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C. A. Bush

Publications and source records attributed to C. A. Bush.

At least 19 recordsLinked to original sources

Uranium-series dating of carbonate (tufa) deposits associated with quaternary fluctuations of Pyramid Lake, Nevada

Uranium-series dating of dense tufa deposited in a small cave, at former lake margins, and in large tufa mounds clarifies the timing of lake-level variation during the past 400,000 yr in the Pyramid Lake basin. A moderate-sized lake occasionally overflowed the Emerson Pass sill at elevation of ???1207 m between ca. 400,000 and 170,000 and from ca. 60,000 to 20,000 yr B.P., as shown by 230Th/234U ages of the cave samples, 230Th-excess ages of tubular tufas, and average isochron-plot ages of shoreline-deposited tufas. (By comparison, modern Pyramid Lake is ???50 m below this sill). There is a lack of tufa record during the intervening period from ca. 170,000 to 60,000 yr B.P. After ca. 20,000 yr, Pyramid Lake underwent abrupt changes in level and, based on previous 14C ages, reached its highest elevation (ca 1335 m) at ca. 14,000 yr B.P. The youngest uranium-series ages are comparable with previously reported 14C ages. ?? 1996 University of Washington.

Quaternary Research↗

Late Holocene eolian activity in the mineralogically mature Nebraska Sand Hills

The age of sand dunes in the Nebraska Sand Hills has been controversial, with some investigators suggesting a full-glacial age and others suggesting that they were last active in the late Holocene. New accelerator mass spectrometry radiocarbon ages of unaltered bison bones and organic-rich sediments suggest that eolian sand deposition occurred at least twice in the past 3000 14C yr B.P. in three widely separated localities and as many as three times in the past 800 14C yr at three other localities. These late Holocene episodes of eolian activity are probably the result of droughts more intense than the 1930s "Dust Bowl" period, based on independent Great Plains climate records from lake sediments and tree rings. However, new geochemical data indicate that the Nebraska Sand Hills are mineralogically mature. Eolian sands in Nebraska have lower K-feldspar (and K2O, Rb, and Ba) contents than most possible source sediments and lower K-feldspar contents than dunes of similar age in Colorado. The most likely explanation for mineralogical maturity is reduction of sand-sized K-feldspar to silt-sized particles via ballistic impacts due to strong winds over many cycles of eolian activity. Therefore, dunes of the Nebraska Sand Hills must have had a long history, probably extending over more than one glacial-interglacial cycle, and the potential for reactivation is high, with or without a future greenhouse warming. ?? 1997 University of Washington.

Quaternary Research↗

Geochemical evidence of Saharan dust parent material for soils developed on Quaternary limestones of Caribbean and western Atlantic islands

Most previous workers have regarded the insoluble residues of high-purity Quaternary limestones (coral reefs and oolites) as the most important parent material for well-developed, clay-rich soils on Caribbean and western Atlantic islands, but this genetic mechanism requires unreasonable amounts of limestone solution in Quaternary time. Other possible parent materials from external sources are volcanic ash from the Lesser Antilles island arc and Saharan dust carried across the Atlantic Ocean on the northeast trade winds. Soils on Quaternary coral terraces and carbonate eolianites on Barbados, Jamaica, the Florida Keys (United States), and New Providence Island (Bahamas) were studied to determine which, if either, external source was important. Caribbean volcanic ashes and Saharan dust can be clearly distinguished using ratios of relatively immobile elements ( Al2O3 TiO2, Ti Y, Ti Zr, and Ti Th). Comparison of these ratios in 25 soils, where estimated ages range from 125,000 to about 870,000 yr, shows that Saharan dust is the most important parent material for soils on all islands. These results indicate that the northeast trade winds have been an important component of the regional climatology for much of the Quaterary. Saharan dust may also be an important parent material for Caribbean island bauxites of much greater age. ?? 1990.

Quaternary Research↗

Genesis of marine terrace soils, Barbados, West Indies: evidence from mineralogy and geochemistry

Well-developed, clay-rich soils dominated by interstratified kaolinite-smectite are found on the uplifted coral reef terraces on the island of Barbados. The reef limestone is unlikely to have been the soil parent material however, because it is 98% CaCO 3 and geomorphic evidence argues against the 20 m of reef solution required to produce the soils by this process. The mineralogy of the sand, silt, and clay fractions of the soils, and trace element geochemistry, suggest that aeolian materials carried on the trade winds from Africa, volcanic ash from the island of St. Vincent, and quartz from Tertiary bedrock on the island itself are the parent materials for the soils. -Authors

Earth Surface Processes and Landforms↗

Limits of mountain and continental glaciations east of the Continental Divide in northern Montana and north-western North Dakota, U.S.A.

This chapter provides an overview of the limits of glaciations and glacial history in, and east and south-east of, Glacier National Park, Montana, and on the Northern Plains further east in Montana and north-western North Dakota. The term “Laurentide glacier” was applied to a continental ice sheet east of the Rocky Mountains in North America. It describes Laurentide Ice Sheet as any Quaternary continental ice sheet east of the Rocky Mountains in the United States and Canada. Laurentide till refers to till deposited by a Laurentide Ice Sheet. A Laurentide continental ice sheet is distinguished from a Cordilleran continental ice sheet in the Cordilleran region in parts of Washington, Idaho, and Montana in the United States and in adjacent Canada. Clague indicated that Cordilleran Ice Sheets formed several times during the Pleistocene. The chapter also reviews that the base for the digital map is simplified. Selected hydrographic features, selected towns and cities, selected physiographic features, and a grid of 1° × 2° topographic quadrangles are included to aid the reader in location of the glacial limits and other features depicted here on other maps at different scales.

Montana, North Dakota↗

Origin of the late quaternary dune fields of northeastern Colorado

Stabilized eolian deposits, mostly parabolic dunes and sand sheets, cover much of the landscape of northeastern Colorado and adjacent parts of southwestern Nebraska in four geographically distinct dune fields. Stratigraphic and soil-geomorphic relations and accelerator radiocarbon dating indicate that at least three episodes of eolian sand movement occurred between 27 ka and 11 ka, possibly between 11 ka and 4 ka, and within the past 1.5 ka. Thus, eolian sand deposition took place under both glacial and interglacial climatic conditions. In the youngest episodes of eolian sand movement, Holocene parabolic dunes partially buried Pleistocene sand sheet deposits. Late Holocene sands in the Fort Morgan and Wray dune fields, to the south of the South Platte River, have trace element ratios that are indistinguishable from modern South Platte River sands, but different from Ogallala Formation bedrock, which has previously been cited as the main source of dune sand on the Great Plains. Sands in the Greeley dune field, to the north of the South Platte River, have trace element concentrations that indicate a probable Laramie Formation source. Measurements of parabolic dunes indicate paleowinds from the northwest in all dune fields, in good agreement with resultant drift directions calculated for nearby weather stations. Thus, paleowinds were probably not significantly different from present-day winds, and are consistent with a South Platte River source for the Fort Morgan and Wray dune fields, and a Laramie Formation source for the Greeley dune field. Sand accumulated downwind of the South Platte River to form the Fort Morgan duen field. In addition, sand was also transported farther downwind over the upland formed by the calcrete caprock of the Ogallala Formation, and deposited in the lee of the upland on the southeast side. Because of high wind energy, the upland itself served as a zone of sand transport, but little or no sand accumulation took place on this surface. These studies, which demonstrate the importance of fluvial-source sediments for dune fields in Colorado, may be applicable to other dune fields in North America. Because modern drift potentials in northeastern Colorado are among the highest in the world, the present stability of dunes in the region may be in part a function of the dunes being supply-limited rather than solely transport-limited. Extensive (∼ 7700 km 2 ) late Holocene dunes document that eolian sand in northeastern Colorado is very sensitive to small changes in climate or fluvial source conditions.

Geomorphology↗

Geochemical hosts of solubilized radionuclides in uranium mill tailings

The solubilization and subsequent resorption of radionuclides by ore components or by reaction products during the milling of uranium ores may have both economic and environmental consequences. Particle-size redistribution of radium during milling has been demonstrated by previous investigators; however, the identification of sorbing components in the tailings has received little experimental attention. In this study, uranium-bearing sandstone ore was milled, on a laboratory scale, with sulfuric acid. At regular intervals, filtrate from this suspension was placed in contact with mixtures of quartz sand and various potential sorbents which occur as gangue in uranium ores; the potential sorbents included clay minerals, iron and aluminum oxides, feldspar, fluorspar, barite, jarosite, coal, and volcanic glass. After equilibration, the quartz sand-sorbent mixtures were separated from the filtrate and radioassayed by gamma-spectrometry to determine the quantities of 238 U, 230 Th, 226 Ra, and 210 Pb sorbed, and the radon emanation coefficients. Sorption of 238 U was low in all cases, with maximal sorptions of 1–2% by the bentonite- and coal-bearing samples. 230 Th sorption also was generally less than 1%; maximal sorption here was observed in the fluorspar-bearing sample and appears to be associated with the formation of gypsum during milling. 226 Ra and 210 Pb generally showed higher sorption than the other nuclides - more than 60% of the 26 Ra solubilized from the ore was sorbed on the barite-bearing sample. The mechanism (s) for this sorption by a wide variety of substrates is not yet understood. Radon emanation coefficients of the samples ranged from about 5 to 30%, with the coal-bearing samples clearly demonstrating an emanating power higher than any of the other materials.

Hydrometallurgy↗

Uranium-series dating of secondary carbonates near Yucca Mountain, Nevada. Applications to tectonic, paleoclimatic, and paleohydrologic problems

Near-surface accumulations of secondary carbonates are common in the soils and sediments of the Yucca Mountain area. These carbonates contain small amounts of uranium that allow dating by the uranium-series disequilibrium method. Preliminary results from the Yucca Mountain area indicate that the U-series methods can (1) identify multiple episodes of tectonic fracturing, (2) provide a chronologic framework for paleoclimatically significant eolian deposits, and (3) place constraints on the probable source of waters from which the carbonates precipitated.

Conference Paper↗

The Uranium-trend dating method: Principles and application for southern California marine terrace deposits

Uranium-trend dating is an open-system method for age estimation of Quaternary sediments, using disequilibrium in the 238U234U230Th decay series. The technique has been applied to alluvium, colluvium, loess, till, and marine sediments. In this study we tested the U-trend dating method on calcareous marine terrace deposits from the Palos Verdes Hills and San Nicolas Island, California. Independent age estimates indicate that terraces in these areas range from ???80 ka to greater than 1.0 Ma. Two low terraces on San Nicolas Island yielded U-trend plots that have a clustered array of points and the ages of these deposits are indeterminate or highly suspect. Middle Pleistocene terraces and one early Pleistocene terrace on San Nicolas Island and all terraces on the Palos Verdes Hills gave reasonably linear U-trend plots and estimated ages that are stratigraphically consistent and in agreement with independent age estimates. We conclude that many marine terrace deposits are suitable for U-trend dating, but U-trend plots must be carefully evaluated and U-trend ages should be consistent with independent geologic control. ?? 1989.

Quaternary International↗

Geochemistry and preliminary assessment of resource potential for postorogenic granites of the southwestern Arabian Shield, Kingdom of Saudi Arabia

Geochemical data for samples from 55 postorogenic plutons of the southwestern Arabian Shield show that these granitoids are generally less evolved than similar granitoids of the eastern Arabian Shield. Radioelement contents are low to normal relative to typical granitic rocks and uranium contents are distinctly low relative to rocks of the eastern Arabian Shield. The data indicate low favorability for ore deposits of elements that are typically enriched in granites at the end stages of magmatism such as tin, tungsten, niobium, tantalum, molybdenum, rare-earth elements, and radioactive elements. Regional geochemical patterns are not consistent with the north-south trending microplate boundary that has been proposed by other workers. Correlation coefficients for trace-element data obtained during the current study also argue against sharp compositional breaks in the protolith for the postorogenic granites. Consideration of the data presented here and similar data for granitoids of the eastern Arabian Shield, suggest the existence of a compositionally gradational protolith of continental affinity to the east and oceanic affinity to the west.

Open-File Report↗

Uranium series disequilibrium in a young surficial uranium deposit, northeastern Washington, U.S.A.

A recently discovered ore-grade accumulation of U in organic-rich sediments of late Quaternary age provides an opportunity for studying the early association of U, U-daughters, and organic matter in a natural setting. The U occurs in valley-fill sediments of peat, peaty clay, silt, and sand along the north fork of Flodelle Creek, Stevens County, Washington. Radiometric techniques (delayed neutron, high-resolution gamma-ray spectrometry, thin-source alpha spectrometry) were employed to determine the abundance and distribution of U-series nuclides, the extent of secular equilibrium within the U decay series, and the apparent U-series ages of U incorporation. Sixteen lithologically distinct intervals were sampled from a 292 cm core. Uranium contents range from 140 to 2790 ppm and are positively correlated with organic contents. Measured alpha activity ratios of 234 U/ 238 U (1.31–1.38) are very similar to those reported in coexisting waters, suggesting a rather constant isotopic composition of introduced U. Much lower Th contents of <10–40 ppm are controlled by the type and abundance of silicate detritus. The youth of the host sediments (<15 000 a) and the paucity of associated radioactivity suggested large excesses of U relative to radioactive daughters and such excesses were observed, particularly in the shallowest intervals. Apparent ages of U emplacement determined by the (alpha) activity ratio of 230 Th daughter to 234 U parent show a general increase with depth and fair agreement with estimated depositional ages. This observation suggests dominantly syndepositional or early post depositional emplacement of U followed by decay-generated buildup of 230 Th daughter with time. However, interval by interval comparisons of the relative abundances of other daughters, particularly 226 Ra and 210 Pb, indicate variability caused by processes other than closed-system growth and decay, probably because chemically diverse daughters that are decay-generated in situ have differing mobilities and because upwelling ground water continuously adds more U and minor amounts of daughters. If 230 Th is considered the least susceptible to these modifications, the data suggest some addition of 234 U in the deepest intervals and some loss of 226 Ra and/or gain of 222 Rn throughout the studied core.

Washington↗

Preliminary assessment of the geochemistry and mineral favorability of the postorogenic granites of the southeastern Arabian Shield, Kingdom of Saudi Arabia

Chemical analyses of samples for 19 postorogenic plutons from the southeastern Arabian Shield show that these rocks have average potassium/rubidium ratios (162) and average rubidium/strontium ratios (11.8) characteristic of highly evolved granites. Most of the analyzed samples are peraluminous. Three plutons are physically similar in terms of shape and megascopic textural zonation to peralkaline complexes in the northeastern part of the Shield, but none of the samples from these plutons is peralkaline. However, these plutons do contain the least-evolved samples. Zinc, yttrium, uranium, thorium, and possibly copper, each occur in anomalously high concentrations in at least one pluton relative to contents typically cited for granite. The average regional concentrations of copper and zinc are anomalously high. These facts suggest at least a moderate potential for mineralization in the southeastern part of the Shield. Good correlations (r of 0.5 to 0.8) between uranium, thorium, yttrium, and rubidium and an excellent correlation (r=0.98) between uranium and radium-equivalent uranium suggest that secondary deposits of these elements are unlikely and that magmatic deposits, especially of a pegmatitic nature, are more likely. Concentrations of some major elements and several trace elements covary with sample location as measured by latitude and longitude. This fact is interpreted to reflect regional variations in the protolith that have been proposed on the basis of lead isotopic data. The chemical variations suggest a largely oceanic crustal component for granites in the southwestern part of the southeastern Shield and a largely continental crustal component to the northeast. Further quantitative analysis is recommended to verify and accurately delineate anomalous concentrations of trace elements. Trend surface analysis of all available data for postorogenic granites from the eastern Arabian Shield is suggested as a method for testing regional variations in the protolith that might control locations of highly favorable areas of ore deposition.

Open-File Report↗