Bradley R. Hacker | Geology Reports

USGS2013

Intermediate-depth earthquakes facilitated by eclogitization-related stresses

Eclogitization of the basaltic and gabbroic layer in the oceanic crust involves a volume reduction of 10%–15%. One consequence of the negative volume change is the formation of a paired stress field as a result of strain compatibility across the reaction front. Here we use waveform analysis of a tiny seismic cluster in the lower crust of the downgoing Pacific plate and reveal new evidence in favor of this mechanism: tensional earthquakes lying 1 km above compressional earthquakes, and earthquakes with highly similar waveforms lying on well-defined planes with complementary rupture areas. The tensional stress is interpreted to be caused by the dimensional mismatch between crust transformed to eclogite and underlying untransformed crust, and the earthquakes are probably facilitated by reactivation of fossil faults extant in the subducting plate. These observations provide seismic evidence for the role of volume change–related stresses and, possibly, fluid-related embrittlement as viable processes for nucleating earthquakes in downgoing oceanic lithosphere.

Geology↗

USGS2005

The calcite → aragonite transformation in low-Mg marble: Equilibrium relations, transformations mechanisms, and rates

Experimental transformation of a rather pure natural calcite marble to aragonite marble did not proceed via the expected straightforward polymorphic replacement. Instead, the small amount of Mg in the starting material (0.36 wt %) was excluded from the growing aragonite and diffused preferentially into the remaining calcite grains, producing Mg-rich calcite rods that persisted as relicts. Nucleation of aragonite occurred exclusively on grain boundaries, with aragonite [001] oriented subparallel to calcite [0001]. The aragonite crystals preferentially consumed the calcite crystal on which they nucleated, and the reaction fronts developed preferentially along the {010} and {110} planes of aragonite. Each aragonite neoblast that grew was nearly free of Mg (typically <0.1 wt %). The excess Mg was taken up by the calcite grains in between, stabilizing them and causing a few volume percent rodlike relicts of Mg-enriched calcite (up to 10 wt % MgO) to be left behind by the advancing reaction front. The aragonite growth rates are approximately linear and range from &sim;3 × 10 −11 m s −1 at 600°C to &sim;9 × 10 −9 m s −1 at 850°C, with an apparent activation enthalpy of 166 ± 91 kJ mol −1 . This reaction mechanism and the resultant texture are akin to cellular precipitation reactions in metals. Similar transformation textures have been reported from high-Mg marbles in Japan and China that disproportionated to low-Mg calcite and dolomite.

Journal of Geophysical Research B: Solid Earth↗