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C. Werner

Publications and source records attributed to C. Werner.

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Volcanic seismicity beneath Chuginadak Island, Alaska (Cleveland and Tana volcanoes): Implications for magma dynamics and eruption forecasting

Cleveland and Tana are remote volcanoes located in the central Aleutian volcanic arc on the eastern end of the Islands of Four Mountains (IFM). The persistently active Mount Cleveland volcano, on the western side of Chuginadak Island, is surrounded by several closely spaced Quaternary volcanic centers including Carlisle, Herbert, Kagamil, Tana, and Uliaga, and numerous small satellite vents on Chiginadak between Cleveland and Tana. The Alaska Volcano Observatory (AVO) installed two permanent broadband seismometers on Chuginadak Island in 2014, and we operated a temporary broadband network focused on the western side of the island in 2015–2016. Collectively, these stations provided the first seismic observations of this frequently active volcano and the surrounding Holocene-aged volcanic vents. During the study period (July 2014–January 2019), eruptive activity at Cleveland was characterized by small explosions separated by periods of lava effusion that formed small domes in the volcano's summit crater. We characterize seismicity beneath Chuginadak Island through automated analysis of event waveform frequency content, development of a one-dimensional P-wave velocity model, calculation of earthquake hypocenters, magnitudes, focal mechanisms, and identification of earthquake families. This analysis reveals the full range of seismic event types expected in a highly active volcanic environment and includes Volcano-Tectonic (VT) earthquakes, Long-Period (LP) events, and explosion signals. LP events appear to cluster at shallow depth beneath the active crater of Mount Cleveland and almost all of the explosions occur without identifiable short-term (hours to days) seismic precursors. VT earthquakes beneath Mount Cleveland occur at depths of 2 to 8 km below sea level (BSL) and range in magnitude from −0.2 to 1.8. VT focal mechanisms have horizontal P-axes that align with the regional axis of maximum stress. These observations, and a relatively slow one-dimensional seismic velocity model, are consistent with a shallow body of magma that is fed through a deeper conduit system. The time-history of VT earthquakes and shallow LP events suggest their occurrence may track the transfer of magma and fluids from the mid-crust to the shallow portions of the conduit system and may provide a means to anticipate future explosions and periods of dome growth. VT hypocenters also extend ~7 km northeast of Cleveland's summit at depths of 5 to 10 km BSL, under a group of Holocene-aged vents between Mount Cleveland and Tana. These earthquakes have vertically-oriented P-axes and a greater percentage occur in families. These observations, combined with observations of vent orientation and morphology and gas flux, suggest the area between Cleveland and Tana represents a zone of complicated volcano-tectonic interaction, similar to calderas elsewhere in the Aleutian arc. The presence of a larger volcanic system in the eastern IFM could influence magmatism and account for the multiple closely spaced volcanic centers in this region.

Alaska

Assessment of the UV camera sulfur dioxide retrieval for point source plumes

Digital cameras, sensitive to specific regions of the ultra-violet (UV) spectrum, have been employed for quantifying sulfur dioxide (SO 2 ) emissions in recent years. The instruments make use of the selective absorption of UV light by SO 2 molecules to determine pathlength concentration. Many monitoring advantages are gained by using this technique, but the accuracy and limitations have not been thoroughly investigated. The effect of some user-controlled parameters, including image exposure duration, the diameter of the lens aperture, the frequency of calibration cell imaging, and the use of the single or paired bandpass filters, have not yet been addressed. In order to clarify methodological consequences and quantify accuracy, laboratory and field experiments were conducted. Images were collected of calibration cells under varying observational conditions, and our conclusions provide guidance for enhanced image collection. Results indicate that the calibration cell response is reliably linear below 1500 ppm m, but that the response is significantly affected by changing light conditions. Exposure durations that produced maximum image digital numbers above 32 500 counts can reduce noise in plume images. Sulfur dioxide retrieval results from a coal-fired power plant plume were compared to direct sampling measurements and the results indicate that the accuracy of the UV camera retrieval method is within the range of current spectrometric methods. ?? 2009 Elsevier B.V.

Journal of Volcanology and Geothermal Research

Diurnal and vertical variability of the sensible heat and carbon dioxide budgets in the atmospheric surface layer

The diurnal and vertical variability of heat and carbon dioxide (CO2) in the atmospheric surface layer are studied by analyzing measurements from a 213 in tower in Cabauw (Netherlands). Observations of thermodynamic variables and CO2 mixing ratio as well as vertical profiles of the turbulent fluxes are used to retrieve the contribution of the budget terms in the scalar conservation equation. On the basis of the daytime evolution of turbulent fluxes, we calculate the budget terms by assuming that turbulent fluxes follow a linear profile with height. This assumption is carefully tested and the deviation ftom linearity is quantified. The budget calculation allows us to assess the importance of advection of heat and CO2 during day hours for three selected days. It is found that, under nonadvective conditions, the diurnal variability of temperature and CO2 is well reproduced from the flux divergence measurements. Consequently, the vertical transport due to the turbulent flux plays a major role in the daytime evolution of both scalars and the advection is a relatively small contribution. During the analyzed days with a strong contribution of advection of either heat or carbon dioxide, the flux divergence is still an important contribution to the budget. For heat, the quantification of the advection contribution is in close agreement with results from a numerical model. For carbon dioxide, we qualitatively corroborate the results with a Lagrangian transport model. Our estimation of advection is compared with, traditional estimations based on the Net Ecosystem-atmosphere Exchange (NEE). Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research D: Atmospheres

Variability of passive gas emissions, seismicity, and deformation during crater lake growth at White Island Volcano, New Zealand, 2002-2006

We report on 4 years of airborne measurements of CO2, SO2, and H2S emission rates during a quiescent period at White Island volcano, New Zealand, beginning in 2003. During this time a significant crater lake emerged, allowing scrubbig processes to be investigated. CO2 emissions varied from a baseline of 250 to >2000 t d-1 and demonstrated clear annual cycling that was consistent with numbers of earthquake detections and annual changes in sea level. The annual variability was found to be most likely related to increases in the strain on the volcano during sea level highs, temporarily causing fractures to reduce in size in the upper conduit. SO2 emissions varied from 0 to >400 t d-1 and were clearly affected by scrubbing processes within the first year of take development. Scrubbing caused increases of SO42- and Cl- in lake waters, and the ratio of carbon to total sulphur suggested that elemental sulphur deposition was also significant in the lake during the first year. Careful measurements of the lake level and chemistry allowed estimates of the rate of H2O(g) and HCl(g) input into the lake and suggested that the molar abundances of major gas species (H2O, CO2, SO2, and HCl) during this quiescent phase were similar to fumarolic ratios observed between earlier eruptive periods. The volume of magma estimated from CO2 emissions (0.0 15-0.04 km3) was validated by Cl- increases in the lake, suggesting that the gas and magma are transported from deep to shallow depths as a closed system and likely become open in the upper conduit region. The absence of surface deformation further leads to a necessity of magma convection to supply and remove magma from the degassing depths. Two models of convection configurations are discussed. Copyright 2008 by the American Geophysical Union.

Journal of Geophysical Research B: Solid Earth

Geochemical surveillance of magmatic volatiles at Popocatepetl volcano, Mexico

Surveillance of Popocatépetl volcanic plume geochemistry and SO 2 flux began in early 1994 after fumarolic and seismic activity increased significantly during 1993. Volatile traps placed around the summit were collected at near-monthly intervals until the volcano erupted on December 21, 1994. Additional trap samples were obtained in early 1996 before the volcano erupted again, emplacing a small dacite dome in the summit crater. Abundances of volatile constituents (ppm/day of Cl, S total , F, CO 2 , Hg, and As) varied, but most constituents were relatively high in early and late 1994. However, ratios of these constituents to Cl were highest in mid-1994. δ 34 S-S total in trap solutions ranged from 1.5‰ to 6.4‰; lowest values generally occurred during late 1994. δ 13 C-CO 2 of trap solutions were greatly contaminated with atmospheric CO 2 and affected by absorption kinetics. When trap data are combined with SO 2 flux measurements made through November 1996, Popocatépetl released about 3.9 Mt SO 2 , 16 Mt CO 2 , 0.75 Mt HCl, 0.075 Mt HF, 260 t As, 2.6 t Hg, and roughly 200 Mt H 2 O. Near-vent gas concentrations in the volcanic plume measured by correlation spectrometer (COSPEC) and Fourier transform infrared (FTIR) commonly exceed human recommended exposure limits and may constitute a potential health hazard. Volatile geochemistry combined with petrologic observations and melt-inclusion studies show that mafic magma injection into a preexisting silicic chamber has accompanied renewed volcanism at Popocatépetl. Minor assimilation of Cretaceous wall rocks probably occurred in mid-1994.

Mexico