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C. S. Cronan

Publications and source records attributed to C. S. Cronan.

2 recordsLinked to original sources

Acidic deposition in the northeastern United States: Sources and inputs, ecosystem effects, and management strategies: The effects of acidic deposition in the northeastern United States include the acidification of soil and water, which stresses terrestrial and aquatic biota

Acidic deposition is the transfer of strong acids and acid-forming substances from the atmosphere to the surface of the Earth. The composition of acidic deposition includes ions, gases, and particles derived from the following: gaseous emissions of sulfur dioxide (SO 2 ), nitrogen oxides (NO x ), ammonia (NH 3 ), and particulate emissions of acidifying and neutralizing compounds. Over the past quarter century of study, acidic deposition has emerged as a critical environmental stress that affects forested landscapes and aquatic ecosystems in North America, Europe, and Asia. This complex problem is an example of a new class of environmental issues that are multiregional in scale and are not amenable to simple resolution by policymakers. Acidic deposition can originate from transboundary air pollution and can affect large geographic areas. It is highly variable across space and time, links air pollution to diverse terrestrial and aquatic ecosystems, and alters the interactions of many elements (e.g., sulfur [S], nitrogen [N], hydrogen ion [H + ], calcium [Ca 2+ ], magnesium [Mg 2+ ], and aluminum [Al]). It also contributes directly and indirectly to biological stress and to the degradation of ecosystems. Despite the complexity of the effects of acidic deposition, North American and European management actions directed toward the recovery of damaged natural resources have resulted in recent decreases in both emissions and deposition of acidic S compounds. Accordingly, acidic deposition presents an instructive case study for coordinating science and policy efforts aimed at resolving large-scale environmental problems.

northeastern United States

Chemistry and transport of soluble humic substances in forested watersheds of the Adirondack Park, New York

Studies were conducted in conjunction with the Integrated Lake-Watershed Acidification Study (ILWAS) to examine the chemistry and leaching patterns of soluble humic substances in forested watersheds of the Adirondack region. During the summer growing season, mean dissolved organic carbon (DOC) concentrations in the ILWAS watersheds ranged from 21–32 mg C l −1 in O/A horizon leachates, from 5–7 mg C l −1 in B horizon leachates, from 2–4 mg C l −1 in groundwater solutions, from 6–8 mg C l −1 in first order streams, from 3–8 mg C l −1 in lake inlets, and from 2–7 mg C l −1 in lake outlets. During the winter, mean DOC concentrations dropped significantly in the upper soil profile. Soil solutions from mixed and coniferous stands contained as much as twice the DOC concentration of lysimeter samples from hardwood stands. Results of DOC fractionation analysis showed that hydrophobia and hydrophilic acids dominate the organic solute composition of natural waters in these watersheds. Charge balance and titration results indicated that the general acid-base characteristics of the dissolved humic mixture in these natural waters can be accounted for by a model organic acid having an average p K a of 3.85, an average charge density of 4–5 μeq mg −1 C at ambient pH, and a total of 6–7 meq COOH per gram carbon.

New York