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Barbara Mahler

Publications and source records attributed to Barbara Mahler.

At least 37 records · Page 2Linked to original sources
USGS2018

Complex mixtures of dissolved pesticides show potential aquatic toxicity in a synoptic study of Midwestern U.S. streams

Aquatic organisms in streams are exposed to pesticide mixtures that vary in composition over time in response to changes in flow conditions, pesticide inputs to the stream, and pesticide fate and degradation within the stream. To characterize mixtures of dissolved-phase pesticides and degradates in Midwestern streams, a synoptic study was conducted at 100 streams during May–August 2013. In weekly water samples, 94 pesticides and 89 degradates were detected, with a median of 25 compounds detected per sample and 54 detected per site. In a screening-level assessment using aquatic-life benchmarks and the Pesticide Toxicity Index (PTI), potential effects on fish were unlikely in most streams. For invertebrates, potential chronic toxicity was predicted in 53% of streams, punctuated in 12% of streams by acutely toxic exposures. For aquatic plants, acute but likely reversible effects on biomass were predicted in 75% of streams, with potential longer-term effects on plant communities in 9% of streams. Relatively few pesticides in water—atrazine, acetochlor, metolachlor, imidacloprid, fipronil, organophosphate insecticides, and carbendazim—were predicted to be major contributors to potential toxicity. Agricultural streams had the highest potential for effects on plants, especially in May–June, corresponding to high spring-flush herbicide concentrations. Urban streams had higher detection frequencies and concentrations of insecticides and most fungicides than in agricultural streams, and higher potential for invertebrate toxicity, which peaked during July–August. Toxicity-screening predictions for invertebrates were supported by quantile regressions showing significant associations for the Benthic Invertebrate-PTI and imidacloprid concentrations with invertebrate community metrics for MSQA streams, and by mesocosm toxicity testing with imidacloprid showing effects on invertebrate communities at environmentally relevant concentrations. This study documents the most complex pesticide mixtures yet reported in discrete water samples in the U.S. and, using multiple lines of evidence, predicts that pesticides were potentially toxic to nontarget aquatic life in about half of the sampled streams.

Illinois, Iowa, Kansas, Kentucky, Michigan, Minnes↗
USGS2017

Complex mixtures of Pesticides in Midwest U.S. streams indicated by POCIS time-integrating samplers

The Midwest United States is an intensely agricultural region where pesticides in streams pose risks to aquatic biota, but temporal variability in pesticide concentrations makes characterization of their exposure to organisms challenging. To compensate for the effects of temporal variability, we deployed polar organic chemical integrative samplers (POCIS) in 100 small streams across the Midwest for about 5 weeks during summer 2013 and analyzed the extracts for 227 pesticide compounds. Analysis of water samples collected weekly for pesticides during POCIS deployment allowed for comparison of POCIS results with periodic water-sampling results. The median number of pesticides detected in POCIS extracts was 62, and 141 compounds were detected at least once, indicating a high level of pesticide contamination of streams in the region. Sixty-five of the 141 compounds detected were pesticide degradates. Mean water concentrations estimated using published POCIS sampling rates strongly correlated with means of weekly water samples collected concurrently, however, the POCIS-estimated concentrations generally were lower than the measured water concentrations. Summed herbicide concentrations (units of ng/POCIS) were greater at agricultural sites than at urban sites but summed concentrations of insecticides and fungicides were greater at urban sites. Consistent with these differences, summed concentrations of herbicides correlate to percent cultivated crops in the watersheds and summed concentrations of insecticides and fungicides correlate to percent urban land use. With the exception of malathion concentrations at nine sites, POCIS-estimated water concentrations of pesticides were lower than aquatic-life benchmarks. The POCIS provide an alternative approach to traditional water sampling for characterizing chronic exposure to pesticides in streams across the Midwest region.

Environmental Pollution↗
USGS2017

Similarities and differences in occurrence and temporal fluctuations in glyphosate and atrazine in small Midwestern streams (USA) during the 2013 growing season

Glyphosate and atrazine are the most intensively used herbicides in the United States. Although there is abundant spatial and temporal information on atrazine occurrence at regional scales, there are far fewer data for glyphosate, and studies that compare the two herbicides are rare. We investigated temporal patterns in glyphosate and atrazine concentrations measured weekly during the 2013 growing season in 100 small streams in the Midwestern United States. Glyphosate was detected in 44% of samples (method reporting level 0.2 μg/L); atrazine was detected above a threshold of 0.2 μg/L in 54% of samples. Glyphosate was detected more frequently in 12 urban streams than in 88 agricultural streams, and at concentrations similar to those in streams with high agricultural land use (> 40% row crop) in the watershed. In contrast, atrazine was detected more frequently and at higher concentrations in agricultural streams than in urban streams. The maximum concentration of glyphosate measured at most urban sites exceeded the maximum atrazine concentration, whereas at agricultural sites the reverse was true. Measurement at a 2-day interval at 8 sites in northern Missouri revealed that transport of both herbicide compounds appeared to be controlled by spring flush, that peak concentration duration was brief, but that peaks in atrazine concentrations were of longer duration than those of glyphosate. The 2-day sampling also indicated that weekly sampling is unlikely to capture peak concentrations of glyphosate and atrazine.

Science of the Total Environment↗
USGS2017

Influence of sediment chemistry and sediment toxicity on macroinvertebrate communities across 99 wadable streams of the Midwestern USA

Simultaneous assessment of sediment chemistry, sediment toxicity, and macroinvertebrate communities can provide multiple lines of evidence when investigating relations between sediment contaminants and ecological degradation. These three measures were evaluated at 99 wadable stream sites across 11 states in the Midwestern United States during the summer of 2013 to assess sediment pollution across a large agricultural landscape. This evaluation considers an extensive suite of sediment chemistry totaling 274 analytes (polycyclic aromatic hydrocarbons, organochlorine compounds, polychlorinated biphenyls, polybrominated diphenyl ethers, trace elements, and current-use pesticides) and a mixture assessment based on the ratios of detected compounds to available effects-based benchmarks. The sediments were tested for toxicity with the amphipod Hyalella azteca (28-d exposure), the midge Chironomus dilutus (10-d), and, at a few sites, with the freshwater mussel Lampsilis siliquoidea (28-d). Sediment concentrations, normalized to organic carbon content, infrequently exceeded benchmarks for aquatic health, which was generally consistent with low rates of observed toxicity. However, the benchmark-based mixture score and the pyrethroid insecticide bifenthrin were significantly related to observed sediment toxicity. The sediment mixture score and bifenthrin were also significant predictors of the upper limits of several univariate measures of the macroinvertebrate community (EPT percent, MMI (Macroinvertebrate Multimetric Index) Score, Ephemeroptera and Trichoptera richness) using quantile regression. Multivariate pattern matching (Mantel-like tests) of macroinvertebrate species per site to identified contaminant metrics and sediment toxicity also indicate that the sediment mixture score and bifenthrin have weak, albeit significant, influence on the observed invertebrate community composition. Together, these three lines of evidence (toxicity tests, univariate metrics, and multivariate community analysis) suggest that elevated contaminant concentrations in sediments, in particular bifenthrin, is limiting macroinvertebrate communities in several of these Midwest streams.

Science of the Total Environment↗
USGS2017

Coal-tar-based pavement sealants—a potent source of PAHs

P avement sealants are applied to the asphalt pavement of many parking lots, driveways, and even playgrounds in North America (Figure 1), where, when first applied, they render the pavement glossy black and looking like new. Sealant products used commercially in the central, eastern, and northern United States typically are coal-tarbased, whereas those used in the western United States typically are asphalt-based. Although the products look similar, they are chemically different. Coal-tarbased pavement sealants typically are 25-35 percent (by weight) coal tar or coal-tar pitch, materials that are known human carcinogens and that contain high concentrations of polycyclic aromatic hydrocarbons (PAHs) and related chemicals (unless otherwise noted, all Figure 1. Pavement sealant is commonly used to seal parking lots, playgrounds, and driveways throughout the United States. Sealants used in the central, northern, eastern, and southern United States typically contain coal tar or coal-tar pitch, both of which are known human carcinogens. Photos by the U.S. Geological Survey. data in this article are from Mahler et al. 2012 and references therein).

Lakeline↗
USGS2017

Trends and sources of PAHs to urban lakes and streams

Over the past few decades, concentrations of polycyclic aromatic hydrocarbons (PAHs) have been increasing in the sediments of many U.S. urban lakes and streams. These upward trends contrast those of legacy pollutants, such as lead, PCBs, and DDT, which were restricted or banned in the 1970s. Trends of these legacy pollutants have been downward since they were banned (Figures 1 and 2). Understanding the causes of trends in PAHs is complicated by their many natural and anthropogenic sources. PAHs are contained in fossil fuels and also are produced when materials that contain carbon, including oil, coal, gasoline, and diesel fuel, are heated or burned. Although many studies have considered vehicle emissions as a potential source of urban PAHs, estimated emissions of PAHs from vehicles in the United States declined almost ten-fold from 1971 (32,000 metric tons, or Mg) to 2000 (3,500 Mg), and this decline continues. Vehicle emissions therefore cannot account for the upward trend found in urban lake sediments – there must be some other primary source or sources of the upward trend in PAHs.

Lakeline↗
USGS2016

Bifenthrin causes trophic cascades and alters insect emergence in mesocosms: implication for small streams

Direct and indirect ecological effects of the widely used insecticide bifenthrin on stream ecosystems are largely unknown. To investigate such effects, a manipulative experiment was conducted in stream mesocosms that were colonized by aquatic insect communities and exposed to bifenthrin-contaminated sediment; implications for natural streams were interpreted through comparison of mesocosm results to a survey of 100 Midwestern streams, USA. In the mesocosm experiment, direct effects of bifenthrin exposure included reduced larval macroinvertebrate abundance, richness, and biomass at concentrations (EC50s ranged 197.6 – 233.5 ng bifenthrin/ g organic carbon) previously thought safe for aquatic life. Indirect effects included a trophic cascade in which periphyton abundance increased after macroinvertebrate scrapers decreased. Adult emergence dynamics and corresponding terrestrial subsidies were altered at all bifenthrin concentrations tested. Extrapolating these results to the Midwestern stream assessment suggests pervasive ecological effects, with altered emergence dynamics likely in 40% of streams and a trophic cascade in 7% of streams. This study provides new evidence that a common pyrethroid might alter aquatic and terrestrial ecosystem function at the regional scale.

Environmental Science & Technology↗
USGS2016

Metformin and other pharmaceuticals widespread in wadeable streams of the southeastern United States

Pharmaceutical contaminants are growing aquatic-health concerns and largely attributed to wastewater treatment facility (WWTF) discharges. Five biweekly water samples from 59 small Piedmont (United States) streams were analyzed for 108 pharmaceuticals and degradates using high-performance liquid chromatography and tandem mass spectrometry. The antidiabetic metformin was detected in 89% of samples and at 97% of sites. At least one pharmaceutical was detected at every site (median of 6, maximum of 45), and several were detected at ≥10% of sites at concentrations reported to affect multiple aquatic end points. Maximal cumulative (all detected compounds) concentrations per site ranged from 17 to 16000 ng L –1 . Watershed urbanization, water table depth, soil thickness, and WWTF metrics correlated significantly with in-stream pharmaceutical contamination. Comparable pharmaceutical concentrations and detections at sites with and without permitted wastewater discharges demonstrate the importance of non-WWTF sources and the need for broad-scale mitigation. The results highlight a fundamental biochemical link between global human-health crises like diabetes and aquatic ecosystem health.

Environmental Science & Technology Letters↗
USGS2016

Coal-tar-based pavement sealcoat—Potential concerns for human health and aquatic life

Introduction Sealcoat is the black, viscous liquid sprayed or painted on many asphalt parking lots, driveways, and playgrounds to protect and enhance the appearance of the underlying asphalt. Studies by the U.S. Geological Survey (USGS), academic institutions, and State and local agencies have identified coal-tar-based pavement sealcoat as a major source of polycyclic aromatic hydrocarbon (PAH) contamination in urban and suburban areas and a potential concern for human health and aquatic life. Key Findings: Human Health Concerns —As coal-tar-based sealcoat ages, it wears into small particles with high levels of PAHs that can be tracked into homes and incorporated into house dust. For people who live adjacent to coal-tar-sealcoated pavement, ingestion of PAH-contaminated house dust and soil results in an elevated potential cancer risk, particularly for young children. Exposure to PAHs, especially early in childhood, has been linked by health professionals to an increased risk of lung, skin, bladder, and respiratory cancers. Aquatic Life Concerns —Runoff from coal-tar-sealcoated pavement, even runoff collected more than 3 months after sealcoat application, is acutely toxic to fathead minnows and water fleas, two species commonly used to assess toxicity to aquatic life. Exposure to even highly diluted runoff from coal-tar-sealcoated pavement can cause DNA damage and impair DNA repair. These findings demonstrate that coal-tar-sealcoat runoff can remain a risk to aquatic life for months after application.

Fact Sheet↗
USGS2016

Source, variability, and transformation of nitrate in a regional karst aquifer: Edwards aquifer, central Texas.

Many karst regions are undergoing rapid population growth and expansion of urban land accompanied by increases in wastewater generation and changing patterns of nitrate (NO 3 − ) loading to surface and groundwater. We investigate variability and sources of NO 3 − in a regional karst aquifer system, the Edwards aquifer of central Texas. Samples from streams recharging the aquifer, groundwater wells, and springs were collected during 2008–12 from the Barton Springs and San Antonio segments of the Edwards aquifer and analyzed for nitrogen (N) species concentrations and NO 3 − stable isotopes (δ 15 N and δ 18 O). These data were augmented by historical data collected from 1937 to 2007. NO 3 − concentrations and discharge data indicate that short-term variability (days to months) in groundwater NO 3 − concentrations in the Barton Springs segment is controlled by occurrence of individual storms and multi-annual wet-dry cycles, whereas the lack of short-term variability in groundwater in the San Antonio segment indicates the dominance of transport along regional flow paths. In both segments, longer-term increases (years to decades) in NO 3 − concentrations cannot be attributed to hydrologic conditions; rather, isotopic ratios and land-use change indicate that septic systems and land application of treated wastewater might be the source of increased loading of NO 3 − . These results highlight the vulnerability of karst aquifers to NO 3 − contamination from urban wastewater. An analysis of N-species loading in recharge and discharge for the Barton Springs segment during 2008–10 indicates an overall mass balance in total N, but recharge contains higher concentrations of organic N and lower concentrations of NO 3 − than does discharge, consistent with nitrification of organic N within the aquifer and consumption of dissolved oxygen. This study demonstrates that subaqueous nitrification of organic N in the aquifer, as opposed to in soils, might be a previously unrecognized source of NO 3 − to karst groundwater or other oxic groundwater systems.

Texas↗
USGS2016

High nitrate concentrations in some Midwest United States streams in 2013 after the 2012 drought

Nitrogen sources in the Mississippi River basin have been linked to degradation of stream ecology and to Gulf of Mexico hypoxia. In 2013, the USGS and the USEPA characterized water quality stressors and ecological conditions in 100 wadeable streams across the midwestern United States. Wet conditions in 2013 followed a severe drought in 2012, a weather pattern associated with elevated nitrogen concentrations and loads in streams. Nitrate concentrations during the May to August 2013 sampling period ranged from <0.04 to 41.8 mg L −1 as N (mean, 5.31 mg L −1 ). Observed mean May to June nitrate concentrations at the 100 sites were compared with May to June concentrations predicted from a regression model developed using historical nitrate data. Observed concentrations for 17 sites, centered on Iowa and southern Minnesota, were outside the 95% confidence interval of the regression-predicted mean, indicating that they were anomalously high. The sites with a nitrate anomaly had significantly higher May to June nitrate concentrations than sites without an anomaly (means, 19.8 and 3.6 mg L −1 , respectively) and had higher antecedent precipitation indices, a measure of the departure from normal precipitation, in 2012 and 2013. Correlations between nitrate concentrations and watershed characteristics and nitrogen and oxygen isotopes of nitrate indicated that fertilizer and manure used in crop production, principally corn, were the dominant sources of nitrate. The anomalously high nitrate levels in parts of the Midwest in 2013 coincide with reported higher-than-normal nitrate loads in the Mississippi River.

Journal of Environmental Quality↗
USGS2015

Effects of projected climate (2011–50) on karst hydrology and species vulnerability—Edwards aquifer, south-central Texas, and Madison aquifer, western South Dakota

Karst aquifers&mdash;formed by the dissolution of soluble rocks such as limestone&mdash;are critical groundwater resources in North America, and karst springs, caves, and streams provide habitat for unique flora and fauna. Springflow and groundwater levels in karst terrane can change greatly over short time scales, and therefore are likely to respond rapidly to climate change. How might the biological communities and ecosystems associated with karst respond to climate change and accompanying changes in groundwater levels and springflow? Sites in two central U.S. regions&mdash;the Balcones Escarpment of south-central Texas and the Black Hills of western South Dakota (fig. 1)&mdash;were selected to study climate change and its potential effects on the local karst hydrology and ecosystem. The ecosystems associated with the Edwards aquifer (Balcones Escarpment region) and Madison aquifer (Black Hills region) support federally listed endangered and threatened species and numerous State-listed species of concern, including amphibians, birds, insects, and plants. Full results are provided in Stamm and others (2014), and are summarized in this fact sheet.

South Dakota, Texas↗
USGS2015

Historical and projected climate (1901–2050) and hydrologic response of karst aquifers, and species vulnerability in south-central Texas and western South Dakota

Two karst aquifers, the Edwards aquifer in the Balcones Escarpment region of south-central Texas and the Madison aquifer in the Black Hills of western South Dakota, were evaluated for hydrologic response to projected climate change through 2050. Edwards aquifer sites include Barton Springs, the Bexar County Index Well, and Comal Springs. Madison aquifer sites include Spearfish Creek and Rhoads Fork Spring. Climate projections at sites were based on output from the Community Climate System Model of global climate, linked to the Weather Research and Forecasting (WRF) model of regional climate. The WRF model output was bias adjusted to match means for 1981&ndash;2010 from records at weather stations near Madison and Edwards aquifer sites, including Boerne, Texas, and Custer and Lead, South Dakota. Hydrologic response at spring and well sites was based on the Rainfall-Response Aquifer and Watershed Flow (RRAWFLOW) model. The WRF model climate projections for 2011&ndash;50 indicate a significant upward trend in annual air temperature for all three weather stations and a significant downward trend in annual precipitation for the Boerne weather station. Annual springflow simulated by the RRAWFLOW model had a significant downward trend for Edwards aquifer sites and no trend for Madison aquifer sites. Flora and fauna that rely on springflow from Edwards and Madison aquifer sites were assessed for vulnerability to projected climate change on the basis of the Climate Change Vulnerability Index (CCVI). The CCVI is determined by the exposure of a species to climate, the sensitivity of the species, and the ability of the species to cope with climate change. Sixteen species associated with springs and groundwater were assessed in the Balcones Escarpment region. The Barton Springs salamander ( Eurycea sosorum ) was scored as highly vulnerable with moderate confidence. Nine species&mdash;three salamanders, a fountain darter ( Etheostoma fonticola ), three insects, and two amphipods&mdash;were scored as moderately vulnerable. The remaining six species&mdash;four vascular plants, the Barton cavesnail ( Stygopyrgus bartonensis ), and a cave shrimp&mdash;were scored as not vulnerable/presumed stable (not vulnerable and evidence does not support change in abundance or range of the species). Vulnerability of eight species associated with streams that receive springflow from the Madison aquifer in the Black Hills was assessed. Of these, the American dipper ( Cinclus mexicanus ) and the lesser yellow lady&rsquo;s slipper ( Cypripedium parviflorum ) were scored as moderately vulernable with high confidence. The dwarf scouringrush ( Equisetum scirpoides ) and autumn willow ( Salix serissima ) were also scored as moderately vulnerable with moderate to low confidence, respectively. Other species were assessed as not vulnerable/presumed stable or not vulnerable/increase likely (not vulnerable and evidence supporting an increase in abundance or range of the species). Lower vulnerability scores for the Black Hills species in comparison to the Balcones Escarpment species reflect lower endemicity, higher projected springflow than in the historical period, and high thermal tolerance of many of the species for the Black Hills. Importantly, climate change vulnerability scores differed substantially for Edwards aquifer species when RRAWFLOW model projections were included, resulting in increased vulnerability scores for 12 of the 16 species.

South Dakota, Texas↗
USGS2015

Declining Dioxin concentrations in the Rhone River, France, attest to the effectiveness of emissions controls

Emission-control policies have been implemented in Europe and North America since the 1990s for polychlorodibenzodioxins (PCDDs) and furans (PCDFs). To assess the effect of these policies on temporal trends and spatial patterns for these compounds in a large European river system, sediment cores were collected in seven depositional areas along the Rhone River in France, dated, and analyzed for PCDDs and PCDFs. Results show concentrations increase in the downstream direction and have decreased temporally at all sites during the last two decades, with an average decrease of 83% from 1992 to 2010. The time for a 50% decrease in concentrations (t1/2) averaged 6.9 &plusmn; 2.6 and 9.1 &plusmn; 2.9 years for the sum of measured PCDDs and PCDFs, respectively. Congener patterns are similar among cores and indicate dominance of regional atmospheric deposition and possibly weathered local sources. Local sources are clearly indicated at the most downstream site, where concentrations of the most toxic dioxin, TCDD, are about 2 orders of magnitude higher than at the other six sites. The relatively steep downward trends attest to the effects of the dioxin emissions reduction policy in Europe and suggest that risks posed to aquatic life in the Rhone River basin from dioxins and furans have been greatly reduced.

Environmental Science & Technology↗
USGS2015

Acute toxicity of runoff from sealcoated pavement to Ceriodaphnia dubia and Pimephales promelas

Runoff from coal-tar-based (CT) sealcoated pavement is a source of polycyclic aromatic hydrocarbons (PAHs) and N -heterocycles to surface waters. We investigated acute toxicity of simulated runoff collected from 5 h to 111 days after application of CT sealcoat and from 4 h to 36 days after application of asphalt-based sealcoat containing about 7% CT sealcoat (AS/CT-blend). Ceriodaphnia dubia (cladocerans) and Pimephales promelas (fathead minnows) were exposed in the laboratory to undiluted and 1:10 diluted runoff for 48 h, then transferred to control water and exposed to 4 h of ultraviolet radiation (UVR). Mortality following exposure to undiluted runoff from unsealed asphalt pavement and UVR was &le;10% in all treatments. Test organisms exposed to undiluted CT runoff samples collected during the 3 days ( C. dubia ) or 36 days ( P. promelas ) following sealcoat application experienced 100% mortality prior to UVR exposure; with UVR exposure, mortality was 100% for runoff collected across the entire sampling period. Phototoxic-equivalent PAH concentrations and mortality demonstrated an exposure-response relation. The results indicate that runoff remains acutely toxic for weeks to months after CT sealcoat application.

Environmental Science & Technology↗
USGS2015

Exposure to runoff from coal-tar-sealed pavement induces genotoxicity and impairment of DNA repair capacity in the RTL-W1 fish liver cell line

Coal-tar-based (CTB) sealcoat, frequently applied to parking lots and driveways in North America, contains elevated concentrations of polycyclic aromatic hydrocarbons (PAHs) and related compounds. The RTL-W1 fish liver cell line was used to investigate two endpoints (genotoxicity and DNA-repair-capacity impairment) associated with exposure to runoff from asphalt pavement with CTB sealcoat or with an asphalt-based sealcoat hypothesized to contain about 7% CTB sealcoat (AS-blend). Genotoxic potential was assessed by the Formamido pyrimidine glycosylase (Fpg)-modified comet assay for 1:10 and 1:100 dilutions of runoff samples collected from 5 h to 36 d following sealcoat application. DNA-repair capacity was assessed by the base excision repair comet assay for 1:10 dilution of samples collected 26 h and 36 d following application. Both assays were run with and without co-exposure to ultraviolet-A radiation (UVA). With co-exposure to UVA, genotoxic effects were significant for both dilutions of CTB runoff for three of four sample times, and for some samples of AS-blend runoff. Base excision repair was significantly impaired for CTB runoff both with and without UVA exposure, and for AS-blend runoff only in the absence of UVA. This study is the first to investigate the effects of exposure to the complex mixture of chemicals in coal tar on DNA repair capacity. The results indicate that co-exposure to runoff from CT-sealcoated pavement and UVA as much as a month after sealcoat application has the potential to cause genotoxicity and impair DNA repair capacity.

Science of the Total Environment↗
USGS2015

The quality of our Nation's waters: Groundwater quality in the Columbia Plateau and Snake River Plain basin-fill and basaltic-rock aquifers and the Hawaiian volcanic-rock aquifers, Washington, Idaho, and Hawaii, 1993-2005

The Columbia Plateau, Snake River Plain, and Hawaii are large volcanic areas in the western United States and mid-Pacific ocean that contain extensive regional aquifers of a hard, gray, volcanic rock called basalt. Residents of the Columbia Plateau, the Snake River Plain, and the island of Oahu depend on groundwater as their primary source of drinking water. Although the depth to the water table can be several hundred feet, the groundwater is highly vulnerable to contamination because the permeable sediments and rocks allow contaminants to move readily down to the water table. Intense agricultural and urban activities occur above the drinking-water supply and are increasing in some areas. Contaminants, such as nitrate, pesticides, and volatile organic compounds, associated with agricultural and urban activities, have adversely affected groundwater quality.

Hawaii, Idaho, Washington↗