Geology topics

Carma A. San Juan

Publications and source records attributed to Carma A. San Juan.

At least 19 recordsLinked to original sources

USGS2025

The abandoned mine inventory of the United States—A brief summary

The Infrastructure Investment and Jobs Act of 2021 required the Secretary of the Interior to establish a program to inventory abandoned hard-rock mines in the United States. The Department of the Interior’s Office of Environmental Policy and Compliance asked the U.S. Geological Survey’s Mineral Deposit Database project (USMIN) to use existing data sources to build an inventory of all individual abandoned mine features in the United States. In addition to feature locations, this new database documents the surface land management agency, associated physical and environmental hazards, and any completed mitigation efforts. This information will improve risk assessment and support land management efforts, including hazard mitigation, ecosystem restoration planning, and reclamation. This fact sheet provides a brief overview of USMIN’s collaborative efforts with Federal, State, and Tribal agencies to build a comprehensive and authoritative national inventory of abandoned mine features.

Fact Sheet↗

USGS2022

Data-driven prospectivity modelling of sediment-hosted Zn-Pb mineral systems and their critical raw materials

Demand for critical raw materials is expected to accelerate over the next few decades due to continued population growth and the shifting consumption patterns of the global economy. Sedimentary basins are important sources for critical raw materials and new discoveries of sediment–hosted Mississippi Valley–type (MVT) and/or clastic–dominated (CD) Zn–Pb deposits are likely required to mitigate future supply chain disruptions for Zn, Pb, Ag, Cd, Ga, Ge, Sb, and In. Herein we integrate public geoscience datasets using a discrete global grid to system to model the mineral potential for MVT and CD deposits across Canada, the United States of America, and Australia. Statistical analysis of the model results demonstrates that surface–wave tomography and derivative products from satellite gravity datasets can be used to map the most favourable paleo–tectonic settings of MVT and CD deposits inboard of orogenic belts and at the rifted edges of cratonic lithosphere, respectively. Basin development at pre–existing crustal boundaries was likely important for maintaining the low geothermal–gradients that are favourable for metal transport and generating the crustal fluid pathways that were reactivated during ore–formation, as suggested by the statistical association of both sediment–hosted mineral deposit types with the edges of upward–continued gravity and long–wavelength magnetic anomalies. Multivariate statistical analysis demonstrates that the most prospective combination of these geophysical datasets varies for each geological region and deposit type. We further demonstrate that maximum and minimum geological ages, coupled with Phanerozoic paleogeographic reconstructions, represent mappable proxies for the availability of oxidized, brine–generating regions that are the most likely source of ore–forming fluids (e.g., low– to mid–latitude carbonate platforms and evaporites). Ore deposition was likely controlled by interaction between oxidized, low–temperature brines and sulfidic and/or carbonaceous rocks, which, in some cases, can be mapped at the exposed surface or identified using the available rock descriptions. Baseline weights–of–evidence models are based on regional geophysics and are the least impacted by missing surface information but yield relatively poor results, as demonstrated by the low area–under–the–curve (AUC) for the spatially independent test set on the success–rate plot (AUC = 0.787 for MVT and AUC = 0.870 for CD). Model performance can be improved by: (1) using advanced methods that were trained and validated during a series of semi–automated machine learning competitions; and/or (2) incorporating geological and geophysical datasets that are proxies for each component of the mineral system. The best–performing gradient boosting machine models yield higher AUC for the test set (AUC = 0.983 for MVT and AUC = 0.991 for CD) and reduce the search space by >94%. The model results highlight the potential benefits of mapping sediment–hosted mineral systems at continental scale to improve mineral exploration targeting for critical raw materials.

Ore Geology Reviews↗

USGS2021

Data-driven prospectivity modelling of sediment-hosted mineral systems

Mississippi Valley-type (MVT) and clastic-dominated (CD) deposits are important sources for Zn, Pb, Ag, and Cd as well as the critical elements Ga, Ge, In, and Sb. However, mapping the drivers, sources, pathways, and traps of MVT and CD deposits within the much larger and mostly unmineralized sedimentary basins remain some of the least understood aspects of these mineral systems. Herein we address those knowledge gaps by integrating public geoscience datasets from Canada, the United States of America, and Australia using a discrete global grid system to map the continent-scale footprints of MVT and CD deposits.

Conference Paper↗

USGS2021

The critical minerals initiative of the U.S. Geological Survey’s mineral deposit database project: USMIN

The objective of the US Geological Survey’s mineral deposit database project (USMIN) is to develop a comprehensive twenty-first century geospatial database that is the authoritative source of the most important mines, mineral deposits, and mineral districts of the US. Since May 2017, the project has focused on critical minerals. Data for critical minerals that are produced as products are relatively robust, whereas data for critical minerals that may be recovered as byproducts are commonly of much poorer quality. Similarly, more is known about critical minerals that occur in conventional deposits than where those critical minerals occur in unconventional deposits. For example, rare earth elements occur principally in deposits hosted by alkaline igneous rocks, but there is potential for their production from phosphate rock mining, which is less documented. Lithium (Li) has been recovered from pegmatites and brines, but other Li-bearing deposit types have been delineated that may go into production. Cobalt may be produced as a byproduct or coproduct from a wide range of mineral deposit types, whereas rhenium is a byproduct of copper ore. Significant opportunities for research exist that could help identify new sources of critical minerals, and may also help increase production and recovery from existing sources.

Mining, Metallurgy & Exploration (MME)↗

USGS2020

Pyrrhotite distribution in the conterminous United States, 2020

In parts of Connecticut and Massachusetts, foundations of some homes are cracking and crumbling. Failing foundations can reduce the market value of a home and lifting a house to replace and repour a foundation is an expensive undertaking. In response, some homeowners are defaulting on their mortgages and abandoning their homes. The culprit is pyrrhotite, which occurs in construction aggregate (crushed stone) that was used as a filler in concrete. When pyrrhotite is naturally exposed to water and oxygen, it breaks down to produce sulfuric acid and secondary minerals, including gypsum, which have larger volumes than the pyrrhotite they replace. The expanded volume of the secondary minerals cracks and degrades concrete. Pyrrhotite occurs in rocks in many areas of the United States. To help assess the national risk of pyrrhotite in aggregate, the fiscal year 2019 appropriations bill for the U.S. Geological Survey’s (USGS) Mineral Resources Program allocated funds to develop a map showing the distribution of pyrrhotite across the United States. The purpose of this fact sheet is to (1) present a nationwide map that shows where pyrrhotite may occur in rocks in the United States, (2) describe and discuss the factors that control the presence and abundance of pyrrhotite in rocks, (3) provide information on geographic information system datasets that deliver more detailed information on these distributions, and (4) describe U.S. and international standards on aggregate that are designed to prevent failing concrete. While this map and fact sheet provide general information about the possible distribution of pyrrhotite in the United States, they are no substitute for site-specific characterization and quality control programs designed to ensure that aggregate used in concrete is of appropriate quality for its intended purpose.

Conterminous United States↗

USGS2017

The State Geologic Map Compilation (SGMC) geodatabase of the conterminous United States

The State Geologic Map Compilation (SGMC) geodatabase of the conterminous United States (https://doi. org/10.5066/F7WH2N65) represents a seamless, spatial database of 48 State geologic maps that range from 1:50,000 to 1:1,000,000 scale. A national digital geologic map database is essential in interpreting other datasets that support numerous types of national-scale studies and assessments, such as those that provide geochemistry, remote sensing, or geophysical data. The SGMC is a compilation of the individual U.S. Geological Survey releases of the Preliminary Integrated Geologic Map Databases for the United States. The SGMC geodatabase also contains updated data for seven States and seven entirely new State geologic maps that have been added since the preliminary databases were published. Numerous errors have been corrected and enhancements added to the preliminary datasets using thorough quality assurance/quality control procedures. The SGMC is not a truly integrated geologic map database because geologic units have not been reconciled across State boundaries. However, the geologic data contained in each State geologic map have been standardized to allow spatial analyses of lithology, age, and stratigraphy at a national scale.

Data Series↗

USGS2016

Geology and mineral resources of the North-Central Idaho Sagebrush Focal Area: Chapter C in Mineral resources of the Sagebrush Focal Areas of Idaho, Montana, Nevada, Oregon, Utah, and Wyoming

Summary The U.S. Department of the Interior has proposed to withdraw approximately 10 million acres of Federal lands from mineral entry (subject to valid existing rights) from 12 million acres of lands defined as Sagebrush Focal Areas (SFAs) in Idaho, Montana, Nevada, Oregon, Utah, and Wyoming (for further discussion on the lands involved see Scientific Investigations Report 2016–5089–A). The purpose of the proposed action is to protect the greater sage-grouse ( Centrocercus urophasianus ) and its habitat from potential adverse effects of locatable mineral exploration and mining. The U.S. Geological Survey Sagebrush Mineral-Resource Assessment (SaMiRA) project was initiated in November 2015 and supported by the Bureau of Land Management to (1) assess locatable mineral-resource potential and (2) to describe leasable and salable mineral resources for the seven SFAs and Nevada additions. This chapter summarizes the current status of locatable, leasable, and salable mineral commodities and assesses the potential of locatable minerals in the North-Central Idaho SFA, which extends from east-central to south-central Idaho. The geologically complex area is composed of many different rock units that locally contain potential mineral resources.

Idaho↗

USGS2016

Geology and mineral resources of the North-Central Montana Sagebrush Focal Area: Chapter D in Mineral resources of the Sagebrush Focal Areas of Idaho, Montana, Nevada, Oregon, Utah, and Wyoming

Summary The U.S. Department of the Interior has proposed to withdraw approximately 10 million acres of Federal lands from mineral entry (subject to valid existing rights) from 12 million acres of lands defined as Sagebrush Focal Areas (SFAs) in Idaho, Montana, Nevada, Oregon, Utah, and Wyoming (for further discussion on the lands involved see Scientific Investigations Report 2016–5089–A). The purpose of the proposed action is to protect the greater sage-grouse ( Centrocercus urophasianus ) and its habitat from potential adverse effects of locatable mineral exploration and mining. The U.S. Geological Survey Sagebrush Mineral-Resource Assessment (SaMiRA) project was initiated in November 2015 and supported by the Bureau of Land Management to (1) assess locatable mineral-resource potential and (2) to describe leasable and salable mineral resources for the seven SFAs and Nevada additions. This chapter summarizes the current status of locatable, leasable, and salable mineral commodities and assesses the potential of locatable minerals in the North-Central Montana SFA. The proposed withdrawal area that is evaluated in this report is located in north-central Montana, and includes parts of Fergus, Petroleum, Phillips, and Valley Counties.

Montana↗

USGS2016

Anticipating environmental and environmental-health implications of extreme storms: ARkStorm scenario

The ARkStorm Scenario predicts that a prolonged winter storm event across California would cause extreme precipitation, flooding, winds, physical damages, and economic impacts. This study uses a literature review and geographic information system-based analysis of national and state databases to infer how and where ARkStorm could cause environmental damages, release contamination from diverse natural and anthropogenic sources, affect ecosystem and human health, and cause economic impacts from environmental-remediation, liability, and health-care costs. Examples of plausible ARkStorm environmental and health concerns include complex mixtures of contaminants such as petroleum, mercury, asbestos, persistent organic pollutants, molds, and pathogens; adverse physical and contamination impacts on riverine and coastal marine ecosystems; and increased incidences of mold-related health concerns, some vector-borne diseases, and valley fever. Coastal cities, the San Francisco Bay area, the Sacramento-San Joaquin River Delta, parts of the Central Valley, and some mountainous areas would likely be most affected. This type of screening analysis, coupled with follow-up local assessments, can help stakeholders in California and disaster-prone areas elsewhere better plan for, mitigate, and respond to future environmental disasters.

Natural Hazards Review↗

USGS2015

Geochemical, modal, and geochronologic data for 1.4 Ga A-type granitoid intrusions of the conterminous United States

Introduction The purpose of this report is to present available geochemical, modal, and geochronologic data for approximately 1.4 billion year (Ga) A-type granitoid intrusions of the United States and to make those data available to ongoing petrogenetic investigations of these rocks. A-type granites, as originally defined by Loiselle and Wones (1979), are iron-enriched granitoids (synonymous with the ferroan granitoids of Frost and Frost, 2011) that occur in an anorogenic, within-continent setting. Relative to other granitic rocks, A-type granites have high FeO*/(FeO*+MgO), high K 2 O and K 2 O/Na 2 O, are metaluminous to weakly peraluminous, and are enriched in incompatible trace elements. Loiselle and Wones (1979) further suggested that A-type granites are relatively anhydrous. Anderson (1983) provides an early compilation of data for the products of 1.4 Ga magmatism in North America and notes the spatial and temporal association of a trio of rock types, which includes gabbro to anorthosite, intermediate composition mangerite, and granitic rapakivi rocks. In North America, the majority of known A-type intrusions were emplaced between 1.5 and 1.3 Ga and are predominantly of the granitic variety (Anderson, 1983). This report addresses the broadly Mesoproterozoic-age granitic rocks of the conterminous United States. Constituents of this group of intrusive rocks were defined using a variety of spatial, compositional, and geochronologic metrics. Thomas and others (2012) provided an updated synthesis, largely based on new isotopic and geochronologic data (for example, Fisher and others, 2010), for the large-scale geologic and tectonic evolution of the eastern United States. Their findings suggest that the basement rocks of the central and southern Appalachian region are allochthonous relative to the remainder of Laurentia and were accreted along the Grenville front between 1.25 and 1.0 Ga. Accordingly, Mesoproterozoic rocks east of the Grenville front and south of the approximate latitude of New York City do not represent North American magmatism. Consequently, geochemical, modal, and geochronologic data for these rocks are not included in the compilation described herein. Further, the structural styles and compositions of granitoid rocks east of the Grenville front, mostly highly deformed gneissic rocks, are dissimilar to those characteristic of the A-type granitoid rocks described herein. A variety of compositional and age information further characterizes the 1.4 Ga A-type granitoid rocks in the conterminous United States. Most samples included in this compilation have felsic compositions, although some extend to intermediate compositions. SiO2 contents range from 56 to almost 78 weight percent, and median and mean SiO2 contents are 72.0 and 71.1 weight percent, respectively. The majority of these rocks for which modal data are available are composed of monzogranite (Streckeisen, 1976), although the dataset also contains many samples composed of granodiorite and syenogranite. A smaller group of the granitoid rocks in this dataset are composed of quartz monzodiorite and quartz monzonite, and a very small subset of samples is composed of alkali-feldspar granite, tonalite, alkali-feldspar quartz syenite, and quartz syenite (fig. 1). Many of the 1.4 Ga granitoid rocks are further characterized by medium- to coarse-grain size and are also conspicuously porphyritic; alkali feldspar phenocrysts or megacrysts (2–10 cm), often with rapakivi overgrowths, are a common feature of many of these rocks (Anderson, 1983; Anderson and Bender, 1989; Anderson and Cullers, 1978; Condie and Budding, 1979). The age of A-type magmatism in North America ranges from about 1.8 to 1.0 Ga, although Anderson (1983) suggests that more than 70 percent (by volume) of A-type magmatism in this region occurred between 1.49 and 1.41 Ga. In the conterminous United States, ages of A-type granitoid rocks are restricted to the period between about 1.49 and 1.33 Ga (Anderson, 1983; Bauer and Pollock, 1993; Bickford and Mose, 1975; Bickford, Harrower, and others, 1981; Bickford and others, 1989; Dewane and Van Schmus, 2007; Hoppe and others, 1983; Peterman and Hedge, 1968; Van Schmus and Bickford, 1981; Van Schmus and others, 1975). Using these recognition criteria, we identified A-type granitoid intrusions of the conterminous United States; for those intrusions, we compiled available geochemical, modal, isotopic (Sr and Nd) and geochronologic data for inclusion in the databases described herein. The significance of 1.4 Ga granitoid rocks relative to the geologic evolution of the conterminous United States remains unclear, despite Anderson’s (1983) compilation and synthesis of compositional data pertinent to these rocks. The large-volume magmatic events indicated by these rocks, as well as their broad geographic distribution, tectonic significance, and association with mineral deposits, underscore their importance. The broad distribution of these rocks, from the northern mid-continent to the southwestern United States (in New Mexico, Arizona, California, and southernmost Nevada), throughout the Rocky Mountains in New Mexico and Colorado (and sporadically in southern Wyoming and central Idaho), and beneath much of the Plains region (as indicated by drilling), has led to the large-scale tectonic and magmatic processes responsible for genesis of the associated magmas being actively studied. In addition, Kisvarsanyi (1972) suggests that iron-copper deposits in the St. Francois Mountains of southeastern Missouri are petrogenetically associated with 1.4 Ga A-type granitoids that occur in that region. Similarly, Dall’Agnol and others (2012) summarize important global associations between A-type granitoid rocks and a variety of important ore deposit types, particularly tin, high-field-strength elements (Zr, Hf, Nb, Ta), rare-earth elements, and iron oxide-copper-gold deposits. Consequently, the need to better understand relations between A-type granitoid rocks, tectonic setting, and magma petrogenesis, as well as their genetic associations with important types of ore deposits, suggests that developing a definitive geochemical, modal, and geochronologic database for these rocks in the conterminous United States is of considerable value.

Data Series↗

USGS2015

Basement domain map of the conterminous United States and Alaska

The basement-domain map is a compilation of basement domains in the conterminous United States and Alaska designed to be used at 1:5,000,000-scale, particularly as a base layer for national-scale mineral resource assessments. Seventy-seven basement domains are represented as eighty-three polygons on the map. The domains are based on interpretations of basement composition, origin, and architecture and developed from a variety of sources. Analysis of previously published basement, lithotectonic, and terrane maps as well as models of planetary development were used to formulate the concept of basement and the methodology of defining domains that spanned the ages of Archean to present but formed through different processes. The preliminary compilations for the study areas utilized these maps, national-scale gravity and aeromagnetic data, published and limited new age and isotopic data, limited new field investigations, and conventional geologic maps. Citation of the relevant source data for compilations and the source and types of original interpretation, as derived from different types of data, are provided in supporting descriptive text and tables. The tectonic settings for crustal types represented in the basement domains are subdivided into constituent geologic environments and the types of primary metals endowments and deposits in them are documented. The compositions, architecture, and original metals endowments are potentially important to assessments of primary mineral deposits and to the residence and recycling of metals in the crust of the United States portion of the North American continent. The databases can be configured to demonstrate the construction of the United States through time, to identify specific types of crust, or to identify domains potentially containing metal endowments of specific genetic types or endowed with specific metals. The databases can also be configured to illustrate other purposes chosen by users.

Data Series↗

USGS2012

Geologic processes influence the effects of mining on aquatic ecosystems

Geologic processes strongly influence water and sediment quality in aquatic ecosystems but rarely are geologic principles incorporated into routine biomonitoring studies. We test if elevated concentrations of metals in water and sediment are restricted to streams downstream of mines or areas that may discharge mine wastes. We surveyed 198 catchments classified as “historically mined” or “unmined,” and based on mineral-deposit criteria, to determine whether water and sediment quality were influenced by naturally occurring mineralized rock, by historical mining, or by a combination of both. By accounting for different geologic sources of metals to the environment, we were able to distinguish aquatic ecosystems limited by metals derived from natural processes from those due to mining. Elevated concentrations of metals in water and sediment were not restricted to mined catchments; depauperate aquatic communities were found in unmined catchments. The type and intensity of hydrothermal alteration and the mineral deposit type were important determinants of water and sediment quality as well as the aquatic community in both mined and unmined catchments. This study distinguished the effects of different rock types and geologic sources of metals on ecosystems by incorporating basic geologic processes into reference and baseline site selection, resulting in a refined assessment. Our results indicate that biomonitoring studies should account for natural sources of metals in some geologic environments as contributors to the effect of mines on aquatic ecosystems, recognizing that in mining-impacted drainages there may have been high pre-mining background metal concentrations.

Ecological Applications↗

USGS2012

Geospatial database for regional environmental assessment of central Colorado.

In conjunction with the future planning needs of the U.S. Department of Agriculture, Forest Service, the U.S. Geological Survey conducted a detailed environmental assessment of the effects of historical mining on Forest Service lands in central Colorado. Stream sediment, macroinvertebrate, and various filtered and unfiltered water quality samples were collected during low-flow over a four-year period from 2004–2007. This report summarizes the sampling strategy, data collection, and analyses performed on these samples. The data are presented in Geographic Information System, Microsoft Excel, and comma-delimited formats. Reports on data interpretation are being prepared separately.

Colorado↗

USGS2011

Critical tissue residue approach linking accumulated metals in aquatic insects to population and community-level effects

Whole body Zn concentrations in individuals ( n = 825) from three aquatic insect taxa (mayflies Rhithrogena spp. and Drunella spp. and the caddisfly Arctopsyche grandis ) were used to predict effects on populations and communities ( n = 149 samples). Both mayflies accumulated significantly more Zn than the caddisfly. The presence/absence of Drunella spp. most reliably distinguished sites with low and high Zn concentrations; however, population densities of mayflies were more sensitive to increases in accumulated Zn. Critical tissue residues (634 μg/g Zn for Drunella spp. and 267 μg/g Zn for Rhithrogena spp.) caused a 20% reduction in maximum (90th quantile) mayfly densities. These critical tissue residues were associated with exposure to 7.0 and 3.9 μg/L dissolved Zn for Drunella spp. and Rhithrogena spp., respectively. A threshold in a measure of taxonomic completeness (observed/expected) was observed at 5.4 μg/L dissolved Zn. Dissolved Zn concentrations associated with critical tissue residues in mayflies were also associated with adverse effects in the aquatic community as a whole. These effects on populations and communities occurred at Zn concentrations below the U.S. EPA hardness-adjusted continuous chronic criterion.

Environmental Science & Technology↗

USGS2010

Development of a new toxic-unit model for the bioassessment of metals in streams

Two toxic-unit models that estimate the toxicity of trace-metal mixtures to benthic communities were compared. The chronic criterion accumulation ratio (CCAR), a modification of biotic ligand model (BLM) outputs for use as a toxic-unit model, accounts for the modifying and competitive influences of major cations (Ca 2+ , Mg 2+ , Na + , K + , H + ), anions (HCO 3 − , CO 3 2− ,SO 4 2− , Cl − , S 2− ) and dissolved organic carbon (DOC) in determining the free metal ion available for accumulation on the biotic ligand. The cumulative criterion unit (CCU) model, an empirical statistical model of trace-metal toxicity, considers only the ameliorative properties of Ca 2+ and Mg 2+ (hardness) in determining the toxicity of total dissolved trace metals. Differences in the contribution of a metal (e.g., Cu, Cd, Zn) to toxic units as determined by CCAR or CCU were observed and attributed to how each model incorporates the influences of DOC, pH, and alkalinity. Akaike information criteria demonstrate that CCAR is an improved predictor of benthic macroinvertebrate community metrics as compared with CCU. Piecewise models depict great declines (thresholds) in benthic macroinvertebrate communities at CCAR of 1 or more, while negative changes in benthic communities were detected at a CCAR of less than 1. We observed a 7% reduction in total taxa richness and a 43% decrease in Heptageniid abundance between background (CCAR = 0.1) and the threshold of chronic toxicity on the basis of continuous chronic criteria (CCAR = 1). In this first application of the BLM as a toxic-unit model, we found it superior to CCU.

Environmental Toxicology and Chemistry↗

USGS2010

Death Valley regional groundwater flow system, Nevada and California: Hydrogeologic framework and transient groundwater flow model

A numerical three-dimensional (3D) transient groundwater flow model of the Death Valley region was developed by the U.S. Geological Survey for the U.S. Department of Energy programs at the Nevada Test Site and at Yucca Mountain, Nevada. Decades of study of aspects of the groundwater flow system and previous less extensive groundwater flow models were incorporated and reevaluated together with new data to provide greater detail for the complex, digital model. A 3D digital hydrogeologic framework model (HFM) was developed from digital elevation models, geologic maps, borehole information, geologic and hydrogeologic cross sections, and other 3D models to represent the geometry of the hydrogeologic units (HGUs). Structural features, such as faults and fractures, that affect groundwater flow also were added. The HFM represents Precambrian and Paleozoic crystalline and sedimentary rocks, Mesozoic sedimentary rocks, Mesozoic to Cenozoic intrusive rocks, Cenozoic volcanic tuffs and lavas, and late Cenozoic sedimentary deposits of the Death Valley regional groundwater flow system (DVRFS) region in 27 HGUs. Information from a series of investigations was compiled to conceptualize and quantify hydrologic components of the groundwater flow system within the DVRFS model domain and to provide hydraulic-property and head-observation data used in the calibration of the transient-flow model. These studies reevaluated natural groundwater discharge occurring through evapotranspiration (ET) and spring flow; the history of groundwater pumping from 1913 through 1998; groundwater recharge simulated as net infiltration; model boundary inflows and outflows based on regional hydraulic gradients and water budgets of surrounding areas; hydraulic conductivity and its relation to depth; and water levels appropriate for regional simulation of prepumped and pumped conditions within the DVRFS model domain. Simulation results appropriate for the regional extent and scale of the model were provided by acquiring additional data, by reevaluating existing data using current technology and concepts, and by refining earlier interpretations to reflect the current understanding of the regional groundwater flow system. Groundwater flow in the Death Valley region is composed of several interconnected, complex groundwater flow systems. Groundwater flow occurs in three subregions in relatively shallow and localized flow paths that are superimposed on deeper, regional flow paths. Regional groundwater flow is predominantly through a thick Paleozoic carbonate rock sequence affected by complex geologic structures from regional faulting and fracturing that can enhance or impede flow. Spring flow and ET are the dominant natural groundwater discharge processes. Groundwater also is withdrawn for agricultural, commercial, and domestic uses. Groundwater flow in the DVRFS was simulated using MODFLOW-2000, the U.S. Geological Survey 3D finitedifference modular groundwater flow modeling code that incorporates a nonlinear least-squares regression technique to estimate aquifer parameters. The DVRFS model has 16 layers of defined thickness, a finite-difference grid consisting of 194 rows and 160 columns, and uniform cells 1,500 meters (m) on each side. Prepumping conditions (before 1913) were used as the initial conditions for the transient-state calibration. The model uses annual stress periods with discrete recharge and discharge components. Recharge occurs mostly from infiltration of precipitation and runoff on high mountain ranges and from a small amount of underflow from adjacent basins. Discharge occurs primarily through ET and spring discharge (both simulated as drains) and water withdrawal by pumping and, to a lesser amount, by underflow to adjacent basins simulated by constant-head boundaries. All parameter values estimated by the regression are reasonable and within the range of expected values. The simulated hydraulic heads of the final calibrated transient model generally fit observed heads reasonably well (residuals with absolute values less than 10 meters) with two exceptions: in most areas of nearly flat hydraulic gradient the fit is considered moderate (residuals with absolute values of 10 to 20 meters), and in areas of steep hydraulic gradient along the Eleana Range and western part of Yucca Flat, southern part of the Owlshead Mountains, southern part of the Bullfrog Hills, and the north-northwestern part of the model domain (residuals with absolute values greater than 20 meters). Groundwater discharge residuals are fairly random, with as many areas where simulated flows are less than observed flows as areas where simulated flows are greater. The highest unweighted groundwater discharge residuals occur at Death Valley, Sarcobatus Flat (northeastern area), Tecopa, and early observations at Manse Spring in Pahrump Valley. High weighted-discharge residuals were computed in Indian Springs Valley and parts of Death Valley. Most of these inaccuracies in head and discharge can be attributed to insufficient representation of the hydrogeology in the HFM and(or) discharge estimates, misrepresentation of water levels, and(or) model error associated with grid-cell size. The model represents the large and complex groundwater flow system of the Death Valley region at a greater degree of refinement and accuracy than has been possible previously. The representation of detail provided by the 3D digital hydrogeologic framework model and the numerical groundwater flow model enabled greater spatial accuracy in every model parameter. The lithostratigraphy and structural effects of the hydrogeologic framework; recharge estimates from simulated net infiltration; discharge estimates from ET, spring flow, and pumping; and boundary inflow and outflow estimates all were reevaluated, some additional data were collected, and accuracy was improved. Uncertainty in the results of the flow model simulations can be reduced by improving on the quality, interpretation, and representation of the water-level and discharge observations used to calibrate the model and improving on the representation of the HGU geometries, the spatial variability of HGU material properties, the flow model physical framework, and the hydrologic conditions.

California, Nevada↗

USGS2010

Evaluation of the extent of contamination caused by historical mining in catchments of central Colorado

The U.S. Geological Survey conducted an assessment of stream water and sediment quality in central Colorado, an area of about 54,000 km2. The study area is focused on small tributary catchments in the Rocky Mountains. The Colorado Mineral belt, a northeast-trending mineralized zone that experienced base- and precious-metal mining at the beginning of the late 1800s and early 1900s, cuts diagonally across the geologic trend in the study area. The goal of this study was to compare water and sediment quality in background catchments with those which have been mined. Water and sediment data from 200 catchments, and data from macroinvertebrates from more than 100 catchments, provided ample data for evaluation of the effects of mining on water and sediment quality. Focused sampling was conducted during low-flow conditions in the summers of 2004-2007. Samples were collected from catchments that (1) were underlain largely by a single lithologic unit, (2) contained hydrothermally altered rock and had been prospected, and (3) contained historical mines. Geochemical data determined from catchments that did not contain hydrothermal alteration or historical mines met water-quality criteria and recommended sediment-quality guidelines and showed small variations in base-metal concentrations. Hydrothermal alteration and mineralization typically are associated with igneous rocks that have intruded older bedrock. Base-metal concentrations were elevated in sediment from catchments underlain by hydrothermally altered rock. Catchments affected by historical mining contained highly elevated base-metal concentrations. Classification of catchments on the basis of mineral deposit types proved to be an efficient and accurate method for discriminating catchments that had degraded water and sediment quality. Only about 4.5 percent of the study area has been affected by historical mining, whereas a larger portion of the study area is underlain by hydrothermally altered rock. Weathering of QSP-altered catchments release metals and result in naturally elevated geochemical background concentrations in both sediment and water. The presence of hydrothermal alteration is shown to be a major consideration in the selection of sites for the determination of geochemical background.

Conference Paper↗

USGS2009

Accelerated weathering of limestone for CO2 mitigation: Opportunities for the stone and cement industries

Large amounts of limestone fines co-produced during the processing of crushed limestone may be useful in the sequestration of carbon dioxide (CO 2 ). Accelerated weathering of limestone (AWL) is proposed as a low-tech method to capture and sequester CO 2 from fossil fuel-fired power plants and other point sources such as cement manufacturing. AWL reactants are readily available, inexpensive and environmentally benign. Waste CO 2 is hydrated with water to produce carbonic acid. This reacts with and is neutralized by limestone fines, thus converting CO 2 gas to dissolved calcium bicarbonate.

Mining Engineering↗