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Charles G. Cunningham

Publications and source records attributed to Charles G. Cunningham.

At least 19 recordsLinked to original sources

Quantitative mineral resource assessment of copper, molybdenum, gold, and silver in undiscovered porphyry copper deposits in the Andes Mountains of South America

Quantitative information on the general locations and amounts of undiscovered porphyry copper resources of the world is important to exploration managers, land-use and environmental planners, economists, and policy makers. This publication contains the results of probabilistic estimates of the amounts of copper (Cu), molybdenum (Mo), gold (Au), and silver (Ag) in undiscovered porphyry copper deposits in the Andes Mountains of South America. The methodology used to make these estimates is called the 'Three-Part Form'. It was developed to explicitly express estimates of undiscovered resources and associated uncertainty in a form that allows economic analysis and is useful to decisionmakers. The three-part form of assessment includes: (1) delineation of tracts of land where the geology is permissive for porphyry copper deposits to form; (2) selection of grade and tonnage models appropriate for estimating grades and tonnages of the undiscovered porphyry copper deposits in each tract; and (3) estimation of the number of undiscovered porphyry copper deposits in each tract consistent with the grade and tonnage model. A Monte Carlo simulation computer program (EMINERS) was used to combine the probability distributions of the estimated number of undiscovered deposits, the grades, and the tonnages of the selected model to obtain the probability distributions for undiscovered metals in each tract. These distributions of grades and tonnages then can be used to conduct economic evaluations of undiscovered resources in a format usable by decisionmakers. Economic evaluations are not part of this report. The results of this assessment are presented in two principal parts. The first part identifies 26 regional tracts of land where the geology is permissive for the occurrence of undiscovered porphyry copper deposits of Phanerozoic age to a depth of 1 km below the Earth's surface. These tracts are believed to contain most of South America's undiscovered resources of copper. The second part presents probabilistic estimates of the amounts of copper, molybdenum, gold, and silver in undiscovered porphyry copper deposits in each tract. The study also provides tables showing the location, tract number, and age (if available) of discovered deposits and prospects. For each of the 26 permissive tracts delineated in this study, summary information is provided on: (1) the rationale for delineating the tract; (2) the rationale for choosing the mineral deposit model used to assess the tract; (3) discovered deposits and prospects; (4) exploration history; and (5) the distribution of undiscovered deposits in the tract. The scale used to evaluate geologic information and draw tracts is 1:1,000,000.

Open-File Report

Supergene destruction of a hydrothermal replacement alunite deposit at Big Rock Candy Mountain, Utah: Mineralogy, spectroscopic remote sensing, stable-isotope, and argon-age evidences

Big Rock Candy Mountain is a prominent center of variegated altered volcanic rocks in west-central Utah. It consists of the eroded remnants of a hypogene alunite deposit that, at ∼21 Ma, replaced intermediate-composition lava flows. The alunite formed in steam-heated conditions above the upwelling limb of a convection cell that was one of at least six spaced at 3- to 4-km intervals around the margin of a monzonite stock. Big Rock Candy Mountain is horizontally zoned outward from an alunite core to respective kaolinite, dickite, and propylite envelopes. The altered rocks are also vertically zoned from a lower pyrite–propylite assemblage upward through assemblages successively dominated by hypogene alunite, jarosite, and hematite, to a flooded silica cap. This hydrothermal assemblage is undergoing natural destruction in a steep canyon downcut by the Sevier River in Marysvale Canyon. Integrated geological, mineralogical, spectroscopic remote sensing using AVIRIS data, Ar radiometric, and stable isotopic studies trace the hypogene origin and supergene destruction of the deposit and permit distinction of primary (hydrothermal) and secondary (weathering) processes. This destruction has led to the formation of widespread supergene gypsum in cross-cutting fractures and as surficial crusts, and to natrojarosite, that gives the mountain its buff coloration along ridges facing the canyon. A small spring, Lemonade Spring, with a pH of 2.6 and containing Ca, Mg, Si, Al, Fe, Mn, Cl, and SO 4 , also occurs near the bottom of the canyon. The 40 Ar/ 39 Ar age (21.32±0.07 Ma) of the alunite is similar to that for other replacement alunites at Marysvale. However, the age spectrum contains evidence of a 6.6-Ma thermal event that can be related to the tectonic activity responsible for the uplift that led to the downcutting of Big Rock Candy Mountain by the Sevier River. This ∼6.6 Ma event also is present in the age spectrum of supergene natrojarosite forming today, and probably dates the beginning of supergene alteration at Big Rock Candy Mountain. The δ 34 S value (11.9‰) of alunite is similar to those for replacement alunite from other deposits in the Marysvale volcanic field. The δ 34 S values of natrojarosite (0.7‰ to −1.2‰) are similar to those for aqueous sulfate in Lemonade Spring, but are larger than those in pyrite (0.4‰ to −4.7‰). The δ 34 S and δ 18 O SO 4 values of gypsum show an excellent correlation, with values ranging from 15.2‰ to −5.2‰ and 7‰ to −8.2‰, respectively. The stable-isotope data indicate that the aqueous sulfate for gypsum is a mixture derived from the dissolution of hypogene gypsum and alunite, and from the supergene oxidation of pyrite. The aqueous sulfate for the natrojarosite, however, is derived largely from the supergene oxidation of pyrite, with a minor contribution from the dissolution of alunite and gypsum. The exceptional detailed spectral mapping capabilities of AVIRIS led to the recognition of a small amount of jarosite that is probably the top of the steam-heated system that produced the primary hypogene alteration at Big Rock Candy Mountain.

Utah

Geologic Map of the Central Marysvale Volcanic Field, Southwestern Utah

The geologic map of the central Marysvale volcanic field, southwestern Utah, shows the geology at 1:100,000 scale of the heart of one of the largest Cenozoic volcanic fields in the Western United States. The map shows the area of 38 degrees 15' to 38 degrees 42'30' N., and 112 degrees to 112 degrees 37'30' W. The Marysvale field occurs mostly in the High Plateaus, a subprovince of the Colorado Plateau and structurally a transition zone between the complexly deformed Great Basin to the west and the stable, little-deformed main part of the Colorado Plateau to the east. The western part of the field is in the Great Basin proper. The volcanic rocks and their source intrusions in the volcanic field range in age from about 31 Ma (Oligocene) to about 0.5 Ma (Pleistocene). These rocks overlie sedimentary rocks exposed in the mapped area that range in age from Ordovician to early Cenozoic. The area has been deformed by thrust faults and folds formed during the late Mesozoic to early Cenozoic Sevier deformational event, and later by mostly normal faults and folds of the Miocene to Quaternary basin-range episode. The map revises and updates knowledge gained during a long-term U.S. Geological Survey investigation of the volcanic field, done in part because of its extensive history of mining. The investigation also was done to provide framework geologic knowledge suitable for defining geologic and hydrologic hazards, for locating hydrologic and mineral resources, and for an understanding of geologic processes in the area. A previous geologic map (Cunningham and others, 1983, U.S. Geological Survey Miscellaneous Investigations Series I-1430-A) covered the same area as this map but was published at 1:50,000 scale and is obsolete due to new data. This new geologic map of the central Marysvale field, here published as U.S. Geological Survey Geologic Investigations Series I-2645-A, is accompanied by gravity and aeromagnetic maps of the same area and the same scale (Campbell and others, 1999, U.S. Geological Survey Geologic Investigations Series I-2645-B).

IMAP

Aeromagnetic and Gravity Maps of the Central Marysvale Volcanic Field, Southwestern Utah

Gravity and aeromagnetic features in the Marysvale volcanic field result from the composite effects of many factors, including rock composition, style of magmatic emplacement, type and intensity of rock alteration, and effects of structural evolution. Densities and magnetic properties measured on a suite of rock samples from the Marysvale volcanic field differ in systematic ways. Generally, the measured densities, magnetic susceptibilities, and natural remanent magnetizations all increase with mafic index, but decrease with degree of alteration, and for tuffs, with degree of welding. Koenigsberger Q indices show no such systematic trends. The study area is divided into three geophysical domains. The northern domain is dominated by aeromagnetic lows that probably reflect reversed-polarity volcanic flows. There are no intermediate-sized magnetic highs in the northern domain that might reflect plutons. The northern domain has a decreasing-to-the-south gravity gradient that reflects the Pavant Range homocline. The central domain has gravity lows that reflect altered rocks in calderas and low-density plutons of the Marysvale volcanic field. Its aeromagnetic signatures consist of rounded highs that reflect plutons and birdseye patterns that reflect volcanic flows. In many places the birdseyes are attenuated, indicating that the flows there have been hydrothermally altered. We interpret the central domain to reflect an east-trending locus of plutons in the Marysvale volcanic field. The southern domain has intermediate gravity fields, indicating somewhat denser rocks there than in the central domain, and high-amplitude aeromagnetic birdseyes that reflect unaltered volcanic units. The southern domain contains no magnetic signatures that we interpret to reflect plutons. Basin-and-range tectonism has overprinted additional gravity features on the three domains. A deep gravity low follows the Sevier and Marysvale Valleys, reflecting grabens there. The gravity gradient in the north reflects the southern flank of a structural dome that led to the Pavant Range homocline and whose southern edge lies along the Clear Creek downwarp.

IMAP

Evolution of volcanic rocks and associated ore deposits in the Marysvale volcanic field, Utah

A geological account on the igneous activity and associated mineral deposition in the volcanic field of Marysvale in Utah is presented. Three episodes (34-22 Ma, 22-14 Ma and 9-5 Ma) involved in the volcanic rock eruption and associated mineralization are described. The first episode is believed to have occurred during the time of tectonic convergence when two contrasting suites of rocks, Mount Dutton Formation and Bullion Canyon Volcanics, erupted concurrently. Mineralization during this period was sparse. In the second episode, change from intermediate to bimodal volcanism occurred. During the third episode, basaltic compositions did not change. Although major element constituent had rhyolites similar to that of the second episode, rhyolites had a marked radiogenic isotope characteristic difference.

Utah

Geologic characteristics of sediment- and volcanic-hosted disseminated gold deposits - Search for an occurrence model

The current expansion of resource information, particularly on "disseminated" gold, and the improved technologies now available for resource investigations should place us in an enhanced position for developing a better predictive methodology for meeting one of the important responsibilities of the U.S. Geological Survey-to examine and assess the mineral resources of the geologic terranes composing the public (and privately owned) lands of the United States. The first step is systematic organization of these data. Geologic-occurrence models are an effective systematic method by which to organize large amounts of resource information into a logical sequence facilitating its use more effectively in meeting several industry and Survey objectives, which include the exploration for resources and the assessment of resource potential for land-use decisions. Such models also provide a scientific basis for metallogenesis research, which considers the observable features or attributes of ore occurrence and their "fit" into the Earth's resource puzzle. The use of models in making resource assessments/appraisals was addressed by Shawe (1981), who reported the results of a workshop on methods for resource appraisal of Wilderness and Conterminous United States Mineral Appraisal Program (CUSMAP; 1:250,000-scale quadrangles) areas. The Survey's main objective in the 1982 workshop was to evaluate the status of knowledge about disseminated or very fine grained gold deposits and, if possible, to develop an occurrence model(s). This report on the workshop proceedings has three main objectives: (1) Education through the publication of a summary review and presentation of new thinking and observations about the scientific bases for those geologic processes and environments that foster disseminated gold-ore formation; (2) systematic organization of available geologic, geochemical, and geophysical information for a range of typical disseminated gold deposits (including recognition of gaps in those data); and (3) assessment of current understanding (as presented in objective 2) toward formulating an empirical ore-occurrence model for this type of deposit. As such, this volume represents a preliminary first step at classification and provides a source of pertinent background information. Readers of this volume will soon discover, however, that full agreement has not yet been achieved in the interpretation of some of the geologic evidence. The resulting variations in tentative occurrence models for these controversial deposits ultimately will be resolved by filling the gaps in information that have already been identified. Thus, this volume does not report a U.S. Geological Survey consensus; the conclusions expressed in each chapter represent the particular interpretations of the various workshop participants.

Arizona, California, Idaho, Nevada, Utah

Integrated uranium system in the Marysvale volcanic field, west-central Utah

Uranium in the Marysvale volcanic field is known to occur in several geologic environments, and is hypothesized to occur in others. Together the known and hypothetical occurrences range from a source in rhyolite magma, through porphyry-type deposits, hydrothermal vein deposits, dispersed hydrothermal deposits, and after transport in ground and surface water, to roll-front or sedimentary trap-deposits in basin-fill sediments. To date, only the hydrothermal vein environment has been productive, but billions of pounds of uranium were available in all other environments, and if proper circumstances occurred, significant concentrations probably exist there too. The intracaldera fill of the Mount Belknap caldera and sediment-filled basins adjoining the Tushar Mountains are especially favorable for the undiscovered uranium that may be expected.

Utah

Postulated model of uranium occurrence in the central mining area, Marysvale District, west-central Utah

Uranium in the central mining area of Marysvale, Utah occurs in hydrothermal veins cutting granitic and volcanic rocks in the eastern source area of the Mount Belknap Volcanics. A preliminary model for the origin of the veins envisages deposition in near-surface fractures above an unexposed pluton that may host a porphyry-type ore deposit. This model is based on the work in progress by the U.S. Geological Survey, and embodies all presently available data from field mapping, literature study, fluid inclusion studies, and diverse geochemical and isotopic studies. Recent advances in uranium geochemistry have been particularly helpful. The work is not yet complete so this model should be considered as a progress report suggesting possible targets for exploration and testing; such testing would in turn lead to refinements in the model and to a clearer understanding of vein-type uranium deposits in general.

Utah

Pressure gradients and boiling as mechanisms for localizing ore in porphyry systems

Fluid inclusions in ore zones of porphyry systems indicate that extensive boiling of hydrothermal fluids accompanies deposition of ore and gangue minerals. The boiling commonly accompanied a change from a lithostatic to a hydrostatic environment during evolution of an epizonal stock. Pressure gradients near the margin of the stock can determine whether ore or only a diffuse zone of mineralization is formed. A sharp drop in pressure in an epizonal environment is more likely to cause extensive boiling than a comparable change in a deeper environment, as the slope of the boiling curve steepens with an increase 'in pressure. The drop in pressure causes the hydrothermal fluids to boil and creates a crackle (stockwork) breccia, which hosts the veinlets of gangue quartz and ore minerals. The boiling selectively partitions CO 2 , H 2 S, and HCl into the vapor phase, changing the pH, composition, ionic strength, and thus the solubility product of metal complexes in the remaining liquid and causing the ore and gangue to come out of solution. Fluid inclusions trapped from boiling solutions can exhibit several forms, depending on the physical and chemical conditions of the hydrothermal fluid from which they were trapped. In one case, inclusions when heated can homogenize to either liquid or vapor at the same temperature, which is the true boiling temperature. In another case, homogenization of various inclusions can occur through a range of temperatures. The latter case results from the trapping of mixture of liquid and vapor. Variations in salinity can result from boiling of the hydrothermal fluid, or intermittent incorporation of high-salinity fluids from the magma, or trapping of fluids of varying densities at pressure-temperature conditions above the critical point of the fluid. In places, paleopressure-temperature transition zones can be recognized by fluid-inclusion homogenization temperatures and phase relationships and by the presence of anhydrite daughter minerals. Boiling of a hydrothermal fluid in the porphyry environment affects light stable isotopes. Hydrogen is preferentially fractionated into the vapor phase from water boiling below 223°C; above this temperature deuterium is selectively enriched in the vapor phase. In certain environments boiling creates a vapor-dominated system in which the condensate is swept away by meteoric waters and the H/D in the residual fluids is progressively increased through time.

Utah