Geology topics

Bryant C. Jurgens

Publications and source records attributed to Bryant C. Jurgens.

At least 19 recordsLinked to original sources

USGS2026

Quality of groundwater used for domestic supply in the western Central Valley, California—2023

More than 2 million Californians rely on groundwater from domestic wells for their drinking-water supply. This report summarizes a 2023 California Groundwater Ambient Monitoring and Assessment Priority Basin Project water-quality survey of 44 domestic and small-system drinking-water supply wells in the western Sacramento Valley (basin number 5-021) and San Joaquin Valley (basin number 5-022) groundwater basins in the Central Valley, California, where more than 88,000 residents are estimated to utilize privately owned, domestic wells. The study area includes the Corning, Colusa, Yolo, and Solano subbasins (subbasin numbers 5-021.51, 5-021.52, 5-021.67, and 5-021.66, respectively) of the Sacramento Valley groundwater basin, and the East Contra Costa, Tracy, Delta-Mendota, and Westside subbasins (subbasin numbers 5-022.19, 5-022.15, 5-022.07, and 5-022.09, respectively) of the San Joaquin Valley groundwater basin. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of the aquifer system rather than groundwater resources used for public drinking-water supply, which are typically drawn from deeper parts. This assessment characterized the quality of ambient groundwater used for domestic supply, rather than the quality of drinking water at a tap or faucet, which may be filtered or treated after extraction. To provide context, concentrations of constituents in groundwater were compared to Federal and State of California regulatory and non-regulatory benchmarks for drinking-water quality. Regulatory benchmarks were U.S. Environmental Protection Agency and State of California maximum contaminant levels (MCLs) for drinking water. Non-regulatory benchmarks were State of California secondary maximum contaminant levels (SMCLs) for managing aesthetic conditions, such as taste, odor, or color. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking supply that have water-quality constituents present at high concentrations (greater than the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth of the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other California Groundwater Ambient Monitoring and Assessment Priority Basin Project study areas. In this study, inorganic constituents in groundwater were greater than regulatory benchmarks for public drinking-water quality in 30 percent of domestic groundwater resources. Inorganic constituents present at concentrations greater than MCLs for drinking water were hexavalent chromium, total chromium, and nitrate. Total dissolved solids, manganese, and iron were present at concentrations greater than their SMCL in 27 percent of domestic groundwater resources. 1,2,3-trichloropropane was present at concentrations greater than State of California MCLs for drinking water in 2.3 percent of domestic groundwater resources and was the only volatile organic compound detected at concentrations greater than a benchmark. Per-and polyfluoroalkyl substances were detected in 16 percent of domestic groundwater resources, and 2.3 percent had concentrations greater than U.S. Environmental Protection Agency MCLs. Total coliform bacteria and enterococci were detected in 9.1 and 2.3 percent of domestic groundwater resources, respectively. To understand groundwater quality in the study area, factors that affect groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential physical and chemical variables. Relevant factors include the oxidation-reduction conditions of groundwater, agricultural land use, and geologic sources of aquifer sediments. Manganese and iron concentrations were affected by oxidation-reduction state. Nitrate concentrations were affected by the interplay of agricultural practices and denitrification, where denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Ultramafic aquifer sediments in the western Central Valley provide a geogenic source for chromium and hexavalent chromium. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials, but agricultural practices may also contribute to these concentrations.

California↗

USGS2026

Status and understanding of groundwater quality in the San Joaquin Valley Kern County subbasin domestic-supply aquifer study unit, 2022—California GAMA Priority Basin Project

The quality of water accessed by domestic wells (here referred to as domestic groundwater resources) in the San Joaquin Valley Kern County subbasin (basin number 5-022.14) was assessed as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project (GAMA-PBP), in cooperation with the California State Water Resources Control Board. Kern County is at the southern end of the San Joaquin Valley in California, and about 30,000 residents are estimated to use privately owned domestic wells for drinking water. Domestic wells typically draw from shallower parts of the aquifer system than public-supply wells and can be more vulnerable to effects from surface activities. Kern County is host to a highly productive agricultural industry, with Bakersfield as the main urban center. The Kern River runs through Bakersfield from the southern Sierra Nevada and intersects the Kern Water Bank, one of the largest groundwater banking operations in California, at the Kern River Intertie. The section of the Kern River running through the Kern Water Bank is dry most years. Kern County also encompasses some of the most productive oil and gas basins in California, with extensive underground and surface disposal of oil-field wastewater. This study was based on data collected from 33 sites sampled by the U.S. Geological Survey for the GAMA-PBP in 2022. To provide context for the water quality assessment, measured concentrations were compared to regulatory and non-regulatory health-based and aesthetic benchmarks. A grid-based method was used to estimate the proportions of the groundwater resources used for domestic-supply wells that have water-quality constituents below (low relative concentration), approaching (moderate relative concentration), or above (high relative concentration) benchmark concentrations. At least one measured constituent with a regulatory benchmark was categorized as having a high relative concentration in 72 percent of the aquifer area used for domestic groundwater resources. Inorganic constituents were detected at high concentrations in 45 percent of the domestic groundwater resources, and the constituents detected above regulatory benchmarks were arsenic, nitrate, and uranium. At least one organic constituent was detected at high concentrations in 41 percent of the domestic groundwater resources, and the constituents exceeding regulatory benchmarks were the fumigants 1,2,3-trichloropropane (1,2,3-TCP), 1,2-dibromo-3-chloropropane (dibromochloropropane [DBCP]), 1,2-dibromoethane (EDB), and the per-and polyfluoroalkyl substance (PFAS) perfluorooctanesulfonate. The disinfection by-product chloroform, the fumigant 1,2-dichloropropane, the herbicides atrazine and hexazinone, and the herbicide degradates 2-chloro-6-ethylamino-4-amino-s-triazine, 2-chloro-4,6-diamino-s-triazine, 4-hydroxychlorothalonil, and metolachlor sulfonic acid were detected in more than 10 percent of domestic groundwater resources, but concentrations did not exceed regulatory benchmarks. Land use, groundwater age (fraction of modern water and mean age), and geochemical environment (oxic or anoxic conditions, pH, alkalinity) were associated with the distribution of high relative concentrations of inorganic and organic constituents. Young, oxygenated water is recharged along the Kern River and adjacent recharge ponds, or as irrigation water in the agricultural areas. High concentrations of nitrate and volatile organic compounds occurred in the oxic water in urban and agricultural areas. The fumigants 1,2,3-TCP, DBCP, and EDB were reported throughout the agricultural areas, whereas chloroform, tetrachloroethene, and PFAS were associated with urban land use. High uranium concentrations were associated with young, modern groundwater in agricultural areas with low pH and high bicarbonate. Total dissolved solids increased with distance from the Kern River, as the contributions of fresh, oxic water decreased. High concentrations of arsenic were present in older anoxic or alkaline groundwater away from areas of recharge. Overall, groundwater age, redox conditions, and the source of recharge as a result of different land uses contribute to large aquifer-scale portions of domestic groundwater resources that exceed health-based benchmarks for nitrate, uranium, and fumigant concentrations.

California↗

USGS2026

Decadal shifts in groundwater age detected by environmental tracers across California, USA

Groundwater age offers important insight into recharge, storage, and contamination risk. Although models predict age changes can be driven by pumping and climate variability, direct observational evidence remains limited. Here, we analyzed paired environmental tracer suites (tritium, carbon-14, and tritiogenic helium-3) collected a decade apart from 268 wells across California to assess the prevalence of groundwater age transience. Travel-time distribution models and statistical tests indicated age transience at 29% of sites, occurring most often in agricultural regions, such as the San Joaquin Valley and Southern Coast Ranges, where large carbon-14 changes coincided with substantial nitrate and chloride shifts. Sites with tritiogenic helium-3 data showed more frequent age transience, underscoring the value of multi-tracer data sets. These results provide the first regional evidence of widespread groundwater age change and a method for detecting changing water balances with implications for groundwater sustainability and water quality.

California↗

USGS2026

Legacy of the fumigant 1,2-dibromo-3-chloropropane (DBCP) in California groundwater

The fumigant pesticide 1,2-dibromo-3-chloropropane (DBCP) was widely used in California agriculture during the 1960s and 1970s before being banned in 1979. Despite this ban, DBCP continues to contaminate groundwater due to its persistence and mobility. This study evaluates the distribution, historical trends, and projected persistence of DBCP in California using data from over 13,000 public supply wells and additional domestic, irrigation, and observation wells (1980-2022). Since 2010, DBCP has been detected in 9% of public supply wells statewide, with higher frequencies in the San Joaquin Valley (21%) and upper Santa Ana River watershed (13%), where DBCP use was most prevalent. Approximately 70% of wells had decreasing concentration trends, whereas increases were more common in deeper wells, indicating downward vertical migration of the DBCP front. Groundwater age estimates show that recharge timing aligns with the 1960s–1970s loading period, enabling reconstruction of peak inputs and providing a basis for age based modeling. To estimate future persistence, we applied a one dimensional advection–dispersion model that simulates long term declines in peak concentrations based on groundwater age, historical loading, and a 38 year degradation half life. Model projections suggest that concentrations above the maximum contaminant level may persist in a declining number of wells until approximately 2080 (range: 2048–2109), with longer persistence in the San Joaquin Valley. The simplified modeling framework, based on age distributions typical of wells capturing peak concentrations, can provide practical regional scale assessment of non-point source contaminants where long-term monitoring exists. This study highlights how the legacy of DBCP contamination will likely affect California's groundwater resources throughout the 21st century.

California↗

USGS2025

Quality of groundwater used for domestic supply in the Gilroy-Hollister basin and surrounding areas, California, 2022

More than 2 million Californians rely on groundwater from domestic wells for drinking-water supply. This report summarizes a 2022 California Groundwater Ambient Monitoring and Assessment Priority Basin Project (GAMA-PBP) water-quality survey of 33 domestic and small-system drinking-water supply wells in the Gilroy-Hollister Valley groundwater basin and the surrounding areas, where more than 20,000 residents are estimated to utilize privately owned domestic wells. The study area includes the Llagas subbasin in the north, the North San Benito subbasin in the south, and the surrounding uplands. The study was focused on groundwater resources used for domestic drinking-water supply, which are mostly drawn from shallower parts of aquifer systems rather than those of groundwater resources used for public drinking-water supply in the same area. This assessment characterized the quality of ambient groundwater in the aquifer before filtration or treatment, rather than the quality of drinking water delivered to the tap. To provide context, the measured concentrations of constituents in groundwater were compared to Federal and California State regulatory and non-regulatory benchmarks for drinking-water quality. A grid-based method was used to estimate the areal proportions of groundwater resources used for domestic drinking wells that have water-quality constituents present at high concentrations (above the benchmark), moderate concentrations (between one-half of the benchmark and the benchmark for inorganic constituents, or between one-tenth of the benchmark and the benchmark for organic constituents), and low concentrations (less than one-half or one-tenth the benchmark for inorganic and organic constituents, respectively). This method provides statistically representative results at the study-area scale and permits comparisons to other GAMA-PBP study areas. In the study area, inorganic constituents in groundwater were greater than regulatory benchmarks (U.S. Environmental Protection Agency [EPA] or State of California maximum contaminant levels [MCLs]) for public drinking-water quality in 24 percent of domestic groundwater resources. The inorganic constituents present at concentrations greater than MCLs for drinking water were nitrate (as nitrogen), barium, chromium, and selenium. Total dissolved solids (TDS) or manganese were present at concentrations greater than the secondary maximum contaminant levels (SMCLs) that the State of California uses as aesthetic-based benchmarks in 48 percent of domestic groundwater resources. No volatile organic compounds or pesticide constituents were present at concentrations greater than regulatory benchmarks. Total coliform bacteria and enterococci were detected in 4 percent of domestic groundwater resources. Per- and polyfluoroalkyl substances (PFAS) were detected in 19 percent of domestic groundwater resources, and 10 percent had concentrations greater than recently enacted (April 2024) EPA MCLs. Physical and chemical factors from natural and anthropogenic sources that could affect the groundwater quality were evaluated using results from statistical testing of associations between constituent concentrations and potential explanatory variables. In this study, relevant physical factors include well construction characteristics, groundwater age, site proximity to groundwater recharge or discharge zones, and potential sources of contamination. Relevant chemical factors include the initial chemistry of the recharge water, the mineralogy of the aquifer sediments, and the subsequent shifts in chemistry as biologic and geologic reactions alter groundwater in the subsurface. Nitrate concentrations were correlated to agricultural land use, distance from the boundary of the Gilroy-Hollister Valley groundwater basin, and the proportion of modern (post-1950s) water captured by the well. Denitrification under anoxic redox conditions can mitigate some nitrate derived from fertilizer application. Total dissolved solids primarily were derived from water-rock interactions with soils and aquifer materials in the study area, but there were high concentrations where agricultural practices contributed additional TDS. Mineralogy of aquifer sediments and rocks also affect barium, selenium, boron, and chromium concentrations in the Gilroy-Hollister Valley groundwater basin. PFAS were positively correlated with urban land use and the proportion of modern water captured by the well.

California↗

USGS2025

The systematics of stable hydrogen (δ2H) and oxygen (δ18O) isotopes and tritium (3H) in the hydrothermal system of the Yellowstone Plateau volcanic field, USA

To improve our understanding of hydrothermal activity on the Yellowstone Plateau volcanic field, we collected and analyzed a large data set of δ 2 H, δ 18 O, and the 3 H concentrations of circum-neutral and alkaline waters. We find that (a) hot springs are fed by recharge throughout the volcanic plateau, likely focused through fractured, permeable tuff units. Previous work had stressed the need for light δ 2 H water recharge restricted to the northern part of the plateau or recharge during past cold periods. However, new data from the Y-7 drill hole suggests that recharge is not restricted to a certain area or a cold period. (b) δ 18 O values of thermal waters in the geyser basins are shifted from the global meteoric water line by temperature-dependent water-rock reactions with higher subsurface temperatures resulting in a greater shift. (c) Large temporal variations in the isotopic composition of meteoric water recharge and small temporal variability in the isotopic composition of hot spring discharge implies that the volume of groundwater in, and around the Yellowstone caldera is substantially larger than the volume of annual water recharge. (d) Hot springs discharged through different rhyolitic units correlate with identifiable differences in δ 2 H and δ 18 O compositions, 3 H concentrations, and water chemistry that imply equilibration at different temperatures and travel along different flow paths. (e) Based on measured 3 H concentrations, we calculate that hot spring waters in the central part of the geyser basins mostly contain <2% post-1950 meteoric water, whereas waters discharged at the basin margins contain larger fractions of post-1950s meteoric water.

Wyoming↗

USGS2024

Basin-scale responses of groundwater-resource quality to drought and recovery, San Joaquin Valley, California

Groundwater-resource quality is assumed to be less responsive to drought compared to that of surface water due to relatively long transit times of recharge to drinking-supply wells. Here, we evidence dynamic perturbations in aquifer pressure dynamics during drought and subsequent recovery periods cause dramatic shifts in groundwater quality on a basin scale. We used a novel application of time-series clustering on annual nitrate anomalies at >450 public-supply wells (PSWs) across California's San Joaquin Valley during 2000–22 to group sub-populations of wells with similar water-quality responses to drought. Additionally, we statistically evaluated the direction and magnitude of multi-constituent water-quality changes across the San Joaquin Valley using a broader dataset of >3000 PSWs with data during two select hydrologic stress periods representing an extreme drought (2012–16) and subsequent recovery (2016–19). Results of time-series clustering and stress-period change analyses corroborate a predominant regional response to pumping stress characterized by increased concentrations of anthropogenic constituents (nitrate, total dissolved solids) and decreased concentrations of geogenic constituents (arsenic, fluoride), which largely reversed during recovery. Cluster analysis also identified a secondary, less commonly occurring group of PSWs where nitrate decreased during drought, but explanatory factor analysis was not able to discern hydrogeologic drivers for these two divergent response patterns. Long-term tracer data support the hypothesis that the predominant regional signal of nitrate increase during drought is caused by enhanced capture of modern-aged groundwater by PSWs during periods of pumping stress, which can drive rapid changes in water quality on seasonal and multiannual timescales. Pumping-induced migration of modern, oxic groundwater to depth during drought may affect geochemical conditions in deeper portions of regional aquifers controlling the mobility of geogenic contaminants over the long term.

California↗

USGS2024

Predictions of groundwater PFAS occurrence at drinking water supply depths in the United States

Per- and polyfluoroalkyl substances (PFAS), known colloquially as “forever chemicals”, have been associated with adverse human health effects and have contaminated drinking water supplies across the United States owing to their long-term and widespread use. People in the United States may unknowingly be drinking water that contains PFAS because of a lack of systematic analysis, particularly in domestic water supplies. We present an extreme gradient boosting model for predicting the occurrence of PFAS in groundwater at the depths of drinking water supply for the conterminous United States. Our model results indicate that 71 to 95 million people in the conterminous United States potentially rely on groundwater with detectable concentrations of PFAS for their drinking-water supplies prior to any treatment.

conterminous United States↗

USGS2023

Salinity trends in a groundwater system supplemented by 50 years of imported Colorado River water

The Indio subbasin of the Coachella Valley is a desert area of southern California where a growing population depends primarily on groundwater for drinking and agricultural uses. The aquifer system has been supplemented with Colorado River water through managed recharge and widespread irrigation since the mid-20th century. We use a combination of geochemical modeling and trend analysis to identify changes in total dissolved solids through time, elucidate the sources of dissolved solids, and quantify the extent of contributions from those sources throughout the Indio subbasin. We conclude that recharged Colorado River water is the primary source and driver of increasing salinity, particularly in areas immediately downgradient from the recharge locations and in the eastern part of the subbasin away from the recharge ponds due to irrigation using imported water. Other contributions of dissolved solids to groundwater resources include geothermal waters, wastewater effluent, and agricultural return flow, although their effects are more localized. This study presents a broadly applicable framework for identifying sources of dissolved solids in groundwater wells and salinity trends at a regional scale in a large data set.

California↗

USGS2023

Karst groundwater vulnerability determined by modeled age and residence time tracers

Karst aquifers are a vital groundwater resource globally, but features such as rapid recharge and conduit flow make them highly vulnerable to land-surface contamination. We apply environmental age tracers to the south-central Texas Edwards aquifer, a karst resource in a rapidly urbanizing and drought-prone region, to assess vulnerability to land-surface contamination and risks unique to karst aquifers. We show that vulnerability of Edwards aquifer groundwater follows similar spatial and depth patterns common to porous-media type aquifers, despite complicated karst hydrogeologic features. Shallow and unconfined parts are more vulnerable to land-surface contamination than the deeper and confined parts, although even the oldest groundwater is mixed with some recent recharge. When modeled age-tracer results are coupled with other independent geochemical tracers of water-rock interaction specific to karst settings, they can yield insight into residence time and associated vulnerability.

Texas↗

USGS2023

Modeling the dynamic penetration depth of post-1950s water in unconfined aquifers using environmental tracers: Central Valley, California

The penetration depth of post-1950s recharge (D-1950) in aquifers is a marker that is frequently used to identify groundwater that is susceptible to anthropogenic contamination. Here, we compute D-1950 values at wells, interpolate them in space, and project them across time to map the moving front of modern recharge in four dimensions in the Central Valley aquifer system, California, USA. Tracers of groundwater age (tritium, carbon-14, noble gases, sulfur hexafluoride, and chlorofluorocarbons) were collected at 650 wells spatially distributed throughout the Central Valley and were fit to a lumped-parameter model that assumes a logarithmic age-depth profile in the aquifer. For samples where tritium was present (>0.3 tritium units), the model was used to predict D-1950 at wells screened above or across the modern-premodern interface (n = 484). Wells with samples where tritium was absent (≤0.3 tritium units) were used to define the depth beyond which groundwater is completely premodern (n = 166). Predicted D-1950 values were below the depth of screen bottoms for wells where groundwater is completely modern, and above the depth of screen tops for wells where groundwater is completely premodern. The interpolated surface of D-1950 is dynamic, less prone to extreme values, and produces maps with lower interpolation errors due to a higher spatial density of wells than maps based on the depth of premodern groundwater. Between 2005 and 2025, D-1950 is expected to deepen by 11 and 12 m in the northern and southern parts of the Central Valley, respectively. Areas where D-1950 increases rapidly are likely to see increases in nitrate and other anthropogenic contaminants associated with the downward moving front of modern water.

California↗

USGS2022

Quality of groundwater used for public supply in the continental United States: A comprehensive assessment

The presence of contaminants in a source water can constrain its suitability for drinking. The quality of groundwater used for public supply was assessed in 25 principal aquifers (PAs) that account for 84% of groundwater pumped for public supply in the U.S. (89.6 million people on a proportional basis). Each PA was sampled across its lateral extent using an equal-area grid, typically with 60 wells per PA. Samples were analyzed for 502 constituents, of which 374 had either a regulatory or nonregulatory human health benchmark (HHB). Nationally, elevated concentrations (relative to HHBs) of geogenic constituents have a larger effect than anthropogenic constituents, as indicated by three metrics: detection frequency, 35% versus 8.1%; prevalence (based on area), 41% versus 6.4%; and population potentially affected, 31.2 million versus 7.1 million. Prevalence of any constituent at elevated concentrations was high─40 to 75%─in PAs comprising unconsolidated sediment (eight PAs) and sandstone or interbedded sandstones and carbonates (four PAs) in the West and Central Interior. Prevalence was lower─15 to 35%─in PAs comprising sediment and sedimentary rocks along the Gulf and Atlantic Coasts (four PAs), carbonates distributed across the continental U.S. (seven PAs), and hard rock (two PAs).

continental United States↗

USGS2022

Over a third of groundwater in USA public-supply aquifers is Anthropocene-age and susceptible to surface contamination

The distribution of groundwater age is useful for evaluating the susceptibility and sustainability of groundwater resources. Here, we compute the aquifer-scale cumulative distribution function to characterize the age distribution for 21 Principal Aquifers that account for ~80% of public-supply pumping in the United States. The aquifer-scale cumulative distribution function for each Principal Aquifer was derived from an ensemble of modeled age distributions (~60 samples per aquifer) based on multiple tracers: tritium, tritiogenic helium-3, sulfur hexafluoride, chlorofluorocarbons, carbon-14, and radiogenic helium-4. Nationally, the groundwater is 38% Anthropocene (since 1953), 34% Holocene (75 – 11,800 years ago), and 28% Pleistocene (>11,800 years ago). The Anthropocene fraction ranges from <5 to 100%, indicating a wide range in susceptibility to land-surface contamination. The Pleistocene fraction of groundwater exceeds 50% in 7 eastern aquifers that are predominately confined. The Holocene fraction of groundwater exceeds 50% in 5 western aquifers that are predominately unconfined. The sustainability of pumping from these Principal Aquifers depends on rates of recharge and release of groundwater stored in fine-grained layers.

Nature Communications Earth & Environment↗

USGS2022

Effects of imported recharge on fluoride trends in groundwater used for public supply in California

Fluoride is a naturally occurring element in groundwater that supports bone and dental health at low concentrations but can cause health problems at elevated concentrations in drinking water. This study investigates spatial and temporal trends for fluoride concentrations in untreated groundwater from over 20,000 public supply wells in California. The presence of a significant temporal trend in fluoride concentrations in a well was assessed using the Mann-Kendall test and a spatial-weighting approach was used to identify the areal extent of the groundwater resources with significant trends. Less than 2% of the groundwater resources used for public supply in the state have concentrations above the California maximum contaminant level of 2 mg/L. Approximately 14% of the groundwater resource used for public supply show a significant recent trend (2000–2019), with decreasing trends occurring in 10% of the resource. Potential drivers for trends were evaluated in two of the areas in southern California with the greatest prevalence of trends but distinct climate and hydrogeological characteristics. Aquifers in the Mojave and Whitewater River watersheds, located in the desert region, and the Los Angeles Basin, located on the coast, have been replenished with imported and treated water over the last half century to maintain sustainable groundwater levels. The recharge of imported water with different chemistries has altered the geochemical conditions in the aquifers, driving changes in fluoride concentrations.

California↗

USGS2021

Critical aquifer overdraft accelerates degradation of groundwater quality in California’s Central Valley during drought

Drought-induced pumpage has precipitated dramatic groundwater-level declines in California’s Central Valley over the past 30 years, but the impacts of aquifer overdraft on water quality are poorly understood. This study coupled over 160,000 measurements of nitrate from ∼6,000 public-supply wells with a 30-year reconstruction of groundwater levels throughout the Central Valley to evaluate dynamic relations between aquifer exploitation and resource quality. We find that long-term rates of groundwater-level decline and water-quality degradation in critically overdrafted basins accelerate by respective factors of 2–3 and 3–5 during drought, followed by brief reversals during wetter periods. Episodic water-quality degradation can occur during drought where increased pumpage draws shallow, contaminated groundwater down to depth zones tapped by long-screened production wells. These data show, for the first time, a direct linkage between climate-mediated aquifer pumpage and groundwater quality on a regional scale.

California↗

USGS2021

DGMETA (version 1)—Dissolved gas modeling and environmental tracer analysis computer program

DGMETA (Dissolved Gas Modeling and Environmental Tracer Analysis) is a Microsoft Excel-based computer program that is used for modeling air-water equilibrium conditions from measurements of dissolved gases and for computing concentrations of environmental tracers that rely on air-water equilibrium model results. DGMETA can solve for the temperature, salinity, excess air, fractionation of gases, or pressure/elevation of water when it is equilibrated with the atmosphere. Models are calibrated inversely using one or more measurements of dissolved gases such as helium, neon, argon, krypton, xenon, and nitrogen. Excess nitrogen gas, originating from denitrification or other sources, also can be included as a fitted parameter or as a separate calculation from the dissolved gas modeling results. DGMETA uses the air-water equilibrium models to separate measured concentrations of gases and isotopes of gases into components that are used for tracing water in the environment. DGMETA calculates atmospheric dry-air mole fractions (mixing ratios) for transient atmospheric gas tracers such as chlorofluorocarbons, sulfur hexafluoride, and bromotrifluoromethane (Halon-1301); and concentrations of tritiogenic helium-3 and radiogenic helium-4, which accumulate from the decay of tritium in water and the decay of uranium and thorium in rocks, respectively. Sample data can be graphed to identify applicable models of excess air, samples that contain excess nitrogen gas, or samples that have partially degassed, for example. Monte Carlo analysis of errors associated with dissolved gas equilibrium model results can be carried through computations of environmental tracer concentrations to provide robust estimates of error. In addition, graphical routines for separating helium sources using helium isotopes are included to refine estimates of tritiogenic helium-3 when terrigenic helium from mantle or crustal sources is present in samples. Environmental tracer concentrations and their errors computed from DGMETA can be used with other programs, such as TracerLPM (Jurgens and others, 2012), to determine groundwater ages and biogeochemical reaction rates. DGMETA also produces output files in a format that meets the U.S. Geological Survey open data requirements for documentation of model inputs and outputs. DGMETA is a versatile and adaptable program that allows users to add solubility data for new gases, modify the existing set of gas solubility data, modify the default set of gases used for modeling, choose calculations based on real (non-ideal) gas behavior, and select various concentration units for data entry and results to match laboratory reports and study objectives. DGMETA comes with a set of gases widely used in hydrology and oceanography and many gases include multiple solubilities from previous work. Seventeen dissolved gases are included in the default version of the program: noble gases (helium, neon, argon, krypton, and xenon), reactive gases (nitrogen, oxygen, methane, carbon dioxide, carbon monoxide, hydrogen, and nitrous oxide), and environmental tracers (chlorofluorocarbon-11, chlorofluorocarbon-12, chlorofluorocarbon-113, sulfur hexafluoride, and Halon-1301).

Techniques and Methods↗

USGS2021

A multi-tracer and well-bore flow profile approach to determine occurrence, movement, and sources of perchlorate in groundwater

The purpose of this study is to determine the occurrence, movement and sources of perchlorate in groundwater using a comprehensive set of environmental tracers coupled with discreet borehole data. Potential sources of perchlorate to groundwater at the study site have been attributed to waste disposal and industrial activities as well as to past agricultural operations. Perchlorate concentrations in samples ranged from <1 to 40 g/l, with a median of 6.1 g/l. Concentrations were relativity consistent with depth except at one site where dilution may be occurring due to the infiltration of surface water from Pyrite Creek. Well-bore flow profiles indicated that perchlorate redistribution was occurring via intra-well bore flow at one site where up to 14,000 mg/year of perchlorate could be moving from the shallower to the deeper zones of the alluvial aquifer. Natural attenuation processes of perchlorate do not appear to be widespread in groundwater but does occur in portions of the aquifer adjacent to the Santa Ana River, likely limiting the mobility of perchlorate from the southernmost extent of the mapped plume to areas further down-gradient. Age dating tracers indicate that perchlorate originating from the waste disposal ponds has largely moved through the zones of the aquifer sampled. Age distributions, noble gas temperature, delta neon values and stable isotopes of water indicate that a substantial fraction of perchlorate in groundwater may have been mobilized from the unsaturated zone and/or is from the infiltration of storm water runoff originating from Pyrite Canyon.

California↗

USGS2021

Groundwater development leads to decreasing arsenic concentrations in the San Joaquin Valley, California

In the San Joaquin Valley (SJV), California, about 10% of drinking water wells since 2010 had arsenic concentrations above the US maximum contaminant level of 10 μg/L. High concentrations of arsenic are often associated with high pH (greater than 7.8) or reduced geochemical conditions. Although most wells have low arsenic (<3 μg/L) and do not have changing arsenic concentrations, this study found that most wells with concentrations above 10 μg/L had arsenic trends. Overall, about 24% of wells had time-series trends since 2010 and 59% had paired-sample trends since 2000. Most wells had decreasing arsenic trends, even in wells with higher arsenic concentrations. These wells often had co-detections of increasing nitrate and sulfate trends that reflect oxic groundwater likely derived from agricultural recharge. Wells with increasing arsenic trends were deeper or located in the valley trough where aquifer materials are more fine-grained and where reducing conditions favor arsenic mobility. Wells with arsenic trends also tend to be clustered near areas of higher well density. Groundwater pumping in these areas has likely increased the contribution of younger, more oxic groundwater in wells with declining arsenic or, less frequently, increased the contribution of higher pH or reduced groundwater in wells with rising arsenic. Projections of arsenic trends indicate that 37 wells with high arsenic presently will be below 10 μg/L in ten years. Unfortunately, these improvements will be largely offset by 31 wells that are expected to increase above 10 μg/L in addition to expected rises in nitrate in wells where arsenic decreased. This study shows how human-altered flow systems can impact the natural geochemical character of water in both beneficial and deleterious ways.

California↗