Geology topics

B.L. Jolliff

Publications and source records attributed to B.L. Jolliff.

At least 19 recordsLinked to original sources

USGS2014

Ancient aqueous environments at Endeavour crater, Mars

Opportunity has investigated in detail rocks on the rim of the Noachian age Endeavour crater, where orbital spectral reflectance signatures indicate the presence of Fe +3 -rich smectites. The signatures are associated with fine-grained, layered rocks containing spherules of diagenetic or impact origin. The layered rocks are overlain by breccias, and both units are cut by calcium sulfate veins precipitated from fluids that circulated after the Endeavour impact. Compositional data for fractures in the layered rocks suggest formation of Al-rich smectites by aqueous leaching. Evidence is thus preserved for water-rock interactions before and after the impact, with aqueous environments of slightly acidic to circum-neutral pH that would have been more favorable for prebiotic chemistry and microorganisms than those recorded by younger sulfate-rich rocks at Meridiani Planum.

Science↗

USGS2012

Ancient impact and aqueous processes at Endeavour Crater, Mars

The rover Opportunity has investigated the rim of Endeavour Crater, a large ancient impact crater on Mars. Basaltic breccias produced by the impact form the rim deposits, with stratigraphy similar to that observed at similar-sized craters on Earth. Highly localized zinc enrichments in some breccia materials suggest hydrothermal alteration of rim deposits. Gypsum-rich veins cut sedimentary rocks adjacent to the crater rim. The gypsum was precipitated from low-temperature aqueous fluids flowing upward from the ancient materials of the rim, leading temporarily to potentially habitable conditions and providing some of the waters involved in formation of the ubiquitous sulfate-rich sandstones of the Meridiani region.

Science↗

USGS2011

Stability of Mg-sulfates at-10C and the rates of dehydration/rehydration processes under conditions relevant to Mars

We report the results of low temperature (−10°C) experiments on the stability fields and phase transition pathways of five hydrous Mg-sulfates. A low temperature form of MgSO 4 ·7H 2 O (LT-7w) was found to have a wide stability field that extends to low relative humidity (∼13% RH at −10°C). Using information on the timing of phase transitions, we extracted information on the reaction rates of five important dehydration and rehydration processes. We found that the temperature dependencies of rate constants for dehydration processes differ from those of rehydration, which reflect differences in reaction mechanisms. By extrapolating these rate constants versus T correlations into the T range relevant to Mars, we can evaluate the possibility of occurrence of specific processes and the presence of common Mg-sulfate species present on Mars in different periods and locations. We anticipate in a moderate obliquity period, starkeyite and LH-MgSO 4 ·H 2 O should be two common Mg-sulfates at the surface, another polymorph MH-MgSO 4 ·H 2 O can exist at the locations where hydrothermal processes may have occurred. In polar regions or within the subsurface of other regions, meridianiite (coexisting with water ice, near 100% RH) and LT-7w (over a large RH range) are the stable phases. During a high obliquity period, meridianiite and LT-7w should exhibit widespread occurrence. The correlations of reaction rates versus temperature found in this study imply that dehydration and rehydration of hydrous Mg-sulfates would always be slower than the sublimation and crystallization of water ice, which would be supported by mission observations from Odyssey and by Mars Exploration Rovers.

Journal of Geophysical Research E: Planets↗

USGS2011

Opportunity Mars Rover mission: Overview and selected results from Purgatory ripple to traverses to Endeavour crater

Opportunity has been traversing the Meridiani plains since 25 January 2004 (sol 1), acquiring numerous observations of the atmosphere, soils, and rocks. This paper provides an overview of key discoveries between sols 511 and 2300, complementing earlier papers covering results from the initial phases of the mission. Key new results include (1) atmospheric argon measurements that demonstrate the importance of atmospheric transport to and from the winter carbon dioxide polar ice caps; (2) observations showing that aeolian ripples covering the plains were generated by easterly winds during an epoch with enhanced Hadley cell circulation; (3) the discovery and characterization of cobbles and boulders that include iron and stony-iron meteorites and Martian impact ejecta; (4) measurements of wall rock strata within Erebus and Victoria craters that provide compelling evidence of formation by aeolian sand deposition, with local reworking within ephemeral lakes; (5) determination that the stratigraphy exposed in the walls of Victoria and Endurance craters show an enrichment of chlorine and depletion of magnesium and sulfur with increasing depth. This result implies that regional-scale aqueous alteration took place before formation of these craters. Most recently, Opportunity has been traversing toward the ancient Endeavour crater. Orbital data show that clay minerals are exposed on its rim. Hydrated sulfate minerals are exposed in plains rocks adjacent to the rim, unlike the surfaces of plains outcrops observed thus far by Opportunity. With continued mechanical health, Opportunity will reach terrains on and around Endeavour's rim that will be markedly different from anything examined to date.

Journal of Geophysical Research E: Planets↗

USGS2011

Bounce Rock-A shergottite-like basalt encountered at Meridiani Planum, Mars

The Opportunity rover of the Mars Exploration Rover mission encountered an isolated rock fragment with textural, mineralogical, and chemical properties similar to basaltic shergottites. This finding was confirmed by all rover instruments, and a comprehensive study of these results is reported here. Spectra from the miniature thermal emission spectrometer and the Panoramic Camera reveal a pyroxene-rich mineralogy, which is also evident in M??ssbauer spectra and in normative mineralogy derived from bulk chemistry measured by the alpha particle X-ray spectrometer. The correspondence of Bounce Rock's chemical composition with the composition of certain basaltic shergottites, especially Elephant Moraine (EET) 79001 lithology B and Queen Alexandra Range (QUE) 94201, is very close, with only Cl, Fe, and Ti exhibiting deviations. Chemical analyses further demonstrate characteristics typical of Mars such as the Fe/Mn ratio and P concentrations. Possible shock features support the idea that Bounce Rock was ejected from an impact crater, most likely in the Meridiani Planum region. Bopolu crater, 19.3km in diameter, located 75km to the southwest could be the source crater. To date, no other rocks of this composition have been encountered by any of the rovers on Mars. The finding of Bounce Rock by the Opportunity rover provides further direct evidence for an origin of basaltic shergottite meteorites from Mars.

Meteoritics and Planetary Science↗

USGS2010

Silica in a Mars analog environment: Ka u Desert, Kilauea Volcano, Hawaii

Airborne Visible/Near-Infrared Imaging Spectrometer (AVIRIS) data acquired over the Ka u Desert are atmospherically corrected to ground reflectance and used to identify the mineralogic components of relatively young basaltic materials, including 250-700 and 200-400 year old lava flows, 1971 and 1974 flows, ash deposits, and solfatara incrustations. To provide context, a geologic surface units map is constructed, verified with field observations, and supported by laboratory analyses. AVIRIS spectral endmembers are identified in the visible (0.4 to 1.2 ??m) and short wave infrared (2.0 to 2.5 ??m) wavelength ranges. Nearly all the spectral variability is controlled by the presence of ferrous and ferric iron in such minerals as pyroxene, olivine, hematite, goethite, and poorly crystalline iron oxides or glass. A broad, nearly ubiquitous absorption feature centered at 2.25 ??m is attributed to opaline (amorphous, hydrated) silica and is found to correlate spatially with mapped geologic surface units. Laboratory analyses show the silica to be consistently present as a deposited phase, including incrustations downwind from solfatara vents, cementing agent for ash duricrusts, and thin coatings on the youngest lava flow surfaces. A second, Ti-rich upper coating on young flows also influences spectral behavior. This study demonstrates that secondary silica is mobile in the Ka u Desert on a variety of time scales and spatial domains. The investigation from remote, field, and laboratory perspectives also mimics exploration of Mars using orbital and landed missions, with important implications for spectral characterization of coated basalts and formation of opaline silica in arid, acidic alteration environments. Copyright 2010 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

USGS2010

Lunar Reconnaissance Orbiter Camera (LROC) instrument overview

The Lunar Reconnaissance Orbiter Camera (LROC) Wide Angle Camera (WAC) and Narrow Angle Cameras (NACs) are on the NASA Lunar Reconnaissance Orbiter (LRO). The WAC is a 7-color push-frame camera (100 and 400 m/pixel visible and UV, respectively), while the two NACs are monochrome narrow-angle linescan imagers (0.5 m/pixel). The primary mission of LRO is to obtain measurements of the Moon that will enable future lunar human exploration. The overarching goals of the LROC investigation include landing site identification and certification, mapping of permanently polar shadowed and sunlit regions, meter-scale mapping of polar regions, global multispectral imaging, a global morphology base map, characterization of regolith properties, and determination of current impact hazards.

Space Science Reviews↗

USGS2008

Hematite spherules at Meridiani: results from MI, Mini-TES, and Pancam

We report on observations of hematite‐bearing spherules at Meridiani Planum made using the Microscopic Imager (MI), Mini‐Thermal Emission Spectrometer (Mini‐TES), and Panoramic Camera (Pancam) instruments on the Mars Exploration Rover Opportunity. Spherules were observed on soil surfaces and in outcrop rocks, both on undisturbed surfaces and in abraded surfaces ground using the Rock Abrasion Tool (RAT). Spherule size and shape change little along the 850 m eastward traverse from Eagle Crater to Endurance Crater, but spherules decrease and then slightly increase in size along the 6 km traverse from Endurance south to Victoria Crater. Local populations range from submillimeters to several millimeters in diameter. An additional small diameter (100 μ m) size population is possible. An increase in irregular shapes is found near Victoria Crater. This, combined with the size decrease south of Endurance, suggests either a changing depositional environment, or variation in the duration and timing of diagenetic events. The dominant smaller size population observed early in the mission in aeolian areas and ripple crests is observed as the primary size population in abraded outcrop farther south. This suggests that successively younger beds are exposed at the surface along the southward traverse. Stratigraphically higher units removed by erosion could be recorded by the present surface lag deposit. Coordinated systematic observations are used to determine optical and infrared hematite indices of the surface soils in Pancam and Mini‐TES. In spite of the systematic variation seen in MI, both Pancam and Mini‐TES indices are highly variable based on the local surface, and neither show systematic trends south of Endurance. The lack of a 390 cm −1 feature in Mini‐TES spectra suggests concentric or radial interior structure within the spherules at scales too fine for MI to observe. Mini‐TES does not detect any silicate component in the spherules. A bound water component in soils or in exchange with the atmosphere is observed. These spherules have been previously interpreted as concretions formed within what were once water‐saturated, diagenetically altered “dirty evaporate” sandstone sediments. Our observations support this interpretation; however, no single terrestrial analog provides a model that can account for all attributes of the spherules on Mars.

Journal of Geophysical Research↗

USGS2008

Veneers, rinds, and fracture fills: Relatively late alteration of sedimentary rocks at Meridiani Planum, Mars

Veneers and thicker rinds that coat outcrop surfaces and partially cemented fracture fills formed perpendicular to bedding document relatively late stage alteration of ancient sedimentary rocks at Meridiani Planum, Mars. The chemistry of submillimeter thick, buff-colored veneers reflects multiple processes at work since the establishment of the current plains surface. Veneer composition is dominated by the mixing of silicate-rich dust and sulfate-rich outcrop surface, but it has also been influenced by mineral precipitation, including NaCl, and possibly by limited physical or chemical weathering of sulfate minerals. Competing processes of chemical alteration (perhaps mediated by thin films of water or water vapor beneath blanketing soils) and sandblasting of exposed outcrop surfaces determine the current distribution of veneers. Dark-toned rinds several millimeters thick reflect more extensive surface alteration but also indicate combined dust admixture, halite precipitation, and possible minor sulfate removal. Cemented fracture fills that are differentially resistant to erosion occur along the margins of linear fracture systems possibly related to impact. These appear to reflect limited groundwater activity along the margins of fractures, cementing mechanically introduced fill derived principally from outcrop rocks. The limited thickness and spatial distribution of these three features suggest that aqueous activity has been rare and transient or has operated at exceedingly low rates during the protracted interval since outcropping Meridiani strata were exposed on the plains surface.

Journal of Geophysical Research E: Planets↗

USGS2008

Meteorites on Mars observed with Mars Exploration Rovers

Reduced weathering rates due to the lack of liquid water and significantly greater typical surface ages should result in a higher density of meteorites on the surface of Mars compared to Earth. Several meteorites were identified among the rocks investigated during Opportunity's traverse across the sandy Meridiani plains. Heat Shield Rock is a IAB iron meteorite and has been officially recognized as 'Meridiani Planum.' Barberton is olivine-rich and contains metallic Fe in the form of kamacite, suggesting a meteoritic origin. It is chemically most consistent with a mesosiderite silicate clast. Santa Catarina is a brecciated rock with a chemical and mineralogical composition similar to Barberton. Barberton, Santa Catarina, and cobbles adjacent to Santa Catarina may be part of a strewn field. Spirit observed two probable iron meteorites from its Winter Haven location in the Columbia Hills in Gusev Crater. Chondrites have not been identified to date, which may be a result of their lower strengths and probability to survive impact at current atmospheric pressures. Impact craters directly associated with Heat Shield Rock, Barberton, or Santa Catarina have not been observed, but such craters could have been erased by eolian-driven erosion.

Journal of Geophysical Research E: Planets↗

USGS2007

Visible and near-infrared multispectral analysis of rocks at Meridiani Planum, Mars, by the Mars Exploration Rover Opportunity

Multispectral measurements in the visible and near infrared of rocks at Meridiani Planum by the Mars Exploration Rover Opportunity's Pancam are described. The Pancam multispectral data show that the outcrops of the Burns formation consist of two main spectral units which in stretched 673, 535, 432 nm color composites appear buff- and purple-colored. These units are referred to as the HFS and LFS spectral units based on higher and lower values of 482 to 535 nm slope. Spectral characteristics are consistent with the LFS outcrop consisting of less oxidized, and the HFS outcrop consisting of more oxidized, iron-bearing minerals. The LFS surfaces are not as common and appear, primarily, at the distal ends of outcrop layers and on steep, more massive surfaces, locations that are subject to greater eolian erosion. Consequently, the HFS surfaces are interpreted as a weathering rind. Further inherent spectral differences between layer's and between different outcrop map units, both untouched and patches abraded by the rover's Rock Abrasion Tool, are also described. Comparisons of the spectral parameters of the Meridiani outcrop with a set of laboratory reflectance measurements of Fe3+-bearing minerals show that the field of outcrop measurements plots near the fields of hematite, ferrihydrite, poorly crystalline goethite, and schwertmannite. Rind and fracture fill materials, observed intermittently at outcrop exposures, are intermediate in their spectral character between both the HFS and LFS spectral classes and other, less oxidized, surface materials (basaltic sands, spherules, and cobbles). Copyright 2007 by the American Geophysical Union.

Journal of Geophysical Research E: Planets↗

USGS2006

Soil grain analyses at Meridiani Planum, Mars

Grain‐size analyses of the soils at Meridiani Planum have been used to identify rock sources for the grains and provide information about depositional processes under past and current conditions. Basaltic sand, dust, millimeter‐size hematite‐rich spherules interpreted as concretions, spherule fragments, coated partially buried spherules, basalt fragments, sedimentary outcrop fragments, and centimeter‐size cobbles are concentrated on the upper surfaces of the soils as a lag deposit, while finer basaltic sands and dust dominate the underlying soils. There is a bimodal distribution of soil grain sizes with one population representing grains <125 μm and the other falling between 1–4.5 mm. Soils within craters like Eagle and Endurance show a much greater diversity of grain morphologies compared to the plains. The spherules found in the plains soils are approximately 1–2 mm smaller in size than those seen embedded in the outcrop rocks of Eagle and Endurance craters. The average major axis for all unfractured spherules measured in the soils and outcrop rocks is 2.87 ± 1.18 mm, with a trend toward decreasing spherule sizes in both the soils and outcrop rocks as the rover drove southward. Wind ripples seen across the plains of Meridiani are dominated by similar size (1.3–1.7 mm) hematite‐rich grains, and they match in size the larger grains on plains ripples at Gusev Crater. Larger clasts and centimeter‐size cobbles that are scattered on the soils have several spectral and compositional types, reflecting multiple origins. The cobbles tend to concentrate within ripple troughs along the plains and in association with outcrop exposures.

Journal of Geophysical Research E: Planets↗

USGS2006

Bedrock formation at Meridiani Planum

The Mars Exploration Rover Opportunity discovered sulphate-rich sedimentary rocks at Meridiani Planum on Mars, which are interpreted by McCollom and Hynek as altered volcanic rocks. However, their conclusions are derived from an incorrect representation of our depositional model , which is upheld by more recent Rover data . We contend that all the available data still support an aeolian and aqueous sedimentary origin for Meridiani bedrock.

Nature↗

USGS2006

Sulfate deposition in subsurface regolith in Gusev crater, Mars

Excavating into the shallow Martian subsurface has the potential to expose stratigraphic layers and mature regolith, which may hold a record of more ancient aqueous interactions than those expected under current Martian surface conditions. During the Spirit rover's exploration of Gusev crater, rover wheels were used to dig three trenches into the subsurface regolith down to 6-11 cm depth: Road Cut, the Big Hole, and The Boroughs. A high oxidation state of Fe and high concentrations of Mg, S, Cl, and Br were found in the subsurface regolith within the two trenches on the plains, between the Bonneville crater and the foot of Columbia Hills. Data analyses on the basis of geochemistry and mineralogy observations suggest the deposition of sulfate minerals within the subsurface regolith, mainly Mg-sulfates accompanied by minor Ca-sulfates and perhaps Fe-sulfates. An increase of Fe2O3, an excess of SiO2, and a minor decrease in the olivine proportion relative to surface materials are also inferred. Three hypotheses are proposed to explain the geochemical trends observed in trenches: (1) multiple episodes of acidic fluid infiltration, accompanied by in situ interaction with igneous minerals and salt deposition; (2) an open hydrologic system characterized by ion transportation in the fluid, subsequent evaporation of the fluid, and salt deposition; and (3) emplacement and mixing of impact ejecta of variable composition. While all three may have plausibly contributed to the current state of the subsurface regolith, the geochemical data are most consistent with ion transportation by fluids and salt deposition as a result of open-system hydrologic behavior. Although sulfates make up >20 wt.% of the regolith in the wall of The Boroughs trench, a higher hydrated sulfate than kieserite within The Boroughs or a greater abundance of sulfates elsewhere than is seen in The Boroughs wall regolith would be needed to hold the structural water indicated by the water-equivalent hydrogen concentration observed by the Gamma-Ray Spectrometer on Odyssey in the Gusev region.

Journal of Geophysical Research E: Planets↗

USGS2006

Evidence of phyllosilicates in Wooly Patch, an altered rock encountered at West Spur, Columbia Hills, by the Spirit rover in Gusev crater, Mars

On its traverse to Columbia Hills, the Mars Exploration Rover Spirit investigated an outcrop designated “Wooly Patch” that exhibited morphological, mineralogical, and geochemical characteristics at the extreme ends of ranges observed among rocks studied at West Spur, a westward projecting salient near the foot of the Columbia Hills, Gusev crater. The major‐element composition and Fe‐mineralogy, as determined by the Alpha‐Particle X‐ray Spectrometer and Mössbauer Spectrometer, are inconsistent with any reasonable assemblage of basaltic minerals in that there is an excess of Si and Al. The combined data are best explained by the presence of 14–17% phyllosilicate minerals. Phyllosilicates that account for the composition and cation ratios include members of the kaolinite, serpentine, chlorite, and septechlorite groups. The potential existence of kaolinite‐type Al‐rich phyllosilicates within the Wooly Patch outcrop suggests a mildly acidic environment (pH 4–6) in the past and an open hydrologic system with good drainage conditions in the environment where these rocks were altered.

Journal of Geophysical Research E: Planets↗

USGS2006

Sulfates on Mars: A systematic Raman spectroscopic study of hydration states of magnesium sulfates

The martian orbital and landed surface missions, OMEGA on Mar Express and the two Mars Explorations Rovers, respectively, have yielded evidence pointing to the presence of magnesium sulfates on the martian surface. In situ identification of the hydration states of magnesium sulfates, as well as the hydration states of other Ca- and Fe- sulfates, will be crucial in future landed missions on Mars in order to advance our knowledge of the hydrologic history of Mars as well as the potential for hosting life on Mars. Raman spectroscopy is a technique well-suited for landed missions on the martian surface. In this paper, we report a systematic study of the Raman spectra of the hydrates of magnesium sulfate. Characteristic and distinct Raman spectral patterns were observed for each of the 11 distinct hydrates of magnesium sulfates, crystalline and non-crystalline. The unique Raman spectral features along with the general tendency of the shift of the position of the sulfate ??1 band towards higher wavenumbers with a decrease in the degree of hydration allow in situ identification of these hydrated magnesium sulfates from the raw Raman spectra of mixtures. Using these Raman spectral features, we have started the study of the stability field of hydrated magnesium sulfates and the pathways of their transformations at various temperature and relative humidity conditions. In particular we report on the Raman spectrum of an amorphous hydrate of magnesium sulfate (MgSO4??2H2O) that may have specific relevance for the martian surface. ?? 2006 Elsevier Inc. All rights reserved.

Geochimica et Cosmochimica Acta↗

USGS2006

Two years at Meridiani Planum: Results from the Opportunity Rover

The Mars Exploration Rover Opportunity has spent more than 2 years exploring Meridiani Planum, traveling ∼8 kilometers and detecting features that reveal ancient environmental conditions. These include well-developed festoon (trough) cross-lamination formed in flowing liquid water, strata with smaller and more abundant hematite-rich concretions than those seen previously, possible relict “hopper crystals” that might reflect the formation of halite, thick weathering rinds on rock surfaces, resistant fracture fills, and networks of polygonal fractures likely caused by dehydration of sulfate salts. Chemical variations with depth show that the siliciclastic fraction of outcrop rock has undergone substantial chemical alteration from a precursor basaltic composition. Observations from microscopic to orbital scales indicate that ancient Meridiani once had abundant acidic groundwater, arid and oxidizing surface conditions, and occasional liquid flow on the surface.

Science↗

USGS2005

Water alteration of rocks and soils on Mars at the Spirit rover site in Gusev crater

Gusev crater was selected as the landing site for the Spirit rover because of the possibility that it once held a lake. Thus one of the rover's tasks was to search for evidence of lake sediments. However, the plains at the landing site were found to be covered by a regolith composed of olivine-rich basaltic rock and wind-blown 'global' dust. The analyses of three rock interiors exposed by the rock abrasion tool showed that they are similar to one another, consistent with having originated from a common lava flow. Here we report the investigation of soils, rock coatings and rock interiors by the Spirit rover from sol (martian day) 1 to sol 156, from its landing site to the base of the Columbia hills. The physical and chemical characteristics of the materials analysed provide evidence for limited but unequivocal interaction between water and the volcanic rocks of the Gusev plains. This evidence includes the softness of rock interiors that contain anomalously high concentrations of sulphur, chlorine and bromine relative to terrestrial basalts and martian meteorites; sulphur, chlorine and ferric iron enrichments in multilayer coatings on the light-toned rock Mazatzal; high bromine concentration in filled vugs and veins within the plains basalts; positive correlations between magnesium, sulphur and other salt components in trench soils; and decoupling of sulphur, chlorine and bromine concentrations in trench soils compared to Gusev surface soils, indicating chemical mobility and separation.

Nature↗