Mn 4 (super +4) O 9 . 5H 2 O; and (3) hydrous silver-bearing lead manganese oxide (Pb,Cu,Ba,Sb,Ag 2 ,Ca,K 2 )Mn 5 (super +4) O 11 . 5H 2 O. Based on the large concentration of silver in argentian chalcophanite (7.50% Ag 2 O) and the low zinc content (0.25% ZnO) this mineral is recognized as a new species and named "aurorite."Physical and optical properties, and chemical analyses of the three minerals are presented together with X-ray powder diffraction data for aurorite and argentian todorokite. All chemical analyses were done with the electron microprobe analyzer. Due to extremely small particle size and textural relations, no X-ray powder data were obtained for the hydrous silver-bearing lead manganese oxide. Associated minerals include cryptomelane, pyrolusite, birnessite(?), cerargyrite, native silver, quartz, and manganoan calcite. Although the general uniform dark color of the "black calcite" and apparent uniform distribution of the inclusions suggests contemporaneous formation, examination of polished sections at high magnifications shows a definite paragenetic sequence. Manganoan calcite is replaced by fine-grained intergrowths of cryptomelane, pyrolusite, birnessite(?), and cerargyrite. Native silver formed early and the silver-bearing manganese oxides formed late in the sequence; aurorite fills microfractures that cut through all other minerals.These three silver-bearing manganese oxides were recognized only at the Aurora mine, Hamilton, Nevada, although black calcite veins were studied from numerous areas in the western United States. The geologic features of silver-bearing black calcites are described by Hewett and Radtke in the preceding paper.