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Bernard E. Hubbard

Publications and source records attributed to Bernard E. Hubbard.

At least 19 recordsLinked to original sources

Spectral characteristics and mapping of lithium-rich playas in the Basin and Range Province, western United States

This report presents a comprehensive set of prospectivity maps for lithium in brines located within the playas of the Basin and Range Province of western United States. The prospectivity assessment is based on criteria established in the descriptive deposit model outlined in a previous U.S. Geological Survey report, with a focus on regional remote sensing methodologies. The playas within the study area have been systematically ranked according to several key factors, including size, the presence and abundance of source rocks, vegetation as an indicator of water availability, documented prospects, and data products derived from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) sensor. Notably, the deposits in the playa of Clayton Valley make it stand out as the sole lithium brine-producing playa in the United States. The ASTER sensor provides optimal regional coverage, characterized by a 60-kilometer swath width and unique multispectral capabilities that are not available with other remote sensing instruments. This report and the accompanying maps are intended to serve as resources for further multidisciplinary assessments of lithium or other elements or commodities where prospectivity can be inferred from the presence of proxies such as alteration minerals.

Arizona, Baja California, California, Chihuahua, I↗

Hyperspectral (VNIR-SWIR) analysis of roll front uranium host rocks and industrial minerals from Karnes and Live Oak Counties, Texas Coastal Plain

VNIR-SWIR (400–2500 nm) reflectance measurements were made on the surfaces of various cores, cuttings and sample splits of sedimentary rocks from the Tertiary Jackson Group, and Catahoula, Oakville and Goliad Formations. These rocks vary in composition and texture from mudstone and claystone to sandstone and are known host rocks for roll front uranium occurrences in Karnes and Live Oak Counties, Texas. Spectral reflectance profiles, 569 in total, were reduced to 125 representative spectral signatures, which were analyzed using the U.S. Geological Survey's (USGS) Material Identification and Characterization Algorithm (MICA). MICA uses an automated continuum-removal procedure together with a least-squares linear regression to determine the fit of observed sample spectral absorption features to those of reference mineral standards in a spectral library. The reference minerals include various clay, mica, carbonate, ferric and ferrous iron minerals and their mixtures. In addition, absorption feature band-depth analysis was done to identify rock surfaces exhibiting absorption features related to uranium and zeolite minerals, which were not included in the command files used to execute MICA. Rocks from each of the four geologic units produced broadly similar spectral signatures as a result of comparable mineral compositions, but there were some notable differences. For example, Ca- and Na-montmorillonite was matched most frequently to the spectral absorption features in 2-μm (∼2000–2500 nm) wavelengths, while goethite occurred often at 1-μm (∼400–1000 nm) wavelengths. The latter is related to limonitic iron-staining in and around oxidized zones of the uranium roll front as described in previous papers. Rocks of the Jackson Group differed from those of the Catahoula, Oakville and Goliad units in that the former exhibited spectral features we interpret as being due to the presence of lignite-bearing mudstone layers. Goliad rocks exhibit spectral features related to dolomite, gypsum, anhydrite, and an unidentified green clay mineral that is possibly glauconite . Jackson Group rocks also exhibit weak but well-resolved absorption features at 964 and 1157 nm related to either or both zeolite minerals clinoptilolite and heulandite. These zeolite minerals and a few spectra exhibiting hydrous silica absorption features are indicative of alteration of volcanic glass in tuffaceous mudstone and claystone layers. A few sample spectra exhibited strong absorption features at around 1135 nm related to the uranium mineral coffinite. Both the 1135 nm coffinite and 1157 nm zeolite absorption features overlap somewhat, potentially making them difficult to distinguish without additional hyperspectral field, laboratory or remote sensing data. The results of this study were compared to mixtures of minerals described for ore, gangue and alteration minerals in deposit models for sandstone-hosted uranium, sedimentary bentonite and sedimentary zeolite. Use of these spectra can help facilitate mapping of both waste materials from the legacy mining of the above commodities, as well as future exploration and resource assessment activities.

Texas↗

Mapping abandoned uranium mine features using Worldview-3 imagery in portions of Karnes, Atascosa and Live Oak Counties, Texas

Worldview-3 (WV3) 16-band multispectral data were used to map exposed bedrock and mine waste piles associated with legacy open-pit mining of sandstone-hosted roll-front uranium deposits along the South Texas Coastal Plain. We used the “spectral hourglass” approach to extract spectral endmembers representative of these features from the image. This approach first requires calibrating the imagery to reflectance, then masking for vegetation, followed by spatial and spectral data reduction using a principal component analysis-based procedure that reduces noise and identifies homogeneous targets which are “pure” enough to be considered spectral endmembers. In this case, we used a single WV3 image which covered an ~11.5 km by ~19.5 km area of Karnes, Atascosa and Live Oak Counties, underlain by mined rocks from the Jackson Group and Catahoula Formation. Up to 58 spectral endmembers were identified using a further multi-dimensional class segregation method and were used as inputs for spectral angle mapper (SAM) classification. SAM classification resulted in the identification of at least 117 mine- and mine waste-related features, most of which were previously unknown. Class similarity was further evaluated, and the dominant minerals in each class were identified by comparison to spectral libraries and measured samples of actual Jackson Group uranium host rocks. Redundant classes were eliminated, and SAM was run a second time using a reduced set of 23 endmembers, which were found to map these same features as effectively as using the full 58 set of endmembers, but with significantly reduced noise and spectral outliers. Our classification results were validated by evaluating detailed scale mapping of three known mine sites (Esse-Spoonamore, Wright-McCrady and Garbysch-Thane) with published ground truth information about the vegetation cover, extent of erosion and exposure of waste pile materials and/or geologic information about host lithology and mineralization. Despite successful demonstration of the utility of WV3 data for inventorying mine features, additional landscape features such as bare agricultural fields and oil and gas drill pads were also identified. The elimination of such features will require combining the spectral classification maps presented in this study with high-quality topographic data. Also, the spectral endmembers identified during the course of this study could be useful for larger-scale mapping efforts using additional well-calibrated WV3 images beyond the coverage of our initial study area.

Texas↗

Environmental geochemistry at Red Mountain, an unmined volcanogenic massive sulphide deposit in the Bonnifield district, Alaska Range, east-central Alaska

The unmined, pyrite-rich Red Mountain (Dry Creek) deposit displays a remarkable environmental footprint of natural acid generation, high metal and exceedingly high rare earth element (REE) concentrations in surface waters. The volcanogenic massive sulphide deposit exhibits well-constrained examples of acid-generating, metal-leaching, metal-precipitation and self-mitigation (via co-precipitation, dilution and neutralization) processes that occur in an undisturbed natural setting, a rare occurrence in North America. Oxidative dissolution of pyrite and associated secondary reactions under near-surface oxidizing conditions are the primary causes for the acid generation and metal leaching. The deposit is hosted in Devonian to Mississippian felsic metavolcanic rocks of the Mystic Creek Member of the Totatlanika Schist. Water samples with the lowest pH (many below 3.5), highest specific conductance (commonly >2500 μS/cm) and highest major- and trace-element concentrations are from springs and streams within the quartz–sericite–pyrite alteration zone. Aluminum, Cd, Co, Cu, Fe, Mn, Ni, Pb, Y, Zn and, particularly, the REEs are found in high concentrations, ranging across four orders of magnitude. Waters collected upstream from the alteration zone have near-neutral pH, lower specific conductance (370 to 830 μS/cm), lower metal concentrations and measurable alkalinities. Water samples collected downstream of the alteration zone have pH and metal concentrations intermediate between these two extremes. Stream sediments are anomalous in Zn, Pb, S, Fe, Cu, As, Co, Sb and Cd relative to local and regional background abundances. Red Mountain Creek and its tributaries do not, and probably never have, supported significant aquatic life.

Alaska↗

Imaging spectroscopy applied to mineral mapping over large areas: Impact of residual atmospheric artefacts in reflectance spectra on mineral identification and mapping

Around the world, imaging spectroscopy (hyperspectral imaging) has been successfully applied to mapping surface minerals over small areas. In this paper, we examine one challenge to reliably mapping surface mineral composition over large areas: the impacts of atmospheric artefacts in reflectance spectra on mineral identification. To examine these impacts, we use a set of Airborne Visible and Infrared Imaging Spectrometer-Classic (AVIRISc) data collected over ~30,000 sq. km of southern California (SoCal) in 2018. The AVIRISc2018 SoCal reflectance data showed residual atmospheric contamination in wavelength regions at the edges of strong water vapor absorption features: 1.44-1.5 µm, 1.75-1.8 µm, and 2.35-2.5 µm. These three regions of atmospheric residuals affect identification and discrimination of mineral absorption features, especially when mineral abundances are low and spectral features are weak. Of these three regions, improving atmospheric correction of imaging spectrometer data in the 2.35-2.5 µm region will result in the most enhancement in mineral identification, discrimination, and mapping. An additional region near 2.2 µm affects phyllosilicate mineral identification. The cause of the distorted reflectance in this region is still being investigated.

Conference Paper↗

Linear deconvolution applied to ASTER imagery of terrestrial dune analog sites

Advanced Spaceborne Thermal Emission and Reflec-tion (ASTER) radiometer onboard NASA’s Terra satellite has nearly complete global coverage in the 8 – 14 µm thermal infrared (TIR) atmospheric window and is the highest resolution sensor providing TIR emissivity data at 90-m spatial resolution and five multispectral bands. ASTER imagery enables mapping of spatial variations in the distribution of mineral abundances across terrestrial dune fields. We compared simulated ASTER emissivity spectra derived from higher resolution laboratory measurements, with those simulated for various higher and lower resolution multispectral and hyperspectral sensors. Linear deconvolution was then applied to simulated ASTER as well as seven other convoluted laboratory spectral measurements of eight samples that we collected from seven different dune fields throughout the Western United States and Alaska: (1) Algodones, CA; (2) Big Dune, NV; (3) Bruneau, ID; (4) Great Kobuk Sand Dunes (GKSD), AK; (5) Great Sand Dunes National Park and Preserve (GSDNPP), CO; (6) Sunset Crater, AZ; and (7) White Sands National Monument, NM. We evaluate the utility of each of these seven dune fields as potential Martian aeolian analog sites by comparing their compositional similarities and differ-ences between morphologically similar dune land-forms found on Mars.

Conference Paper↗

Geochemistry and mineralogy of soils collected in the lower Rio Grande valley, Texas

Presented in this report are the chemical and mineralogical results of a soil study conducted in the lower Rio Grande valley, Texas. Samples were collected from soils formed on Holocene alluvial flood-plain and distributary channel deposits of the Rio Grande, flood plain and meander-belt deposits of the Pliocene Goliad Formation, and the Pleistocene Lissie and Beaumont Formations. The lower Rio Grande valley is located on the old distributary delta of the Rio Grande. The watersheds on the U.S. side of the delta no longer drain into the Rio Grande but are part of a complex system of irrigation channels and wastewater drains that flow into the lower Laguna Madre. The results of the study have been used to map concealed geologic units and identify potential mosquito breeding habitat.

Texas↗

Determining mineralogical variations of aeolian deposits using thermal infrared emissivity and linear deconvolution methods

We apply linear deconvolution methods to derive mineral and glass proportions for eight field sample training sites at seven dune fields: (1) Algodones, California; (2) Big Dune, Nevada; (3) Bruneau, Idaho; (4) Great Kobuk Sand Dunes, Alaska; (5) Great Sand Dunes National Park and Preserve, Colorado; (6) Sunset Crater, Arizona; and (7) White Sands National Monument, New Mexico. These dune fields were chosen because they represent a wide range of mineral grain mixtures and allow us to gauge a better understanding of both compositional and sorting effects within terrestrial and extraterrestrial dune systems. We also use actual ASTER TIR emissivity imagery to map the spatial distribution of these minerals throughout the seven dune fields and evaluate the effects of degraded spectral resolution on the accuracy of mineral abundances retrieved. Our results show that hyperspectral data convolutions of our laboratory emissivity spectra outperformed multispectral data convolutions of the same data with respect to the mineral, glass and lithic abundances derived. Both the number and wavelength position of spectral bands greatly impacts the accuracy of linear deconvolution retrieval of feldspar proportions (e.g. K-feldspar vs. plagioclase) especially, as well as the detection of certain mafic and carbonate minerals. In particular, ASTER mapping results show that several of the dune sites display patterns such that less dense minerals typically have higher abundances near the center of the active and most evolved dunes in the field, while more dense minerals and glasses appear to be more abundant along the margins of the active dune fields.

Alaska, Arizona, California, Colorado, Idaho, Neva↗

Application of imaging spectroscopy for mineral exploration in Alaska: A study over porphyry Cu deposits in the eastern Alaska Range

The U.S. Geological Survey tested the utility of imaging spectroscopy (also referred to as hyperspectral remote sensing) as an aid to regional mineral exploration efforts in remote parts of Alaska. Airborne imaging spectrometer data were collected in 2014 over unmined porphyry Cu deposits in the eastern Alaska Range using the HyMap™ sensor. Maps of the distributions of predominant minerals, made by matching reflectance signatures in the remotely sensed data to reference spectra in the shortwave infrared region, do not uniquely discriminate individual rock units. However, they do highlight hydrothermal alteration associated with porphyry deposits and prospects hosted mostly within the Nabesna pluton. In and around porphyry Cu deposits at Orange Hill and Bond Creek, unique spectral signatures are related to variations in chlorite and white mica abundance and their chemical composition. This is best revealed in the longer-wavelength 2,200-nm Al-OH absorption feature positions in pixels spectrally dominated by white mica proximal to porphyry deposits. Similar spectral signatures of chlorite and white mica wavelength positions were also recognized away from the porphyry deposits; follow-up sampling identified these satellite areas to also contain Cu-Mo-Au mineralized rock. Our study confirms that airborne imaging spectroscopy has application for regional mineral exploration in exposed mountainous terrain in Alaska.

Alaska↗

Multiscale hyperspectral imaging of the Orange Hill Porphyry Copper Deposit, Alaska, USA, with laboratory-, field-, and aircraft-based imaging spectrometers

In the past decade, use of hyperspectral imaging (imaging spectroscopy) for mineral exploration and mining operations has been increasing at different spatial scales. In this paper, we focus on recent trends in applying imaging spectrometer data to: 1) airborne imaging of high latitude deposits, 2) field-based imaging of outcrops, and 3) laboratory-level imaging of geologic samples. Comparing mineral information derived from imaging spectrometer data acquired at these three scales in Alaska in areas of exposed porphyry Cu-Au-Mo deposits, Orange Hill and Bond Creek, we find notable consistency in identifications of spectrally predominant minerals, including white mica, chlorite, clays, and gypsum. Variations in the wavelength position of white mica 2200 nm Al-OH absorption seen at the airborne level are echoed by finerscale field and laboratory imaging, with wavelength positions spanning the 2199 to 2207 nm range. The longerwavelength micas associated with porphyry formation are more phengitic in composition, and thus distinct from mica in plutonic and volcanic arc rocks not affected by magmatic-hydrothermal fluids. The hillside imagery, collected on a cloudy day that would have precluded aircraft survey, gave comparable result to airborne and laboratory data, indicating field-based imaging spectroscopy can be a feasible alternative to airborne survey for accessible targets. Direct spectral observation of molybdenite in rocks collected from the Orange Hill deposit demonstratesthat additional important mineral information can be revealed with laboratory level imaging spectroscopy that is difficult to obtain in coarser scale data, commonly due to low areal extent of target minerals. The spatial association of the clinochlore + white mica and long wavelength white mica spectral classes to multi-element Cu-Mo-Au anomalies from geochemical analyses of rocks and sediments support a causative relationship with magmatic-hydrothermal alteration. Mineral maps from the airborne data were used to guide field sampling that found additional CuMo-Au mineralized areas, which were previously unknown or unreported. The results from this study provide support for utilization of imaging spectroscopy for assisting mineral exploration in other portions of the state of Alaska as well as other areas at high latitudes. Imaging spectroscopy has the potential to provide targeting information for follow-up sampling and investigations, potentially reducing subsequent exploration costs.

Alaska↗

Hyperspectral surveying for mineral resources in Alaska

Alaska is a major producer of base and precious metals and has a high potential for additional undiscovered mineral resources. However, discovery is hindered by Alaska’s vast size, remoteness, and rugged terrain. New methods are needed to overcome these obstacles in order to fully evaluate Alaska’s geology and mineral resource potential. Hyperspectral surveying is one method that can be used to rapidly acquire data about the distributions of surficial materials, including different types of bedrock and ground cover. In 2014, the U.S. Geological Survey began the Alaska Hyperspectral Project to assess the applicability of this method in Alaska. The primary study area is a remote part of the eastern Alaska Range where porphyry deposits are exposed. In collaboration with the Alaska Division of Geological and Geophysical Surveys, the University of Alaska Fairbanks, and the National Park Service, the U.S. Geological Survey is collecting and analyzing hyperspectral data with the goals of enhancing geologic mapping and developing methods to identify and characterize mineral deposits elsewhere in Alaska.

Alaska↗

Geospatial compilation of results from field sample collection in support of mineral resource investigations, Western Alaska Range, Alaska, July 2013

This Data Series summarizes results from July 2013 sampling in the western Alaska Range near Mount Estelle, Alaska. The fieldwork combined in situ and camp-based spectral measurements of talus/soil and rock samples. Five rock and 48 soil samples were submitted for quantitative geochemi­cal analysis (for 55 major and trace elements), and the 48 soils samples were also analyzed by x-ray diffraction to establish mineralogy and geochemistry. The results and sample photo­graphs are presented in a geodatabase that accompanies this report. The spectral, mineralogical, and geochemical charac­terization of these samples and the sites that they represent can be used to validate existing remote-sensing datasets (for example, ASTER) and future hyperspectral studies. Empiri­cal evidence of jarosite (as identified by x-ray diffraction and spectral analysis) corresponding with gold concentrations in excess of 50 parts per billion in soil samples suggests that surficial mapping of jarosite in regional surveys may be use­ful for targeting areas of prospective gold occurrences in this sampling area.

Alaska↗

Assessment of bauxite, clay, and laterite deposits in Afghanistan

Bauxite-bearing rocks are present in several regions of Afghanistan; specifically, the southeast segment of the North Afghanistan Platform, the eastern parts of South Afghanistan, and within the Afghanistan-North and -South Pamir Fold Regions. Bauxite-bearing rocks occur at various stratigraphic levels, in lithologically different sequences of sedimentary rocks. The bauxites are paleosols and represent previous, rather than recent, weathering events. Bauxites and bauxite-type horizons are most common at the base of carbonate rock units, where they form the basal horizons of sedimentary rock sequences separated by erosion and stratigraphic unconformity surfaces. Less common are zones in redeposited weathering developed on igneous rocks. At present there are five known stratigraphic intervals with significant bauxite and bauxite-type deposits and occurrences: the lower Permian, the upper Permian, the Upper Triassic, the Lower Jurassic, and the base of the Upper Jurassic. This report summarizes a compilation and review of geological data for regions in Afghanistan that contain bauxite deposits and occurrences based on work conducted during 2009 to 2011 by the U.S. Geological Survey, the U.S. Department of Defense Task Force for Business and Stability Operations, and the Afghanistan Geological Survey. Permian strata contain bauxites and bauxite-like rocks that are recognizable at various stratigraphic intervals within several areas of southern Afghanistan and in the Central Afghan Massif in central Afghanistan. The main zones of known bauxite occurrences are the Haftqala bauxite zone (late Permian and Late Triassic), Shewa bauxite zone (early Permian), Qarghanaw bauxite zone (late Permian and Late Triassic), Arghandab block in Zabul Province (middle through late Permian), Arghandab block in Ghazni Province (early Permian), Surkhob bauxite zone (Early Jurassic), and Tirin block in Uruzgan, Zabul, and Kandahar Provinces (Late Jurassic). Although some bauxite occurrences were sampled in the course of reconnaissance exploration by Soviet workers in the 1960s and 1970s, the bauxite areas in Afghanistan generally are underexplored. The Obatu Sheila area is a known field of bauxite deposits of Late Jurassic age that had been studied in more detail than other known bauxite deposits and occurrences in Afghanistan. Obatu Sheila has an estimated reserve of 7.2 million tons.

Open-File Report↗

Alteration, slope-classified alteration, and potential lahar inundation maps of volcanoes for the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) Volcano Archive

This study identifies areas prone to lahars from hydrothermally altered volcanic edifices on a global scale, using visible and near infrared (VNIR) and short wavelength infrared (SWIR) reflectance data from the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and digital elevation data from the ASTER Global Digital Elevation Model (GDEM) dataset. This is the first study to create a global database of hydrothermally altered volcanoes showing quantitatively compiled alteration maps and potentially affected drainages, as well as drainage-specific maps illustrating modeled lahars and their potential inundation zones. We (1) identified and prioritized 720 volcanoes based on population density surrounding the volcanoes using the Smithsonian Institution Global Volcanism Program database (GVP) and LandScan™ digital population dataset; (2) validated ASTER hydrothermal alteration mapping techniques using Airborne Visible and Infrared Imaging Spectrometer (AVIRIS) and ASTER data for Mount Shasta, California, and Pico de Orizaba (Citlaltépetl), Mexico; (3) mapped and slope-classified hydrothermal alteration using ASTER VNIR-SWIR reflectance data on 100 of the most densely populated volcanoes; (4) delineated drainages using ASTER GDEM data that show potential flow paths of possible lahars for the 100 mapped volcanoes; (5) produced potential alteration-related lahar inundation maps using the LAHARZ GIS code for Iztaccíhuatl, Mexico, and Mount Hood and Mount Shasta in the United States that illustrate areas likely to be affected based on DEM-derived volume estimates of hydrothermally altered rocks and the ~2x uncertainty factor inherent within a statistically-based lahar model; and (6) saved all image and vector data for 3D and 2D display in Google Earth ™ , ArcGIS ® and other graphics display programs. In addition, these data are available from the ASTER Volcano Archive (AVA) for distribution (available at http://ava.jpl.nasa.gov/recent_alteration_zones.php ). Using the GVP and the LandScan™ digital population dataset, 350 of the most densely populated stratovolcanoes were assessed for study. Of the 350 volcanoes, 250 volcanoes were not mapped due to excessive snow, ice, and (or) vegetation. Results from mapping the remaining 100 stratovolcanoes show that 87 contain slopes with hydrothermal alteration, and 49 have hydrothermally altered rocks on steep slopes situated above areas with populations >100 people per km 2 . Of these, 17 stratovolcanoes exhibit laterally extensive hydrothermal alteration on slopes >35° and cover an area >0.25 km 2 , which may pose a significant possibility of generating debris flows. This study was undertaken during 2012–2013 in cooperation with the National Aeronautics and Space Administration (NASA). Since completion of this study, a new lahar modeling program (LAHAR_pz) has been released, which may produce slightly different modeling results from the LAHARZ model used in this study. The maps and data from this study should not be used in place of existing volcano hazard maps published by local authorities. For volcanoes without hazard maps and (or) published lahar-related hazard studies, this work will provide a starting point from which more accurate hazard maps can be produced. This is the first dataset to provide digital maps of altered volcanoes and adjacent watersheds that can be used for assessing volcanic hazards, hydrothermal alteration, and other volcanic processes in future studies.

Scientific Investigations Report↗

Geochemical and mineralogical characteristics of REE in granite-derived regolith: a model for the Southeast United States

Rare earth element (REE) ion-adsorption clay deposits are of global economic importance because they currently supply a significant portion of the world’s annual production of both light (LREE) and heavy REE (HREE). There is considerable ambiguity regarding the origin of this deposit type: The main criteria include the presence of large, generally granitic, igneous suites; long periods of intense weathering with little subsequent erosion; and evidence for mobility of REE within the regolith. Granitic rocks of the southeastern United States have been subjected to a long history of chemical weathering, comparable to that of South China, an area which contains many REE clay deposits. Detailed comparisons of weathered bedrock-soil profiles for large masses of granitic rocks as exemplified by the Stewartsville, Striped Rock, and Liberty Hill plutons, USA, indicate that REE are mobile within many regolith profiles and locally can attain grades comparable to mined deposits of South China. Primary accessory mineralogy, modal content, and element redistribution as a result of weathering are identified as distinguishing factors in mobility-related enrichment of REE in the regolith profiles. Only limited geochemical separation of REE was observed within profiles, which suggests the importance of source rock composition and mineralogy in the initial distribution of extractable REE in the regolith. Retention of extractable HREE was favored over LREE, Th and U within most of the studied profiles.

Conference Paper↗

A comprehensive population dataset for Afghanistan constructed using GIS-based dasymetric mapping methods

This report summarizes the application of dasymetric methods for mapping the distribution of population throughout Afghanistan. Because Afghanistan's population has constantly changed through decades of war and conflict, existing vector and raster GIS datasets (such as point settlement densities and intensities of lights at night) do not adequately reflect the changes. The purposes of this report are (1) to provide historic population data at the provincial and district levels that can be used to chart population growth and migration trends within the country and (2) to provide baseline information that can be used for other types of spatial analyses of Afghanistan, such as resource and hazard assessments; infrastructure and capacity rebuilding; and assisting with international, regional, and local planning.

Scientific Investigations Report↗

An assessment of hydrothermal alteration in the Santiaguito lava dome complex, Guatemala: implications for dome collapse hazards

A combination of field mapping, geochemistry, and remote sensing methods has been employed to determine the extent of hydrothermal alteration and assess the potential for failure at the Santiaguito lava dome complex, Guatemala. The 90-year-old complex of four lava domes has only experienced relatively small and infrequent dome collapses in the past, which were associated with lava extrusion. However, existing evidence of an active hydrothermal system coupled with intense seasonal precipitation also presents ideal conditions for instability related to weakened clay-rich edifice rocks. Mapping of the Santiaguito dome complex identified structural features related to dome growth dynamics, potential areas of weakness related to erosion, and locations of fumarole fields. X-ray diffraction and backscattered electron images taken with scanning electron microscopy of dacite and ash samples collected from around fumaroles revealed only minor clay films, and little evidence of alteration. Mineral mapping using ASTER and Hyperion satellite images, however, suggest low-temperature (<150 °C) silicic alteration on erosional surfaces of the domes, but not the type of pervasive acid-sulfate alteration implicated in collapses of other altered edifices. To evaluate the possibility of internal alteration, we re-examined existing aqueous geochemical data from dome-fed hot springs. The data indicate significant water–rock interaction, but the Na–Mg–K geoindicator suggests only a short water residence time, and δ18O/δD ratios show only minor shifts from the meteoric water line with little precipitation of secondary (alteration) minerals. Based on available data, hydrothermal alteration on the dome complex appears to be restricted to surficial deposits of hydrous silica, but the study has highlighted, importantly, that the 1902 eruption crater headwall of Santa María does show more advanced argillic alteration. We also cannot rule out the possibility of advanced alteration within the dome complex interior that is not accessible to the methods used here. It may therefore be prudent to employ geophysical methods to make further assessments in the future.

Bulletin of Volcanology↗

The origins of Late Quaternary debris avalanche and debris flow deposits from Cofre de Perote volcano, México

Cofre de Perote volcano is a compound, shield-like volcano located in the northeastern Trans-Mexican volcanic belt. Large debris avalanche and lahar deposits are associated with the evolution of Cofre. The two best preserved of these debris-avalanche and debris-flow deposits are the ∼42 ka “Los Pescados debris flow” deposit and the ∼11–13 ka “Xico avalanche” deposit, both of which display contrasting morphological and textural characteristics, source materials, origins and emplacement environments. Laboratory X-ray diffraction and visible-infrared reflectance spectroscopy were used to identify the most abundant clay, sulfate, ferric-iron, and silica minerals in the deposits, which were either related to hydrothermal alteration or chemical weathering processes. Cloud-free Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) remote sensing imagery, supporting EO-1 Hyperion image spectra, and field ground truth samples were used to map the mineralogy and distribution of hydrothermally altered rocks on the modern summit of Cofre de Perote. The results were then compared to minerals identified in the two debris-avalanche and debris-flow deposits in order to assess possible source materials and origins for the two deposits. The older Los Pescados debris-flow deposit contains mostly halloysite and hydrous silica minerals, which match the dominant mineralogy of soils and weathered volcanic deposit in the surrounding flanks of Cofre de Perote. Its source materials were most likely derived from initially noncohesive or clay-poor flows, which subsequently bulked with clay-rich valley soils and alluvium in a manner similar to lahars from Nevado del Ruiz in 1985, but on a larger scale. The younger Xico avalanche deposit contains abundant smectite, jarosite, kaolinite, gypsum, and mixed-layered illite/smectite, which are either definitely or most likely of hydrothermal alteration origin. Smectite in particular appears to be the most abundant and spectrally dominant mineral in summit ground truth samples, ASTER mapping results, Xico avalanche deposit, and an older (pre-Xico avalanche) deposit derived from collapse(s) of ancestral Cofre de Perote edifice. However, both Xico avalanche and Los Pescados debris flow deposits show some evidence of secondary, postemplacement weathering and induration, which is evident by the presence of gibbsite, and hydroxyl interlayered minerals, in addition to recently formed halloysite and hydrous silica (i.e., indurating) cements. Field-based, visible infrared image spectroscopy (VIS/IR) spectral measurements offer the possibility of distinguishing primary minerals of hydrothermal alteration origin in debris-avalanche and debris-flow deposits from those produced either by in situ chemical weathering or bulked from weathered source materials.

Cofre de Perote volcano↗