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C. Blaine Cecil

Publications and source records attributed to C. Blaine Cecil.

13 recordsLinked to original sources

The chemistry of eolian quartz dust and the origin of chert

Among the numerous models that have been suggested for the primary and predominant source of silica for chert, we suggest that eolian dust is worthy of further considerations. Such considerations are supported by the common association of Phanerozoic chert with evaporites, limestones, dolomites, or other strata that were deposited within or near arid paleoclimates. This association suggests a direct or indirect causal link between aridity and chert formation. In addition, eolian processes export large quantities of quartz-rich dust from arid climate ergs or loess lands. The chemistry of abraded quartz particles derived therefrom is consistent with chert formation. Abrasion of quartz particles produces an amorphous surface layer and underlying lattice disorder. An inverse relation between particle size distribution (< 64 μm) and the enthalpy of solution of abraded quartz is indicative of the degree of lattice disorder; as particle size decreases, the enthalpy of solution increases. The amorphous surface layer and underlying lattice disorder enhance both the rate and amount of dissolution of quartz dust particles; the solubilized silica can then be reprecipitated and diagenetically altered to the various silica polymorphs that occur in chert. An eolian supply and the chemistry of eolian abraded quartz particles may account for chert formation in disparate depositional environments that encompass deep-sea chert, chert in epicontinental seas including shallow shelves, and chert that formed in continental eolinites, lakes, and soils (arid climate silcretes).

Journal of Sedimentary Research

Selenium Concentrations in Middle Pennsylvanian Coal-Bearing Strata in the Central Appalachian Basin

Introduction This report provides the results of a reconnaissance-level investigation of selenium (Se) concentrations in Middle Pennsylvanian coal-bearing strata in the central Appalachian basin. Bryant and others (2002) reported enrichments of Se concentrations in streams draining areas disturbed by surface mining relative to Se concentrations in streams that drain undisturbed areas; the study was conducted without the benefit of data on Se concentrations in coal-bearing strata prior to anthropogenic disturbance. Thus, the present study was conducted to provide data on Se concentrations in coal-bearing strata prior to land disturbance. The principal objectives of this work are: 1) determine the stratigraphic and regional distribution of Se concentrations in coal-bearing strata, 2) provide reconnaissance-level information on relations, if any, between Se concentrations and lithology (rock-type), and 3) develop a cursory evaluation of the leachability of Se from disturbed strata. The results reported herein are derived from analyses of samples obtained from three widely-spaced cores that were collected from undisturbed rock within a region that has been subjected to extensive land disturbance principally by either coal mining or, to a lesser extent, highway construction. The focus was on low-organic-content lithologies, not coal, within the coal-bearing interval, as these lithologies most commonly make up the fill materials after coal mining or in road construction.

Open-File Report

Eolian Dust and the Origin of Sedimentary Chert

This paper proposes an alternative model for the primary source of silica contained in bedded sedimentary chert. The proposed model is derived from three principal observations as follows: (1) eolian processes in warm-arid climates produce copious amounts of highly reactive fine-grained quartz particles (dust), (2) eolian processes in warm-arid climates export enormous quantities of quartzose dust to marine environments, and (3) bedded sedimentary cherts generally occur in marine strata that were deposited in warm-arid paleoclimates where dust was a potential source of silica. An empirical integration of these observations suggests that eolian dust best explains both the primary and predominant source of silica for most bedded sedimentary cherts.

Open-File Report

Influence of climate on deep-water clastic sedimentation: application of a modern model, Peru-Chile Trough, to an ancient system, Ouachita Trough

Traditionally, an abrupt and massive influx of siliciclastic sediments into an area of deposition has been attributed to tectonic uplift without consideration of the influence of climate or climatic change on rates of weathering, erosion, transportation, and deposition. With few exceptions, fluvial sediment transport is minimal in both extremely arid climates and in perhumid (everwet) climates. Maximum sediment transport occurs in climates characterized by strongly seasonal rainfall, where the effect of vegetation on erosion is minimal. The Peru–Chile trench and Andes Mountain system (P–CT/AMS) of the eastern Pacific Ocean clearly illustrates the effects of climate on rates of weathering, erosion, transport, and deep-sea sedimentation. Terrigenous sediment is virtually absent in the arid belt north of lat. 30° S in the P–CT, but in the belt of seasonal rainfall south of lat. 30° S terrigenous sediment is abundant. Spatial variations in the amount and seasonality of annual precipitation are now generally accepted as the cause for this difference. The spatial variation in sediment supply to the P–CT appears to be an excellent modern analogue for the temporal variation in sediment supply to certain ancient systems, such as the Ouachita Trough in the southern United States. By comparison, during the Ordovician through the early Mississippian, sediment was deposited at very slow rates as the Ouachita Trough moved northward through the southern hemisphere dry belt (lat. 10° S to lat. 30° S). The deposystem approached the tropical humid zone during the Mississippian, coincident with increased coarse clastic sedimentation. By the Middle Pennsylvanian (Atokan), the provenance area and the deposystem moved well into the tropical humid zone, and as much as 8,500 m of mineralogically mature (but texturally immature) quartz sand was introduced and deposited. This increase in clastic sediment deposition traditionally has been attributed solely to tectonic activity. However, we contend that the principal control on the introduction of abundant terrigenous sediment was the movement of the deposystem from an arid or semiarid climate into a seasonally wetter climatic regime. The physical and mineralogical maturity of the quartz sand is the result of tropical weathering in provenance areas.

Climate Controls on Stratigraphy: SEPM Special Pub

A modern analogue for tectonic, eustatic, and climatic processes in cratonic basins: Gulf of Carpentaria, northern Australia

The Gulf of Carpentaria is a tropical, silled epicontinental sea and may be a modern analogue for ancient cratonic basins. For the purpose of this study, the Gulf of Carpentaria is compared to Pennsylvanian cratonic basins of the United States. During the Pennsylvanian, the North American continent moved from the Southern Hemisphere, through the Equator, into the Northern Hemisphere. Today, the Gulf of Carpentaria–New Guinea region is a few degrees south of the Equator and is moving towards it. During the Pennsylvanian, the world was subjected to major glaciations and associated sea-level changes. The island of New Guinea and the Gulf of Carpentaria have undergone similar processes during the Quaternary. A reconnaissance seismic survey of the gulf conducted by the USGS and the Australian National University (ANU), combined with oil-exploration well data, provided the first step in a systematic evaluation of a modern tropical epicontinental system. During the Cenozoic, the region was dominated by terrestrial sedimentation in a temperate climate. At the same time, carbonates were being deposited on the northern shelf edge of the Australian Plate. During the Miocene, carbonate deposition expanded southward into the gulf region. Then in the Late Miocene, carbonate sedimentation was replaced by terrigenous clastics derived from the developing Central Range of the island of New Guinea, which developed a wetter climate while moving northwards into the tropics. At least 14 basin-wide transgressive–regressive cycles are identified by channels that were eroded under subaerial conditions since about the Miocene. Comparison of the modern Gulf of Carpentaria sequences with those of the Pennsylvanian reveals many similarities.

Gulf Of Carpentaria

Coal Extraction - Environmental Prediction

Coal from the Appalachian region has supplied energy to the Nation for more than 200 years. Appalachian coal fueled America through a civil war and helped win two world wars. Appalachian coal has also provided fuel for keeping America warm in the winter and cool in the summer and has served as the basis for the steel, automobile, organic chemicals, chlorine, and aluminum industries. These benefits have not come without environmental costs, however. Coal extraction and utilization have had significant environmental impacts.

Fact Sheet

Sea-level and environmental changes since the last interglacial in the Gulf of Carpentaria, Australia: an overview

The Gulf of Carpentaria is an epicontinental sea (maximum depth 70 m) between Australia and New Guinea, bordered to the east by Torres Strait (currently 12 m deep) and to the west by the Arafura Sill (53 m below present sea level). Throughout the Quaternary, during times of low sea-level, the Gulf was separated from the open waters of the Indian and Pacific Oceans, forming Lake Carpentaria, an isolation basin, perched above contemporaneous sea-level with outlet channels to the Arafura Sea. A preliminary interpretation is presented of the palaeoenvironments recorded in six sediment cores collected by the IMAGES program in the Gulf of Carpentaria. The longest core (approx. 15 m) spans the past 130 ka and includes a record of sea-level/lake-level changes, with particular complexity between 80 and 40 ka when sea-level repeatedly breached and withdrew from Gulf/Lake Carpentaria. Evidence from biotic remains (foraminifers, ostracods, pollen), sedimentology and geochemistry clearly identifies a final marine transgression at about 9.7 ka (radiocarbon years). Before this transgression, Lake Carpentaria was surrounded by grassland, was near full, and may have had a surface area approaching 600 km×300 km and a depth of about 15 m. The earlier rise in sea-level which accompanied the Marine Isotopic Stage 6/5 transgression at about 130 ka is constrained by sedimentological and biotic evidence and dated by optical- and thermoluminescence and amino acid racemisation methods.

Gulf Of Carpentaria

Inorganic geochemistry of domed peat in Indonesia and its implication for the origin of mineral matter in coal

The inorganic geochemistry of three domed ombrogenous peat deposits in Riau and West Kalimantan provinces, Indonesia, was investigated as a possible modern analogue for certain types of low-ash, low-sulfur coal. Mineral matter entering the deposits is apparently limited to small amounts from the allogenic sources of dryfall, rainfall, and diffusion from substrate pore water. In the low-ash peat in the interior of the deposits, a large portion of the mineral matter is authigenic and has been mobilized and stabilized by hydrological, chemical, and biological processes and conditions. Ash yield and sulfur content are low through most of the peat deposits and average 1.1% and 0.14%, respectively, on a moisture-free basis. Ash and sulfur contents only exceed 5% and 0.3%, respectively, near the base of the deposits, with maximum concentrations of 19.9% ash and 0.56% sulfur. Peat water in all three deposits has a low pH, about 4 units, and low dissolved cation concentration, averaging 14 ppm. Near the base, in the geographic interior of each peat deposit, pH is about two units higher and dissolved cation concentration averages 110 ppm. Relative concentrations of the inorganic constituents vary, resulting in chemical facies in the peat. In general, Si, Al, and Fe are the abundant inorganic constituents, although Mg, Ca, and Na dominate in the middle horizon in the geographic interior of coastal peat deposits. The composition of the three deposits reported in this paper indicates that domed ombrogenous peat deposits will result in low ash and sulfur coal, probably less than 10% ash and 1% sulfur, even if marine rocks are laterally and vertically adjacent to the coal.

Special Paper of the Geological Society of America

Allogenic and autogenic controls on sedimentation in the central Sumatra basin as an analogue for Pennsylvanian coal-bearing strata in the Appalachian basin

Recent sedimentation patterns in the central Sumatra basin, Republic of Indonesia, may help to explain the cyclic stratigraphy of the Pennsylvanian System of the eastern United States. Modern influx of fluvial siliciclastic sediment to the epeiric seas of the Sunda shelf, including the Strait of Malacca, appears to be highly restricted by rain forest cover within the ever-wet climate belt of equatorial Sumatra. As a result, much of the marine and estuarine environments appear to be erosional or nondepositional except for localized deposition of sediment in slack water areas, such as the down-stream end of islands. Contemporaneously, thick (>13 m), laterally extensive (>70,000 km 2 ), peat deposits are forming on poorly drained coastal lowlands. Modern peat formation in this study, therefore, is not coeval with aggrading fluvial siliciclastic systems, a situation that commonly is assumed in many depositional models of coal formation. The stratigraphy of Pleistocene and Holocene sediments on the Sunda shelf, as well as those of the Pennsylvanian System, appears to be better explained by the allocyclic controls of climate and sea-level change on sediment flux rather than by depositional models that are based on autocyclic processes. The objective of this paper is to evaluate allocyclic and autocyclic controls on sedimentation in an epeiric setting in a humid (ever-wet) tropical region. Of particular interest are the factors that control peat formation and siliciclastic sediment flux in rivers, estuaries, and open marine environments.

GSA Special Papers

ORIGIN OF QUARTZ IN COAL.

Both a scanning electron microscope and an electron microprobe (EMP) were used in this study to analyze the cathodoluminescence properties of quartz grains in samples of the Upper Freeport coal bed because quartz grains in coal are small (silt sized) and below the resolution capabilities of a standard luminoscope. Quartz grains were identified by the detection of silicon alone with energy dispersive X-ray units attached to both the SEM and the EMP.

Conference Paper