Geology topics

B. A. Bonn

Publications and source records attributed to B. A. Bonn.

3 recordsLinked to original sources

USGS1998

Polychlorinated dibenzo-p-dioxin and dibenzofuran concentration profiles in sediment and fish tissue of the Willamette Basin, Oregon

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) are highly hydrophobic compounds that have been implicated as carcinogens and, more recently, as estrogen disrupters. An occurrence and distribution study of these compounds in the Willamette Basin, Oregon, was conducted by the U.S. Geological Survey as part of the National Water-Quality Assessment Program. Bed sediment was collected from 22 sites; fish tissue was collected from eight sites. PCDD/F were found to be ubiquitous in Willamette Basin sediment. A distinct homolog profile, dominated by octachlorodibenzo-p-dioxin, was observed in sediment throughout the basin. The PCDD homolog profile was consistent at all sites, regardless of total PCDD/F concentration, presence of point sources, subbasin size, geographic location or land use. Principal components analysis revealed a gradient among the homolog profiles that showed increasing dominance of highly chlorinated congeners where human and industrial activity increased. Tissue and bed sediment obtained from the same site did not have similar PCDD/F concentrations or homolog profiles. Fish tissue showed enrichment in less chlorinated congeners and congeners with chlorine substitutions in the 2, 3, 7 and 8 positions.

Environmental Science & Technology↗

USGS1998

Dioxins and furans in bed sediment and fish tissue of the Willamette Basin, Oregon, 1992-95

Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F) are related compounds that are of interest primarily because of their potential toxicity. They are considered carcinogens and have been implicated as hormone disrupters. An occurrence and distribution study of these compounds in the Willamette Basin, Oregon, was done by the U.S. Geological Survey in 1992- 1995. Bed sediment samples were collected at 22 sites, and fish tissue samples were collected from 8 sites. Samples were analyzed for 10 tetra- through octa- congener class totals and for 17 individual 2,3,7,8-substituted congeners. PCDD/Fs were found in bed sediment and fish tissue throughout the basin, including samples from the most remote forested sites. PCDD/F concentrations in bed sediment at most sites in agricultural and forested areas were similar to those at reference sites worldwide and are probably background concentrations due to atmospheric deposition. The highest concentrations in bed sediment were found at sites where industrial or urban inputs were likely. Potential toxicity at these sites (as measured by toxicity equivalents concentration) was high enough to be associated with increased risk to sensitive wildlife. From 30-60 percent of the toxicity equivalents concentration in bed sediment was due to hepta- and octa- congeners. The most toxic congener, 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7,8-TCDD), was detected at only 6 of 22 sites. Compared to bed sediment from the same site, fish tissue usually had a lower total PCDD/F concentration, but contained a higher proportion of the most toxic congeners, such as 2,3,7,8-TCDD and 2,3,7,8-tetrachlorodibenzofuran. Because of these differences, toxicity equivalents concentrations in fish were higher than those in bed sediment from the same site at half of the sites where both media were analyzed.

Oregon↗

USGS1995

Analysis of nutrient and ancillary water-quality data for surface and ground water of the Willamette Basin, Oregon, 1980-90

An analysis of historical water-quality data for surface and ground water collected in the Willamette and Sandy River Basins during the 1980-90 water years was performed. For surface water, most data were concentrated at sites on the main stem Willamette River or near the mouths of major tributaries. All seasons were represented. Data for nitrogen and phosphorus species were readily available, but simultaneously collected discharge measurements frequently were not. Seven primary sites were used for a quantitative analysis of nutrient data in surface water. At six of the seven primary sites, median concentrations of nitrite plus nitrate and total phosphorus were less than 0.5 milligrams per liter (mg/L) as nitrogen (N) and 0.1 mg/L as phosphorus (P), respectively. These concen- trations were lower than national median concen- trations for basins with similar land uses. At the Pudding River site, which received significant point-source and agricultural nonpoint-source inputs, median values for nitrite plus nitrate and total phosphorus were 1.4 mg/L as N and 0.2 mg/L as P, respectively. Nitrite-plus-nitrate concentrations at this site were seasonally dependent, with the highest concentrations occurring during winter. Forested sites had significantly lower water temperatures and nutrient concentrations than urban or agricultural sites. Evidence of diel variations in dissolved oxygen concentrations and pH values suggest that, at some sites, low dissolved oxygen concentrations may be a problem during early morning hours in the summer. Historical nutrient data for ground water were limited primarily to nitrate and nitrite-plus-nitrate determinations for wells completed in the basin-fill and alluvial aquifer. Nitrate and nitrite-plus-nitrate concentrations in this aquifer showed a weak inverse relationship with depth.

Water-Resources Investigations Report↗