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Carol Kendall

Publications and source records attributed to Carol Kendall.

At least 55 records · Page 3Linked to original sources
USGS2004

Isotopic views of food web structure in the Florida Everglades

Introduction Nearly one million acres of the Everglades are under a health advisory that discourages the human consumption of largemouth bass and several other fish because of high mercury contents. Food web structure (base of food web, number of trophic steps) plays a potentially critical role in determining the patterns of mercury contamination of the Everglades ecosystem. Methylmercury (MeHg) is present in low concentrations in water, yet after entering the base of the food web it biomagnifies to toxic concentrations in organisms that occupy higher trophic positions (like bass). One of the main research questions under investigation by a multi-agency task force in the Everglades is how MeHg bioaccumulates up the food chain in this complex aquatic ecosystem. Understanding variations in food web structure may help explain mercury patterns in the Everglades and ultimately lead to more effective restoration of Everglades ecosystems.

Florida↗
USGS2004

Sources and Transport of Nutrients, Organic Carbon, and Chlorophyll-a in the San Joaquin River Upstream of Vernalis, California, during Summer and Fall, 2000 and 2001

Oxidizable materials from the San Joaquin River upstream of Vernalis can contribute to low dissolved oxygen episodes in the Stockton Deep Water Ship Channel that can inhibit salmon migration in the fall. The U.S. Geological Survey collected and analyzed samples at four San Joaquin River sites in July through October 2000 and June through November 2001, and at eight tributary sites in 2001. The data from these sites were supplemented with data from samples collected and analyzed by the University of California at Davis at three San Joaquin River sites and eight tributary sites as part of a separate study. Streamflows in the San Joaquin River were slightly above the long-term average in 2000 and slightly below average in 2001. Nitrate loads at Vernalis in 2000 were above the long-term average, whereas loads in 2001 were close to average. Total nitrogen loads in 2000 were slightly above average, whereas loads in 2001 were slightly below average. Total phosphorus loads in 2000 and 2001 were well below average. These nutrient loads correspond with the flow-adjusted concentration trends--nitrate concentrations significantly increased since 1972 (p < 0.01), whereas total nitrogen and total phosphorus concentrations did not (p > 0.05). Loading rates of nutrients and dissolved organic carbon increased in the San Joaquin River in the fall with the release of wetland drainage into Mud Slough and with increased reservoir releases on the Merced River. During August 2000 and September 2001, the chlorophyll-a loading rates and concentrations in the San Joaquin River declined and remained low during the rest of the sampling period. The most significant tributary sources of nutrients were the Tuolumne River, Harding Drain, and Mud Slough. The most significant tributary sources of dissolved organic carbon were Salt Slough, Mud Slough, and the Tuolumne and Stanislaus Rivers. Compared with nutrients and dissolved organic carbon, the tributaries were minor sources of chlorophyll-a, suggesting that most of the chlorophyll-a was produced in the San Joaquin River rather than its tributaries. On the basis of the carbon-to-nitrogen ratios and the d13C of particulate organic matter in the San Joaquin River and tributaries, the particulate organic matter in the river was mostly phytoplankton. On the basis of the d15N values of the particulate organic matter, and of total dissolved nitrogen and nitrate, the nitrate in the San Joaquin River probably was a significant nutrient source for the phytoplankton. The range of d15N and d18O values of nitrate in the San Joaquin River and tributaries suggest that animal waste or sewage was a significant source of nitrate in the river at the time the samples were collected.

Water-Resources Investigations Report↗
USGS2003

Shallow water table fluctuations in relation to soil penetration resistance

Hydrologic modeling of catchments is frequently hampered by lack of information on subsurface stratigraphy and zones of preferred flow. We evaluated the usefulness of soil penetration resistance, easily measured by a dynamic cone penetrometer, together with measurements of ground water level fluctuations, as a cost-effective means to infer subsurface flow patterns. At our field site at Sleepers River, Vermont, penetration resistance was lowest in the surficial 10 to 30 cm, then typically increased to a local maximum at 60 to 80 cm, which we interpreted as the soil/till interface. Below this depth usually lies a zone of decreased resistance in the till, giving way to either a gradual or abrupt increase in resistance toward the bedrock surface at 1 to 4.5 m depth. Penetration resistance had a weak but significant negative correlation with saturated hydraulic conductivity determined by bail tests (r 2 = 0.25, p < 0.05). At many wells, monthly ground water levels tended to cluster at or just above the resistant zone near the soil/till interface. Chemical and isotopic dynamics in nested wells finished above and below the resistant zone suggest that the zone may temporarily isolate the deeper ground water reservoir from meltwater inputs, which were clearly identified by low δ 18 O values. In ground water discharge zones, δ 18 O values tended to converge throughout the profile. In contrast, dissolved organic carbon (DOC) maintained a gradient of increasing concentration toward land surface, even in otherwise well-mixed waters, reflecting its rapid release from organic horizons. Understanding the effect of soil penetration resistance on ground water behavior may be useful in future catchment modeling efforts.

Vermont↗
USGS2002

Analysis of δ15N and δ18O to differentiate NO3− sources in runoff at two watersheds in the Catskill Mountains of New York

To quantify the movement of atmospheric nitrogen deposition through two forested watersheds in the Catskill Mountains of New York, dual‐isotope analysis (δ 15 N and δ 18 O) was used to differentiate NO 3 − derived from precipitation from NO 3 − derived by microbial nitrification and to quantify the contributions of these sources to NO 3 − in drainage waters. Samples of stream water, soil water, precipitation, snowmelt, and O‐horizon soil were collected during the March and April snowmelt period of 1994 and throughout an 18‐month period from August 1995 through February 1997. The mean δ 18 O‐NO 3 − value of precipitation was +50.5‰, whereas the mean values for stream water and soil water were +17.7‰ and +23.6‰, respectively. The mean δ 15 N‐NO 3 − of precipitation was −0.2‰, that of soil water was +1.4‰, and that of stream water was +2.3‰; these values showed greater overlap among the three different waters than did the δ 18 O‐NO 3 − values, indicating that δ 15 N‐NO 3 − was not as useful for source separation. Soil water δ 18 O‐NO 3 − values decreased, and δ 15 N‐NO 3 − values increased, from the O to the B and C horizons, but most of the differences among horizons were not statistically significant. Nitrate derived by nitrification in incubated soil samples had a wide range of δ 15 N‐NO 3 − values, from +1.5‰ to +16.1‰, whereas δ 18 O‐NO 3 − values ranged more narrowly, from +13.2‰ to +16.0‰. Values of δ 18 O‐NO 3 − indicated that NO 3 − in stream water is mainly derived from nitrification. Only during a high‐flow event that exceeded the annual flood was precipitation a major contributor to stream water NO 3 − . Values of δ 18 O‐NO 3 − and δ 15 N‐NO 3 − changed at differing rates as NO 3 − cycled through these watersheds because δ 18 O‐NO 3 − values change sharply through the incorporation of oxygen from ambient water and gas during nitrification, whereas δ 15 N‐NO 3 − values change only incrementally through fractionation during biocycling processes. The results of this study show that most NO 3 − is first cycled through the biota and nitrified before entering the stream.

Water Resources Research↗
USGS2002

Pathways for nitrate release from an alpine watershed: Determination using δ15N and δ18O

Snowpack, snowmelt, precipitation, surface water, and groundwater samples from the Loch Vale watershed in Colorado were analyzed for δ 15 N and δ 18 O of nitrate to determine the processes controlling the release of atmospherically deposited nitrogen from alpine and subalpine ecosystems. Although overlap was found between the δ 15 N (NO3) values for all water types (−4 to +6‰), the δ 18 O (NO3) values for surface water and groundwater (+10 to +30‰) were usually distinct from snowpack, snowmelt, and rainfall values (+40 to +70‰). During snowmelt, δ 18 O (NO3) indicated that about half of the nitrate in stream water was the product of microbial nitrification; at other times that amount was greater than half. Springs emerging from talus deposits had high nitrate concentrations and a seasonal pattern in δ 18 O (NO3) that was similar to the pattern in the streams, indicating that shallow groundwater in talus deposits is a likely source of stream water nitrate. Only a few samples of surface water and groundwater collected during early snowmelt and large summer rain events had isotopic compositions that indicated most of the nitrate came directly from atmospheric deposition with no biological assimilation and release. This study demonstrates the value of the nitrate double‐isotope technique for determining nitrogen‐cycling processes and sources of nitrate in small, undisturbed watersheds that are enriched with inorganic nitrogen.

Water Resources Research↗
USGS2001

Chemical and isotopic evidence of nitrogen transformation in the Mississippi River, 1997-98

Nitrate (NO 3 ) and other nutrients discharged by the Mississippi River are suspected of causing a zone of depleted dissolved oxygen (hypoxic zone) in the Gulf of Mexico each summer. The hypoxic zone may have an adverse affect on aquatic life and commercial fisheries. The amount of NO 3 delivered by the Mississippi River to the Gulf of Mexico is well documented, but the relative contributions of different sources of NO 3 , and the magnitude of subsequent in-stream transformations of NO 3 , are not well understood. Forty-two water samples collected in 1997 and 1998 at eight stations located either on the Mississippi River or its major tributaries were analysed for NO 3 , total nitrogen (N), atrazine, chloride concentrations and NO 3 stable isotopes (δ 15 N and δ 18 O). These data are used to assess the magnitude and nature of in-stream N transformation and to determine if the δ 15 N and δ 18 O of NO 3 provide information about NO 3 sources and transformation processes in a large river system (drainage area 2 900 000 km 2 ) that would otherwise be unavailable using concentration and discharge data alone. Results from 42 samples indicate that the δ 15 N and δ 18 O ratios between sites on the Mississippi River and its tributaries are somewhat distinctive, and vary with season and discharge rate. Of particular interest are two nearly Lagrangian sample sets, in which samples from the Mississippi River at St Francisville, LA, are compared with samples collected from the Ohio River at Grand Chain, II, and the Mississippi River at Thebes, IL. In both Lagrangian sets, mass-balance calculations indicate only a small amount of in-stream N loss. The stable isotope data from the samples suggest that in-stream N assimilation and not denitrification accounts for most of the N loss in the lower Mississippi River during the spring and early summer months.

Illinois, Iowa, Kentucky, Louisiana, Mississippi, ↗
USGS2001

Distribution of oxygen-18 and deuteriun in river waters across the United States

Reconstruction of continental palaeoclimate and palaeohydrology is currently hampered by limited information about isotopic patterns in the modern hydrologic cycle. To remedy this situation and to provide baseline data for other isotope hydrology studies, more than 4800, depth- and width-integrated, stream samples from 391 selected sites within the USGS National Stream Quality Accounting Network (NASQAN) and Hydrologic Benchmark Network (HBN) were analysed for &delta; 18 O and &delta; 2 H ( http://water.usgs.gov/pubs/ofr/ofr00-160/pdf/ofr00-160.pdf ). Each site was sampled bimonthly or quarterly for 2&middot;5 to 3 years between 1984 and 1987. The ability of this dataset to serve as a proxy for the isotopic composition of modern precipitation in the USA is supported by the excellent agreement between the river dataset and the isotopic compositions of adjacent precipitation monitoring sites, the strong spatial coherence of the distributions of &delta; 18 O and &delta; 2 H, the good correlations of the isotopic compositions with climatic parameters, and the good agreement between the &lsquo;national&rsquo; meteoric water line (MWL) generated from unweighted analyses of samples from the 48 contiguous states of &delta; 2 H=8&middot;11&delta; 18 O+8&middot;99 ( r 2 =0&middot;98) and the unweighted global MWL of sites from the Global Network for Isotopes in Precipitation (GNIP) of the International Atomic Energy Agency and the World Meteorological Organization (WMO) of &delta; 2 H=8&middot;17&delta; 18 O+10&middot;35. The national MWL is composed of water samples that arise in diverse local conditions where the local meteoric water lines (LMWLs) usually have much lower slopes. Adjacent sites often have similar LMWLs, allowing the datasets to be combined into regional MWLs. The slopes of regional MWLs probably reflect the humidity of the local air mass, which imparts a distinctive evaporative isotopic signature to rainfall and hence to stream samples. Deuterium excess values range from 6 to 15&permil; in the eastern half of the USA, along the northwest coast and on the Colorado Plateau. In the rest of the USA, these values range from &minus;2 to 6&permil;, with strong spatial correlations with regional aridity. The river samples have successfully integrated the spatial variability in the meteorological cycle and provide the best available dataset on the spatial distributions of &delta; 18 O and &delta; 2 H values of meteoric waters in the USA.

Hydrological Processes↗
USGS2000

Nitrate isotopes in groundwater systems

Nitrate contamination, often associated with agricultural activities, is a major problem in some shallow aquifers and is increasingly becoming a threat to groundwater supplies (Gillham and Cherry, 1978; Ronen et al. , 1983; Spalding and Exner, 1991). The intake of high levels of nitrate can cause methemoglobinemia in infants, and there is substantial evidence collected from animal experiments that N-nitroso compounds are carcinogens. Similar conclusive evidence is not yet available for humans but many observations suggest that these compounds can function as initiators of human carcinogenesis. These findings are the basis for the maximum permissible limit of 10 ppm nitrate-N (50 ppm as NO 3 ) in drinking water set by the World Health Organization and the U.S. Environmental Protection Agency. The impact of high loading of nutrients such as nitrate and phosphorous from agricultural practices via groundwater into surface water is also a major environmental concern, causing eutrophication of streams, rivers and lakes (Hill, 1978; Böhlke and Denver, 1995).

Book chapter↗
USGS2000

Determination of hydrologic pathways during snowmelt for alpine/subalpine basins, Rocky Mountain National Park, Colorado

Alpine/subalpine ecosystems in Rocky Mountain National Park may be sensitive to atmospherically derived acidic deposition. Two‐ and three‐component hydrograph separation analyses and correlation analyses were performed for six basins to provide insight into streamflow generation during snowmelt and to assess basin sensitivity to acidic deposition. Three‐component hydrograph separation results for five basins showed that streamflow contained from 42 to 57% direct snowmelt runoff, 37 to 54% subsurface water, and 4 to 13% direct rain runoff for the May through October 1994 study period. Subsurface contributions were 89% of total flow for the sixth basin. The reliability of hydrograph separation model assumptions was explored. Subsurface flow was positively correlated with the amount of surficial material in a basin and was negatively correlated with basin slope. Basins with extensive surficial material and shallow slopes are less susceptible to ecosystem changes due to acidic deposition than basins with less surficial material and steeper slopes. This study was initiated to expand the intensive hydrologic research that has been conducted in Loch Vale basin to a more regional scale.

Water Resources Research↗
USGS2000

Stable hydrogen and oxygen isotope ratios for selected sites of the U.S. Geological Survey's NASQAN and benchmark surface-water networks

Increasingly, hydrologic studies require information on the isotopic composition of natural waters. This report presents stable hydrogen (delta2H) and oxygen isotope ratios (delta18O) from 391 selected sites of the U.S. Geological Survey's National Stream Quality Accounting Network (NASQAN) and BENCHMARK surface water networks collected during the years 1984-1987. Depth-integrated samples were collected and analyzed from each site bimonthly or quarterly for about 3 years.

Open-File Report↗
USGS1998

Fundamentals of isotope geochemistry

The dominant use of isotopes in catchment research in the last few decades has been to trace sources of waters and solutes. Generally, such data were evaluated with simple mixing models to determine how much was derived from either of the two (sometimes three) constant-composition sources. This chapter illustrates the environmental isotopes that are natural and anthropogenic isotopes whose wide distribution in the hydrosphere can assist in the solution of hydrogeochemical problems. Water isotopes often provide unambiguous information about residence times and relative contributions from different water sources, and these data can then be used to make hypotheses about water flowpaths. Solute isotopes can provide an alternative, independent isotopic method for determining the relative amounts of water flowing along various subsurface flowpaths. The isotopic and chemical compositions provides very detailed information about sources and reactions in shallow systems This integration of chemical and isotopic data with complex hydrologic models constitutes an important frontier of catchment research.

Book chapter↗
USGS1998

Tracing nitrogen sources and cycling in catchments

This chapter focuses on the uses of isotopes to understand water chemistry.I Isotopic compositions generally cannot be interpreted successfully in the absence of other chemical and hydrologic data. The chapter focusses on uses of isotopes in tracing sources and cycling of nitrogen in the water-component of forested catchment, and on dissolved nitrate in shallow waters, nutrient uptake studies in agricultural areas, large-scale tracer experiments, groundwater contamination studies, food-web investigations, and uses of compound-specific stable isotope techniques. Shallow waters moving along a flowpath through a relatively uniform material and reacting with minerals probably do not achieve equilibrium but gradually approach some steady-state composition. The chapter also discusses the use of isotopic techniques to assess impacts of changes in land-management practices and land use on water quality. The analysis of individual molecular components for isotopic composition has much potential as a method for tracing the source, biogeochemistry, and degradation of organic liquids and gases because different materials have characteristic isotope spectrums or biomarkers.

Book chapter↗
USGS1998

Tracing of weathering reactions and water flowpaths: A multi-isotope approach

This chapter discusses the importance of using isotopes in a complementary manner, primarily to constrain and enrich models developed from hydrologic and chemical data. Isotopes are viewed as tools for testing rather than developing hypotheses, particularly in studies operating under tight budgetary constraints. Water isotopes are very useful tools for determining water sources in catchments. Chemical tracers are very useful for understanding the reactions along flowpaths. The potential application of Fe isotopes to catchment studies lies in the assumption that Fe mobilized inorganically from minerals under either reducing or low-pH conditions will have a different isotopic composition than microbially-reduced Fe. To the extent that certain zones or flowpaths in the catchment can be characterized by microbial cycling of labile Fe, the Fe isotopes may provide an effective tracer of contributions from these pathways. The solute isotopes, for example, strontium, carbon, and lead are as yet under-utilized in catchment research compared to the water isotopes.

Book chapter↗
USGS1998

Isotopes as indicators of environmental change

In addition to providing an understanding of processes within a catchment system, isotopic techniques have been instrumental in providing reconstructions of catchment climate and other environmental indicators at various time scales. Many recent changes are a direct consequence of anthropogenic activities. Isotopic analysis serves as a valuable tool for distinguishing between natural variations in long-term climatic patterns and anthropogenic effects, yielding improved understanding of natural feedback mechanisms and the development of realistic remediation strategies. This chapter discusses the examples of isotopic techniques that have been applied to understand several types of ongoing and recent environmental changes, and in paleo-environmental studies. It discusses isotope geochemistry, hydrology, and climatology to look at new ways of applying isotopic tracing techniques to provide information on environmental change. It also gives an overview on how isotopic indicators are being applied in investigations of environmental change in continental settings.

Book chapter↗
USGS1995

Water, energy, and biogeochemical budget research at Sleepers River Research Watershed, Vermont

The U.S. Geological Survey has selected the Sleepers River Research Watershed (Sleepers River) near Danville, Vt., as one of five sites for the investigation of Water, Energy, and Biogeochemical Budgets (WEBB). Sleepers River was chosen because it is a well-designed outdoor laboratory with a long history of hydrologic data collection and research, and also because it provides an ideal opportunity for collaboration among the U.S. Geological Survey, other Federal agencies, and universities at the site. The multiple subwatersheds at Sleepers River present a unique opportunity to investigate hydrologic, energy, and biogeochemical processes over a variety of spatial scales. This WEBB study builds on fundamental research on process mechanisms and rates at the plot scale (in this case, a hillslope). Results then are scaled up to interpret the hydrochemical response of first- and higher- order basins. Five research elements make up the Sleepers River WEBB project. Individually, each of the five elements is designed to investigate specific WEBB processes (such as CO2 efflux through a snowpack), address specific WEBB issues (such as scaling and flowpaths), or apply specific WEBB approaches (such as integrated chemical and physical study of a hillslope). The research elements overlap so that many of the processes investigated will be assessed in more than one way, thus allowing independent verification of research results. For example, flowpath information will be derived separately by use of isotopic tracers, conservative chemical solutes, and soil-moisture fluxes. Collectively, the five elements constitute an integrated approach to a comprehensive understanding of WEBB processes needed for the prediction of the effects of global change.

Open-File Report↗
USGS1995

Applications of isotopes to tracing sources of solutes and water in shallow systems

New awareness of the potential danger to water supplies posed by the use of agricultural chemicals has focused attention on the nature of groundwater recharge and the mobility of various solutes, especially nitrate and pesticides, in shallow systems. A better understanding of hydrologic flowpaths and solute sources is required to determine the potential impact of sources of contamination on water supplies, to develop management practices for preserving water quality, and to develop remediation plans for sites that are already contaminated. In many cases, environmental isotopes can be employed as 'surgical tools' for answering very specific questions about water and solute sources. Isotopic data can often provide more accurate information about the system than hydrologic measurements or complicated hydrologic models. This note focuses on practical and cost-effective examples of how naturally-occurring isotopes can be used to track water and solutes as they move through shallow systems.

Conference Paper↗