Geology topics

Carolyn D. Ruppel

Publications and source records attributed to Carolyn D. Ruppel.

46 records · Page 3Linked to original sources

USGS2011

Observations of mass fractionation of noble gases in synthetic methane hydrate

As a consequence of contemporary or longer term (since 15 ka) climate warming, gas hydrates in some settings are presently dissociating and releasing methane and other gases to the oceanatmosphere system. A key challenge in assessing the susceptibility of gas hydrates to warming climate is the lack of a technique able to distinguish between methane recently released from gas hydrates and methane emitted from leaky thermogenic reservoirs, shallow sublake and subseafloor sediments, coalbeds, and other sources. Carbon and deuterium stable isotopic data provide only a first-order characterization of methane sources, while gas hydrate can sequester any type of methane. Here, we investigate the possibility of exploiting the pattern of noble gas fractionation within the gas hydrate lattice to fingerprint methane released from gas hydrates. Starting with synthetic gas hydrate formed under careful laboratory conditions, we document complex noble gas fractionation patterns in the gases liberated during dissociation and explore the effects of aging and storage (e.g., in liquid nitrogen), as well as sampling and preservation procedures. The laboratory results confirm a unique noble gas fractionation pattern for gas hydrates, one that shows promise in evaluating modern natural gas seeps for a signature associated with gas hydrate dissociation.

Conference Paper↗

USGS2010

The impact of hydrate saturation on the mechanical, electrical, and thermal properties of hydrate-bearing sand, silts, and clay

Proper understanding of the physical properties of hydrate-bearing sediments is required for interpretation of borehole logs and exploration geophysical data, the analysis of borehole and submarine slope stability, and the formulation of reservoir simulation and production models. Yet current knowledge of geophysical and geotechnical properties of hydrate-bearing sediments is still largely derived from laboratory experiments conducted on disparate soils at different confining pressures, degrees of water saturation, and hydrate concentrations and with hydrates formed by methods unlike those that predominate in nature. We conducted a comprehensive laboratory program using sand, silts, and clay subjected to various confining effective stress levels in standardized geotechnical laboratory devices and containing carefully controlled saturations of tetrahydrofuran (THF) hydrate formed from the dissolved phase. Here, we undertake complete analysis of the trends in the measured geophysical and geotechnical properties (e.g., seismic velocities, strength, electrical conductivity and permittivity, and thermal conductivity) as a function of hydrate saturation, soil characteristics, and effective stress. Results reveal that the electrical properties of hydrate-bearing sediments are not very sensitive to the laboratory method used to form hydrate, which controls the pore-scale arrangement of hydrate and sediment grains, but are sensitive to hydrate saturation. Mechanical properties are strongly influenced by both soil properties and the hydrate formation method. Thermal conductivity depends on the complex interplay of a variety of factors, including formation history, and cannot be easily predicted by volume average formulations but will remain within physical upper and lower bounds. When hydrate forms from dissolved phase guest molecules, the resulting mathematical trends for all physical properties require that the hydrate saturation Sh in pore space, which is a quantity between 0≤ Sh ≤1.0 , be raised to a power greater than 1. This significantly reduces the impact of low-hydrate saturations on the measured physical parameters, an effect that is particularly pronounced at the hydrate saturations characteristic of many natural systems (<0.2 of pore space).

Book chapter↗

USGS2010

Volume change associated with formation and dissociation of hydrate in sediment

Gas hydrate formation and dissociation in sediments are accompanied by changes in the bulk volume of the sediment and can lead to changes in sediment properties, loss of integrity for boreholes, and possibly regional subsidence of the ground surface over areas where methane might be produced from gas hydrate in the future. Experiments on sand, silts, and clay subject to different effective stress and containing different saturations of hydrate formed from dissolved phase tetrahydrofuran are used to systematically investigate the impact of gas hydrate formation and dissociation on bulk sediment volume. Volume changes in low specific surface sediments (i.e., having a rigid sediment skeleton like sand) are much lower than those measured in high specific surface sediments (e.g., clay). Early hydrate formation is accompanied by contraction for all soils and most stress states in part because growing gas hydrate crystals buckle skeletal force chains. Dilation can occur at high hydrate saturations. Hydrate dissociation under drained, zero lateral strain conditions is always associated with some contraction, regardless of soil type, effective stress level, or hydrate saturation. Changes in void ratio during formation-dissociation decrease at high effective stress levels. The volumetric strain during dissociation under zero lateral strain scales with hydrate saturation and sediment compressibility. The volumetric strain during dissociation under high shear is a function of the initial volume average void ratio and the stress-dependent critical state void ratio of the sediment. Other contributions to volume reduction upon hydrate dissociation are related to segregated hydrate in lenses and nodules. For natural gas hydrates, some conditions (e.g., gas production driven by depressurization) might contribute to additional volume reduction by increasing the effective stress.

Geochemistry, Geophysics, Geosystems↗

USGS2009

Thermal conductivity of hydrate-bearing sediments

A thorough understanding of the thermal conductivity of hydrate-bearing sediments is necessary for evaluating phase transformation processes that would accompany energy production from gas hydrate deposits and for estimating regional heat flow based on the observed depth to the base of the gas hydrate stability zone. The coexistence of multiple phases (gas hydrate, liquid and gas pore fill, and solid sediment grains) and their complex spatial arrangement hinder the a priori prediction of the thermal conductivity of hydrate-bearing sediments. Previous studies have been unable to capture the full parameter space covered by variations in grain size, specific surface, degree of saturation, nature of pore filling material, and effective stress for hydrate-bearing samples. Here we report on systematic measurements of the thermal conductivity of air dry, water- and tetrohydrofuran (THF)-saturated, and THF hydrate–saturated sand and clay samples at vertical effective stress of 0.05 to 1 MPa (corresponding to depths as great as 100 m below seafloor). Results reveal that the bulk thermal conductivity of the samples in every case reflects a complex interplay among particle size, effective stress, porosity, and fluid-versus-hydrate filled pore spaces. The thermal conductivity of THF hydrate–bearing soils increases upon hydrate formation although the thermal conductivities of THF solution and THF hydrate are almost the same. Several mechanisms can contribute to this effect including cryogenic suction during hydrate crystal growth and the ensuing porosity reduction in the surrounding sediment, increased mean effective stress due to hydrate formation under zero lateral strain conditions, and decreased interface thermal impedance as grain-liquid interfaces are transformed into grain-hydrate interfaces.

Journal of Geophysical Research B: Solid Earth↗

USGS2009

Permafrost gas hydrates and climate change: Lake-based seep studies on the Alaskan north slope

The potential interactions between climate change and methane hydrate destabilization are among the most societally-relevant aspects of gas hydrates research. Massive dissociation of deep marine methane hydrates following rapid Earth warming is the most plausible explanation for carbon isotopic data that imply widespread release of microbial methane during the Late Paleocene Thermal Maximum (~55 million years ago), and massive methane hydrate degradation may have been associated with a major warming event in the Late Neoproterozoic as well. . On contemporary Earth, circumstantial evidence implies that permafrost-associated methane hydrate dissociation, possibly related to climate change, may be contributing to gas seeps in the MacKenzie Delta (Dallimore et al., 2008). Gas is also currently being released from shallow subseafloor hydrates in some areas, and transient bottom water temperature increases are sometimes known to be the destabilizing influence for these gas hydrates. Still, there is no direct evidence that gas hydrates are currently undergoing significant and systematic destabilization on contemporary Earth, that climate processes are responsible for driving any destabilization that may be occurring, or that methane released from dissociating hydrate is a substantial contributor to atmospheric methane concentrations.

Alaska↗

USGS2008

Scientific objectives of the Gulf of Mexico gas hydrate JIP leg II drilling

The Gulf of Mexico Methane Hydrate Joint Industry Project (JIP) has been performing research on marine gas hydrates since 2001 and is sponsored by both the JIP members and the U.S. Department of Energy. In 2005, the JIP drilled the Atwater Valley and Keathley Canyon exploration blocks in the Gulf of Mexico to acquire downhole logs and recover cores in silt- and clay-dominated sediments interpreted to contain gas hydrate based on analysis of existing 3-D seismic data prior to drilling. The new 2007-2009 phase of logging and coring, which is described in this paper, will concentrate on gas hydrate-bearing sands in the Alaminos Canyon, Green Canyon, and Walker Ridge protraction areas. Locations were selected to target higher permeability, coarser-grained lithologies (e.g., sands) that have the potential for hosting high saturations of gas hydrate and to assist the U.S. Minerals Management Service with its assessment of gas hydrate resources in the Gulf of Mexico. This paper discusses the scientific objectives for drilling during the upcoming campaign and presents the results from analyzing existing seismic and well log data as part of the site selection process. Alaminos Canyon 818 has the most complete data set of the selected blocks, with both seismic data and comprehensive downhole log data consistent with the occurrence of gas hydrate-bearing sands. Preliminary analyses suggest that the Frio sandstone just above the base of the gas hydrate stability zone may have up to 80% of the available sediment pore space occupied by gas hydrate. The proposed sites in the Green Canyon and Walker Ridge areas are also interpreted to have gas hydrate-bearing sands near the base of the gas hydrate stability zone, but the choice of specific drill sites is not yet complete. The Green Canyon site coincides with a 4-way closure within a Pleistocene sand unit in an area of strong gas flux just south of the Sigsbee Escarpment. The Walker Ridge site is characterized by a sand-prone sedimentary section that rises stratigraphically across the base of the gas hydrate stability zone and that has seismic indicators of gas hydrate.

Conference Paper↗

USGS2008

Site selection for DOE/JIP gas hydrate drilling in the northern Gulf of Mexico

In the late spring of 2008, the Chevron-led Gulf of Mexico Gas Hydrate Joint Industry Project (JIP) expects to conduct an exploratory drilling and logging campaign to better understand gas hydrate-bearing sands in the deepwater Gulf of Mexico. The JIP Site Selection team selected three areas to test alternative geological models and geophysical interpretations supporting the existence of potential high gas hydrate saturations in reservoir-quality sands. The three sites are near existing drill holes which provide geological and geophysical constraints in Alaminos Canyon (AC) lease block 818, Green Canyon (GC) 955, and Walker Ridge (WR) 313. At the AC818 site, gas hydrate is interpreted to occur within the Oligocene Frio volcaniclastic sand at the crest of a fold that is shallow enough to be in the hydrate stability zone. Drilling at GC955 will sample a faulted, buried Pleistocene channel-levee system in an area characterized by seafloor fluid expulsion features, structural closure associated with uplifted salt, and abundant seismic evidence for upward migration of fluids and gas into the sand-rich parts of the sedimentary section. Drilling at WR313 targets ponded sheet sands and associated channel/levee deposits within a minibasin, making this a non-structural play. The potential for gas hydrate occurrence at WR313 is supported by shingled phase reversals consistent with the transition from gas-charged sand to overlying gas-hydrate saturated sand. Drilling locations have been selected at each site to 1) test geological methods and models used to infer the occurrence of gas hydrate in sand reservoirs in different settings in the northern Gulf of Mexico; 2) calibrate geophysical models used to detect gas hydrate sands, map reservoir thicknesses, and estimate the degree of gas hydrate saturation; and 3) delineate potential locations for subsequent JIP drilling and coring operations that will collect samples for comprehensive physical property, geochemical and other analyses

Gulf of Mexico↗

USGS2008

Climate change and global carbon cycle: Perspectives and opportunities

The relevance of methane hydrates research to broader societal themes is often framed in terms of methane’s role in the global carbon cycle and its potential contribution to future climate change. To date, investigations of these fundamental issues have remained largely disconnected from applied studies focused on locating natural gas hydrate deposits, developing production technologies, and analyzing and mitigating hydrate-related geohazards. The 2005 reauthorization of the 2000 Methane Hydrate Research and Development Act provides broad latitude for better integration of applied and basic research related to methane hydrates, the carbon cycle, and climate change through its direction “to assess and to mitigate the environmental impact of hydrate degassing.” This mandate includes sponsoring research that evaluates whether methane hydrate degassing triggered by either natural or anthropogenic perturbations will (1) contribute to global climate change and (2) release significant quantities of currently sequestered carbon to the ocean-atmosphere system. This article provides an overview of progress and challenges in these areas and sets the stage for future research on related issues under the auspices of the Methane Hydrate Act.

Fire in the Ice: NETL Methane Hydrate Newsletter↗

USGS2007

Triggering mechanism and tsunamogenic potential of the Cape Fear Slide complex, U.S. Atlantic margin

Analysis of new multibeam bathymetry data and seismic Chirp data acquired over the Cape Fear Slide complex on the U.S. Atlantic margin suggests that at least 5 major submarine slides have likely occurred there within the past 30,000 years, indicating that repetitive, large-scale mass wasting and associated tsunamis may be more common in this area than previously believed. Gas hydrate deposits and associated free gas as well as salt tectonics have been implicated in previous studies as triggers for the major Cape Fear slide events. Analysis of the interaction of the gas hydrate phase boundary and the various generations of slides indicates that only the most landward slide likely intersected the phase boundary and inferred high gas pressures below it. For much of the region, we believe that displacement along a newly recognized normal fault led to upward migration of salt, oversteepening of slopes, and repeated slope failures. Using new constraints on slide morphology, we develop the first tsunami model for the Cape Fear Slide complex. Our results indicate that if the most seaward Cape Fear slide event occurred today, it could produce waves in excess of 2 m at the present-day 100 m bathymetric contour.

Cape Fear Slide↗

USGS2007

Characteristics of vesicomyid clams and their environment at the Blake Ridge cold seep, South Carolina, USA

Spatial distributions and patchiness of dominant megafaunal invertebrates in deep-sea seep environments may indicate heterogeneities in the flux of reduced chemical compounds. At the Blake Ridge seep off South Carolina, USA, the invertebrate assemblage includes dense populations of live vesicomyid clams (an undescribed species) as well as extensive clam shell beds (i.e. dead clams). In the present study, we characterized clam parameters (density, size-frequency distribution, reproductive condition) in relation to sulfur chemistry (sulfide and sulfate concentrations and isotopic compositions, pyrite and elemental sulfur concentrations) and other sedimentary metrics (grain size, organic content). For clams >5 mm, clam density was highest where the total dissolved sulfide concentration at 10 cm depth (ΣH 2 S 10cm ) was 0.4 to 1.1 mmol l –1 ; juvenile clams (<5 mm) were most dense where ΣH 2 S 10cm was lowest. Clams were reproductively capable across a broad range of ΣH 2 S 10cm (0.1 to 6.4 mmol l –1 ), and females in the sampled populations displayed asynchronous gametogenesis. Sulfide concentrations in porewaters at the shell–sediment interface of cores from shell beds were high, 3.3 to 12.1 mmol l –1 , compared to <1 mmol l –1 sulfide concentrations at the clam–sediment interface in live clam beds. Concentration profiles for sulfide and sulfate in shell beds were typical of those expected where there is active microbial sulfate reduction. In clam beds, profiles of sulfide and sulfate concentrations were also consistent with rapid uptake of sulfide by the clams. Sulfate in shell beds was systematically enriched in 34 S relative to that in clam beds due to microbial fractionation during sulfate reduction, but in clam beds, sulfate δ 34 S matched that of seawater (~20‰). Residual sulfide values in clam and shell beds were correspondingly depleted in 34 S. Based on porewater sulfide concentrations in shell beds at the time of sampling, we suggest that clam mortality may have been due to an abrupt increase in sulfide concentration and sulfide toxicity, but other alternatives cannot be eliminated.

California↗