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C. Paul Frederick

Publications and source records attributed to C. Paul Frederick.

6 recordsLinked to original sources

Potentiometric surface, 2014–15, and water-level differences, 2009 to 2014–15, in the Chicot equivalent aquifer system in southeastern Louisiana

The U.S. Geological Survey constructed the potentiometric surface of the Upland terrace and upper Ponchatoula aquifers and the “400-foot” sand using the altitude of water levels from 121 wells measured January 2014 to March 2015. Differences in water levels in the Upland terrace and upper Ponchatoula aquifers and “400-foot” sand were measured at 55 wells in 2009 and again at the same wells in 2014–15. Long-term hydrographs for most wells screened in the Upland terrace aquifer and “400-foot” sand show seasonal fluctuations with little net change in water levels. The potentiometric surface of the “600-foot” sand was constructed by using the altitude of water levels from 14 wells measured from January 2014 to March 2015. Differences in water levels between 2009 and 2014–15 were determined in the “600-foot” sand by using measurements collected at seven wells. These differences do not necessarily indicate a trend but show water levels declined by more than 5 feet from 2009 to 2015. Long-term hydrographs for two wells screened in the “600-foot” sand show declines in water levels but vary in their drawdown and recovery based on location relative to areas of substantial groundwater withdrawal.

Louisiana

Mississippi River nitrate loads from high frequency sensor measurements and regression-based load estimation

Accurately quantifying nitrate (NO 3 – ) loading from the Mississippi River is important for predicting summer hypoxia in the Gulf of Mexico and targeting nutrient reduction within the basin. Loads have historically been modeled with regression-based techniques, but recent advances with high frequency NO 3 – sensors allowed us to evaluate model performance relative to measured loads in the lower Mississippi River. Patterns in NO 3 – concentrations and loads were observed at daily to annual time steps, with considerable variability in concentration-discharge relationships over the two year study. Differences were particularly accentuated during the 2012 drought and 2013 flood, which resulted in anomalously high NO 3 – concentrations consistent with a large flush of stored NO 3 – from soil. The comparison between measured loads and modeled loads (LOADEST, Composite Method, WRTDS) showed underestimates of only 3.5% across the entire study period, but much larger differences at shorter time steps. Absolute differences in loads were typically greatest in the spring and early summer critical to Gulf hypoxia formation, with the largest differences (underestimates) for all models during the flood period of 2013. In additional to improving the accuracy and precision of monthly loads, high frequency NO 3 – measurements offer additional benefits not available with regression-based or other load estimation techniques.

Louisiana

Water-quality characteristics of urban storm runoff at selected sites in East Baton Rouge Parish, Louisiana, February 2006 through November 2009

Water samples were collected at three watersheds in East Baton Rouge Parish, Louisiana, during February 2006 through November 2009 for continued evaluation of urban storm runoff. The watersheds represented land uses characterized predominantly as established commercial, industrial, and residential. The following water-quality data are reported: physical and chemical-related properties, fecal coliform, nutrients, trace elements, and organic compounds. Results of water-quality analyses enabled calculation of event-mean concentrations and estimated annual contaminant loads and yields of storm runoff from nonpoint sources for 12 water-quality properties and constituents. Lead met or exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level of 15 micrograms per liter for drinking water standards in 4 of 14 samples. Low level concentrations of mercury were detected in all 14 samples, and half were two to four times above the reporting limit of 0.02 micrograms per liter. The average dissolved phosphorus concentrations from each land use were two to four times the U.S. Environmental Protection Agency criterion of 0.05 milligrams per liter. Diazinon was detected in one sample at a concentration of 0.2 micrograms per liter. In the residential watershed, the largest at 216 acres, contaminant loads for 5 of the 12 water-quality properties and constituents were highest, with 4 of these being nutrients. The industrial watershed, 97 acres, had the highest contaminant loads for 6 of the 12 water-quality properties and constituents with 3 of these being metals, which is indicative of the type of land use. Zinc had the highest metal load (155 pounds per year) in the industrial watershed, compared to 36 pounds per year in the residential watershed, and 32 pounds per year in the established commercial watershed. The industrial watershed had the highest yields for 8 of the 12 water-quality properties and constituents, whereas the established commercial watershed had the lowest yield for 5 of the 12. Lower yields from the established commercial and residential watersheds could be from Best Management Practices in place that help control increased runoff from impervious areas and land development. Metal yields from all the watersheds were less than 1 pound per acre per year, except for the zinc from the industrial watershed, which was 2 pounds per acre per year. Nutrient yields in the established commercial watershed were lowest for total nitrogen, ammonia plus organic nitrogen (Kjeldahl nitrogen), and dissolved phosphorus.

Louisiana

Withdrawals, water levels, and specific conductance in the Chicot aquifer system in southwestern Louisiana, 2000-03

The Chicot aquifer system is the principal source of fresh ground-water supplies in southwestern Louisiana. Much of the area is rural and rice cultivation is the primary agricultural activity. About 540 million gallons per day were withdrawn from the aquifer system in southwestern Louisiana in 2000. Potentiometric-surface maps of the aquifer system were created for June 2002 and January 2003 to determine where water-level declines occur due to seasonal ground-water withdrawals. During June 2002, water levels in the aquifer system were more than 40 feet below the National Geodetic Vertical Datum of 1929 (NGVD 29) in parts of Acadia, Calcasieu, Evangeline, and Jefferson Davis Parishes, in an area that generally coincides with rice-farming areas. During January 2003, water levels were more than 30 feet below NGVD 29 in these areas. From June 2002 to January 2003, water levels generally recovered between 5 and 20 feet in the Chicot aquifer system in most of Acadia and Jefferson Davis Parishes, southeastern Calcasieu Parish, and southern Evangeline Parish, in an area that generally coincides with rice-farming areas. These water-level changes are representative of the areal extent and magnitude of typical seasonal water-level fluctuations that occur in the aquifer system in response to seasonal ground-water withdrawals for rice irrigation. The presence of saltwater has been documented in the Chicot aquifer system beneath coastal parishes and in some areas where the aquifer system merges with the stratigraphically adjacent Atchafalaya aquifer. Data collected during the period 1943 to 2003 from 1,355 wells screened in the massive, upper, and "200-foot" sands of the Chicot aquifer system and the Atchafalaya aquifer were used to delineate areas having similar specific conductance values and determine areas where wells are affected by saltwater. Near the outcrop area, specific conductance values in the Chicot aquifer system generally are less than 150 µS/cm (microsiemens per centimeter at 25 degrees Celsius). Specific conductance values increase south and east of the outcrop area. Specific conductance values generally range from 151 to 500 µS/cm in rice-farming areas of northwestern Acadia Parish, southeastern Allen Parish, western Evangeline Parish, and northern and central Jefferson Davis Parish. Specific conductance values generally range from 501 to 1,000 µS/cm in most of the remaining rice-farming areas. Specific conductance values often exceed 1,000 µS/cm in an area along the border between Calcasieu and Jefferson Davis Parishes near Iowa, Louisiana, parts of northeastern Cameron Parish, an area of northwestern and central St. Landry Parish; parts of Vermilion Parish, and several areas along the eastern boundary of the study area where the Chicot aquifer system merges with the Atchafalaya aquifer. The maximum specific conductance value, 12,100 µS/cm, is from a well in Cameron Parish. During 2000-03, specific conductance was measured in 521 water samples from 166 wells screened in the Chicot aquifer system or the Atchafalaya aquifer. Specific conductance values exceeded 1,000 µS/cm in water samples from wells in Calcasieu, Cameron, Jefferson Davis, St. Landry, St. Martin, St. Mary, and Vermilion Parishes. Specific conductance values exceeded 2,000 µS/cm in only two wells—an irrigation well located about 2 miles south of Iowa and a USGS observation well used to monitor saltwater encroachment in east-central Vermilion Parish. Specific conductance values increased steadily at one well, from 1,090 µS/cm in April 2000 to 2,860 µS/cm in April 2003. Nearby wells did not show similar increases. Specific conductance was measured hourly during pumping at two irrigation wells between 2000 and 2003. Specific conductance values were greater than 1,000 µS/cm in both wells, indicating the presence of saltwater near the wells. Specific conductance values generally fluctuated about 150 µS/cm at both wells, but no long-term trends in the specific conductance were evident in either well.

Louisiana

Water-quality characteristics of urban storm runoff at selected sites in East Baton Rouge Parish, Louisiana, February 1998 through April 2002

Water was sampled at four watersheds for continued evaluation of urban storm runoff in East Baton Rouge Parish, Louisiana, during February 1998 through April 2002. Eighteen samples were collected from four watersheds representing land uses characterized predominantly as established commercial, industrial, new commercial, and residential. Results of water-quality analyses enabled calculation of event-mean concentrations and estimated annual contaminant loads and yields of storm runoff from nonpoint sources for 12 water-quality properties and constituents. The following water-quality data are reported: physical and chemical-related properties, fecal coliform and enterococci bacteria, major inorganic ions, nutrients, trace elements, and organic compounds. The residential land-use is the largest of the watersheds (550 acres), which resulted in high estimated annual contaminant loads compared to other watersheds for 8 of the 12 water-quality properties and constituents. This may indicate that the size of the watershed and runoff from residences with their associated contaminants had substantial effects on annual loads within this land use. The industrial land-use area had the highest estimated annual contaminant loads for metals, followed by the residential landuse area. However, when comparing yields among the watersheds, the industrial watershed had the highest yield for 9 of the 12 water-quality properties and constituents, whereas the residential watershed had the lowest yield for 7 of the 12. The industrial watershed yielded more metals per acre per year than any other watershed. Zinc yields were 2.71 pounds per acre per year from the industrial watershed, compared to 0.35 pounds per acre per year from the residential watershed, which was the lowest of all the watersheds. Lead concentrations exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level of 15 micrograms per liter for drinking water standards in 10 of 18 samples. Low-level concentrations of mercury were detected twice at both the new commercial and residential sites, with all concentrations at or just above reporting limits. The average dissolved phosphorus concentrations from each land use were two to four times higher than the U.S. Environmental Protection Agency criterion of 0.05 milligrams per liter. Diazinon, which is widely used as a general-purpose insecticide for lawns and gardens, was detected in all 18 samples. The maximum diazinon concentration detected, 2.7 micrograms per liter, was from the residential site. Malathion, another insecticide used on lawns, gardens, and plants, was also detected at least once from each site, but all concentrations were below the minimum detection limit of 0.1 micrograms per liter.

Loiusiana