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Brad S. Singer

Publications and source records attributed to Brad S. Singer.

6 recordsLinked to original sources

Interpreting and reporting 40Ar/39Ar geochronologic data

The 40 Ar/ 39 Ar dating method is among the most versatile of geochronometers, having the potential to date a broad variety of K-bearing materials spanning from the time of Earth’s formation into the historical realm. Measurements using modern noble-gas mass spectrometers are now producing 40 Ar/ 39 Ar dates with analytical uncertainties of ∼0.1%, thereby providing precise time constraints for a wide range of geologic and extraterrestrial processes. Analyses of increasingly smaller subsamples have revealed age dispersion in many materials, including some minerals used as neutron fluence monitors. Accordingly, interpretive strategies are evolving to address observed dispersion in dates from a single sample. Moreover, inferring a geologically meaningful “age” from a measured “date” or set of dates is dependent on the geological problem being addressed and the salient assumptions associated with each set of data. We highlight requirements for collateral information that will better constrain the interpretation of 40 Ar/ 39 Ar data sets, including those associated with single-crystal fusion analyses, incremental heating experiments, and in situ analyses of microsampled domains. To ensure the utility and viability of published results, we emphasize previous recommendations for reporting 40 Ar/ 39 Ar data and the related essential metadata, with the amendment that data conform to evolving standards of being findable, accessible, interoperable, and reusable (FAIR) by both humans and computers. Our examples provide guidance for the presentation and interpretation of 40 Ar/ 39 Ar dates to maximize their interdisciplinary usage, reproducibility, and longevity.

GSA Bulletin

Geomorphic expression of rapid Holocene silicic magma reservoir growth beneath Laguna del Maule, Chile

Large rhyolitic volcanoes pose a hazard, yet the processes and signals foretelling an eruption are obscure. Satellite geodesy has revealed surface inflation signaling unrest within magma reservoirs underlying a few rhyolitic volcanoes. Although seismic, electrical, and potential field methods may illuminate the current configuration and state of these reservoirs, they cannot fully address the processes by which they grow and evolve on geologic time scales. We combine measurement of a deformed paleoshore surface, isotopic dating of volcanism and surface exposure, and modeling to determine the rate of growth of a rhyolite-producing magma reservoir. The numerical approach builds on a magma intrusion model developed to explain the current, decade-long, surface inflation at >20 cm/year. Assuming that the observed 62-m uplift reflects several non-eruptive intrusions of magma, each similar to the unrest over the past decade, we find that ~13 km 3 of magma recharged the reservoir at a depth of ~7 km during the Holocene, accompanied by the eruption of ~9 km 3 of rhyolite. The long-term rate of magma input is consistent with reservoir freezing and pluton formation. Yet, the unique set of observations considered here implies that large reservoirs can be incubated and grow at shallow depth via episodic high-flux magma injections. These replenishment episodes likely drive rapid inflation, destabilize cooling systems, propel rhyolitic eruptions, and thus should be carefully monitored.

Laguna del Maule

Incremental heating of Bishop Tuff sanidine reveals preeruptive radiogenic Ar and rapid remobilization from cold storage

Recent improvements in analytical and microsampling techniques for multiple geochronometers have resulted in datasets with unprecedented temporal and spatial resolution. These advances are accompanied by the discovery of crystal- and outcrop-scale complexities previously obscured by low analytical precision. Single-crystal incremental heating resolves subtle, intracrystal isotopic heterogeneity, allowing for more-accurate 40 Ar/ 39 Ar eruption ages. The eruption ages of widespread volcanic ash deposits are critical for calibrating the geologic timescale, and thus their accuracy has substantial implications for the geologic, biologic, and global climate records. Complex distribution of 40 Ar/ 39 Ar dates in the deposits of supervolcanic eruptions requires rethinking the magmatic processes and their effect on the 40 Ar/ 39 Ar system, specifically the extent of cooling and remobilization during the decades to centuries preceding these events.

California

The timing of compositionally-zoned magma reservoirs and mafic 'priming' weeks before the 1912 Novarupta-Katmai rhyolite eruption

The June 6, 1912 eruption of more than 13 km3 of dense rock equivalent (DRE) magma at Novarupta vent, Alaska was the largest of the 20th century. It ejected >7 km3 of rhyolite, ~1.3 km3 of andesite and ~4.6 km3 of dacite. Early ideas about the origin of pyroclastic flows and magmatic differentiation (e.g., compositional zonation of reservoirs) were shaped by this eruption. Despite being well studied, the timing of events that led to the chemically and mineralogically zoned magma reservoir remain poorly known. Here we provide new insights using the textures and chemical compositions of plagioclase and orthopyroxene crystals and by reevaluating previous U-Th isotope data. Compositional zoning of the magma reservoir likely developed a few thousand years before the eruption by several additions of mafic magma below an extant silicic reservoir. Melt compositions calculated from Sr contents in plagioclase fill the compositional gap between 68 and 76% SiO2 in whole pumice clasts, consistent with uninterrupted crystal growth from a continuum of liquids. Thus, our findings support a general model in which large volumes of crystal-poor rhyolite are related to intermediate magmas through gradual separation of melt from crystal-rich mush. The rhyolite is incubated by, but not mixed with, episodic recharge pulses of mafic magma that interact thermochemically with the mush and intermediate magmas. Hot, Mg-, Ca-, and Al-rich mafic magma intruded into, and mixed with, deeper parts of the reservoir (andesite and dacite) multiple times. Modeling the relaxation of the Fe-Mg concentrations in orthopyroxene and Mg in plagioclase rims indicates that the final recharge event occurred just weeks prior to the eruption. Rapid addition of mass, volatiles, and heat from the recharge magma, perhaps aided by partial melting of cumulate mush below the andesite and dacite, pressurized the reservoir and likely propelled a ~10 km lateral dike that allowed the overlying rhyolite to reach the surface.

Earth and Planetary Science Letters

Dynamics of a large, restless, rhyolitic magma system at Laguna del Maule, southern Andes, Chile

Explosive eruptions of large-volume rhyolitic magma systems are common in the geologic record and pose a major potential threat to society. Unlike other natural hazards, such as earthquakes and tsunamis, a large rhyolitic volcano may provide warning signs long before a caldera-forming eruption occurs. Yet, these signs—and what they imply about magma-crust dynamics—are not well known. This is because we have learned how these systems form, grow, and erupt mainly from the study of ash flow tuffs deposited tens to hundreds of thousands of years ago or more, or from the geophysical imaging of the unerupted portions of the reservoirs beneath the associated calderas. The Laguna del Maule Volcanic Field, Chile, includes an unusually large and recent concentration of silicic eruptions. Since 2007, the crust there has been inflating at an astonishing rate of at least 25 cm/yr. This unique opportunity to investigate the dynamics of a large rhyolitic system while magma migration, reservoir growth, and crustal deformation are actively under way is stimulating a new international collaboration. Findings thus far lead to the hypothesis that the silicic vents have tapped an extensive layer of crystal-poor, rhyolitic melt that began to form atop a magmatic mush zone that was established by ca. 20 ka with a renewed phase of rhyolite eruptions during the Holocene. Modeling of surface deformation, magnetotelluric data, and gravity changes suggest that magma is currently intruding at a depth of ~5 km. The next phase of this investigation seeks to enlarge the sets of geophysical and geochemical data and to use these observations in numerical models of system dynamics.

Laguna del Maule Volcanic Field

Geology and 40 Ar/ 39 Ar geochronology of the medium- to high-K Tanaga volcanic cluster, western Aleutians

We used geologic mapping and geochemical data augmented by 40 Ar/ 39 Ar dating to establish an eruptive chronology for the Tanaga volcanic cluster in the western Aleutian arc. The Tanaga volcanic cluster is unique in comparison to other central and western Aleutian volcanoes in that it consists of three closely spaced, active, volumetrically significant edifices (Sajaka, Tanaga, and Takawangha), the eruptive products of which have unusually high K 2 O contents. Thirty-five new 40 Ar/ 39 Ar ages obtained in two different laboratories constrain the duration of Pleistocene–Holocene subaerial volcanism to younger than 295 ka. The eruptive activity has been mostly continuous for the last 150 k.y., unlike most other well-characterized arc volcanoes, which tend to grow in discrete pulses. More than half of the analyzed Tanaga volcanic cluster lavas are basalts that have erupted throughout the lifetime of the cluster, although a considerable amount of basaltic andesite and basaltic trachyandesite has also been produced since 200 ka. Major- and trace-element variations suggest that magmas from Sajaka and Tanaga volcanoes are likely to have crystallized pyroxene and/or amphibole at greater depths than the older Takawangha magmas, which experienced a larger percentage of plagioclase-dominated fractionation at shallower depths. Magma output from Takawangha has declined over the last 86 k.y. At ca. 19 ka, the focus of magma flux shifted to the west beneath Tanaga and Sajaka volcanoes, where hotter, more mafic magma erupted.

Alaska