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Anna C. Baker

Publications and source records attributed to Anna C. Baker.

7 recordsLinked to original sources
USGS2024

Role of tributary cyanobacterial and nutrient transport and sediment processes on cyanobacterial bloom initiation in Lake Superior nearshore

Watershed fluxes of suspended sediment (SS), nutrients, in particular phosphorus (P), and cyanobacteria may play a role in driving cyanobacterial blooms along the southwestern shore of oligotrophic Lake Superior. To understand how tributary loads contribute to nearshore blooms, we sampled two southwestern shore tributaries, Bois Brule and Siskiwit Rivers. We collected water-quality samples to compute nutrient and sediment loads and to assess cyanobacteria community composition from the tributaries to the nearshore. We collected suspended and streambed sediment to assess the capacity for sediment to store and transport bioavailable P and to assess cyanobacteria community composition. Storm flows drove export of SS, total P, and total nitrogen, with the majority of total P being particulate P. Equilibrium P concentrations revealed that SS sorbed P as it is moved through the stream network across sites and seasons and was a potential source of P to the nearshore. However, streambed sediment in the Bois Brule and Siskiwit River watersheds were P sinks during summer, which potentially delayed transport of dissolved P to the lake. The cyanobacteria community varied spatially and temporally relating to multiple environmental variables including nutrients (P, N, and C) and specific conductivity. Cyanobacteria capable of producing cyanotoxins were present in tributaries and found across multiple environmental compartments indicating a potential for fluvial flow to the nearshore. This study demonstrated that streamflow is a primary driver of total nutrient and sediment loading in both watersheds, which indicates the potential for algal loading to the nearshore via suspended sediment or water.

Wisconsin↗
USGS2023

Hydrologic change in the St. Louis River Basin from iron mining on the Mesabi Iron Range, northeastern Minnesota

This study compares the results of two regional steady-state U.S. Geological Survey Modular Three-Dimensional Finite-Difference Ground-Water Flow (MODFLOW) models constructed to quantify the hydrologic changes in the St. Louis River Basin from iron mining on the Mesabi Iron Range in northeastern Minnesota. The U.S. Geological Survey collaborated in this study with bands of the Minnesota Chippewa Tribe, and the Minnesota Pollution Control Agency to inform management decisions about aquatic resources in the St. Louis River Basin. A model constructed and calibrated to represent average 1995–2015 mining conditions produced regional groundwater heads and flows. A pre-mining scenario model was constructed from this mining model but had the land and bedrock surfaces restored to pre-mining topographies and had modeled mining features (mine pits, tailings basins, waste-rock piles, and mining-disturbed areas) eliminated to represent general pre-mining stratigraphy and hydrogeology. Many of the features important to the hydrology of this mining area (like individual mine pits) are difficult to represent in groundwater models and required the use of modeling tools to indirectly account for their effects. The difference between the results of these two models represents mining’s effects on the hydrology in the Mesabi Iron Range area of the St Louis River Basin. The mining and pre-mining regional models also can provide boundary conditions and initial properties for future local or site-specific groundwater-flow models in the area. Total groundwater flow through the mining model is 171 million cubic feet per day. Areal recharge is the largest source of groundwater (78 and 81 percent of total groundwater flow in the mining and pre-mining scenario models, respectively). Seepage from streams and lakes provides another 17 percent of the total groundwater flow through both models. Water leaves aquifers through seepage to streams (discharge as base flow, 43 percent in both models) and areal seepage to the land surface (surface seepage), for example to wetlands (45 and 49 percent, mining and pre-mining scenario models respectively). Comparison of the results from the mining and pre-mining scenario models shows that iron mining has produced measurable hydrologic changes in the St. Louis River Basin, but that most of those changes and the highest magnitude changes occur near the mining features. Flow changes to and from surface-water bodies like streams and wetlands were analyzed in detail because of their importance in sustaining surface waters and aquatic life. Overall, groundwater flow in the mining model was 3.62 million cubic feet per day (2.2 percent) greater than total pre-mining model groundwater flow. This was caused by an increase in recharge from tailings basins and a decrease in discharge from surface seepage. Groundwater discharge to mine pits was the largest change in groundwater flows between the models (a change representing 2.8 percent of total pre-mining model groundwater flow). Net recharge to groundwater from tailings basins (2.4 percent), net decrease in surface seepage from groundwater (2.7 percent), and net increase in seepage to streams (1.0 percent) were all in this same range of total pre-mining model groundwater flow. Groundwater lost through mine-pit withdrawals was nearly offset by groundwater gained through recharge from tailings basins. However, because losses and gains occurred in different areas, the effect of mining can have more substantial effects on local areas than the model-wide averages represent.

Minnesota↗
USGS2019

Simulation of the regional groundwater-flow system in the St. Louis River basin, Minnesota

The St. Louis River Basin (SLRB) covers 3,600 square miles in northeastern Minnesota, with headwaters in the Mesabi Range and extensive wetlands and lakes throughout the basin. To better understand the regional groundwater system in the SLRB, a two-dimensional, steady-state groundwater-flow model of the SLRB was developed by the U.S. Geological Survey, in cooperation with the Minnesota Ojibwe Bands, using the analytic-element computer code GFLOW. The parameter-estimation software suite PEST was used to obtain a best fit of the modeled to measured groundwater levels and streamflows. The calibrated regional model was locally refined to create a smaller version of the model, the central SLRB model, that was used to evaluate hydrologic effects from extensive ditching in wetlands of the central SLRB. The refinements included adding ditches that were not represented in the regional model and modifying the aquifer base elevation to be more representative of the localized area. The central SLRB model was recalibrated to better match the distribution of mapped wetlands. Two scenarios were run of the central SLRB model: one with ditches and one without ditches. The model results were compared between the two scenarios to assess the effect of ditching on the groundwater system and potential changes to hydrologic conditions that support wetlands. Calibration of the regional SRLB model resulted in average horizontal hydraulic conductivity values of 6–39 feet per day for the glacial deposits and 3–4 feet per day for the uppermost fractured bedrock in the Biwabik Iron-Formation on the Mesabi Range. Average recharge across the calibrated model was 5.9 inches per year. Linesink resistance for the routed stream network was calibrated by using resistance categories based on the mapped soil hydrologic groups. The modeled regional groundwater-flow direction was generally to the south near the Mesabi Range topographic high and south or southwest across the rest of the basin. The updated calibration of the central SLRB model resulted in average horizontal hydraulic conductivity values of 5–36 feet per day for the glacial deposits and 3 feet per day for the uppermost fractured Biwabik Iron-Formation of the Mesabi Range. Average recharge across the ditch scenarios was 4.1 inches per year. Comparison of the preditch and postditch model scenarios showed that ditching reduced the area where the modeled water table was within 1 foot of the land surface (a wetland hydrology indicator) in as much as 40,000 acres, or 37 percent, of mapped permanent wetlands in the SLRB. An increase in the depth to the water table in wetland areas has the potential to degrade wetland persistence or function.

Minnesota↗
USGS2017

Optimal hydrograph separation using a recursive digital filter constrained by chemical mass balance, with application to selected Chesapeake Bay watersheds

Quantitative estimates of base flow are necessary to address questions concerning the vulnerability and response of the Nation’s water supply to natural and human-induced change in environmental conditions. An objective of the U.S. Geological Survey National Water-Quality Assessment Project is to determine how hydrologic systems are affected by watershed characteristics, including land use, land cover, water use, climate, and natural characteristics (geology, soil type, and topography). An important component of any hydrologic system is base flow, generally described as the part of streamflow that is sustained between precipitation events, fed to stream channels by delayed (usually subsurface) pathways, and more specifically as the volumetric discharge of water, estimated at a measurement site or gage at the watershed scale, which represents groundwater that discharges directly or indirectly to stream reaches and is then routed to the measurement point. Hydrograph separation using a recursive digital filter was applied to 225 sites in the Chesapeake Bay watershed. The recursive digital filter was chosen for the following reasons: it is based in part on the assumption that groundwater acts as a linear reservoir, and so has a physical basis; it has only two adjustable parameters (alpha, obtained directly from recession analysis, and beta, the maximum value of the base-flow index that can be modeled by the filter), which can be determined objectively and with the same physical basis of groundwater reservoir linearity, or that can be optimized by applying a chemical-mass-balance constraint. Base-flow estimates from the recursive digital filter were compared with those from five other hydrograph-separation methods with respect to two metrics: the long-term average fraction of streamflow that is base flow, or base-flow index, and the fraction of days where streamflow is entirely base flow. There was generally good correlation between the methods, with some biased slightly high and some biased slightly low compared to the recursive digital filter. There were notable differences between the days at base flow estimated by the different methods, with the recursive digital filter having a smaller range of values. This was attributed to how the different methods determine cessation of quickflow (the part of streamflow which is not base flow). For 109 Chesapeake Bay watershed sites with available specific conductance data, the parameters of the filter were optimized using a chemical-mass-balance constraint and two different models for the time-dependence of base-flow specific conductance. Sixty-seven models were deemed acceptable and the results compared well with non-optimized results. There are a number of limitations to the optimal hydrograph-separation approach resulting from the assumptions implicit in the conceptual model, the mathematical model, and the approach taken to impose chemical mass balance (including tracer choice). These limitations may be evidenced by poor model results; conversely, poor model fit may provide an indication that two-component separation does not adequately describe the hydrologic system’s runoff response. The results of this study may be used to address a number of questions regarding the role of groundwater in understanding past changes in stream-water quality and forecasting possible future changes, such as the timing and magnitude of land-use and management practice effects on stream and groundwater quality. Ongoing and future modeling efforts may benefit from the estimates of base flow as calibration targets or as a means to filter chemical data to model base-flow loads and trends. Ultimately, base-flow estimation might provide the basis for future work aimed at improving the ability to quantify groundwater discharge, not only at the scale of a gaged watershed, but at the scale of individual reaches as well.

Scientific Investigations Report↗
USGS2015

Hydrogeologic characterization and assessment of bioremediation of chlorinated benzenes and benzene in wetland areas, Standard Chlorine of Delaware, Inc. Superfund Site, New Castle County, Delaware, 2009-12

Wetlands at the Standard Chlorine of Delaware, Inc. Superfund Site (SCD) in New Castle County, Delaware, are affected by contamination with chlorobenzenes and benzene from past waste storage and disposal, spills, leaks, and contaminated groundwater discharge. In cooperation with the U.S. Environmental Protection Agency, the U.S. Geological Survey began an investigation in June 2009 to characterize the hydrogeology and geochemistry in the wetlands and assess the feasibility of monitored natural attenuation and enhanced bioremediation as remedial strategies. Groundwater flow in the wetland study area is predominantly vertically upward in the wetland sediments and the underlying aquifer, and groundwater discharge accounts for a minimum of 47 percent of the total discharge for the subwatershed of tidal Red Lion Creek. Thus, groundwater transport of contaminants to surface water could be significant. The major contaminants detected in groundwater in the wetland study area included benzene, monochlorobenzene, and tri- and di-chlorobenzenes. Shallow wetland groundwater in the northwest part of the wetland study area was characterized by high concentrations of total chlorinated benzenes and benzene (maximum about 75,000 micrograms per liter [μg/L]), low pH, and high chloride. In the northeast part of the wetland study area, wetland groundwater had low to moderate concentrations of total chlorinated benzenes and benzene (generally not greater than 10,000 μg/L), moderate pH, and high sulfate concentrations. Concentrations in the groundwater in excess of 1 percent of the solubility of the individual chlorinated benzenes indicate that a contaminant source is present in the wetland sediments as dense nonaqueous phase liquids (DNAPLs). Consistently higher contaminant concentrations in the shallow wetland groundwater than deeper in the wetland sediments or the aquifer also indicate a continued source in the wetland sediments, which could include dissolution of DNAPLs and desorption from the sediments. When highly reducing, methanogenic, or sulfate-reducing conditions existed in the wetland groundwater, molar composition of the volatile organic compounds (VOCs) showed that chlorobenzene and benzene were predominant, indicating biodegradation of the chlorinated benzenes through reductive dechlorination pathways. Temporal changes in redox conditions between 2009 and 2011–12 have shifted the locations in the wetland study area where reductive dechlorination is evident. Microbial community analyses of sediment showed relatively high cell numbers and diversity of populations ( Dehalococcoides , Dehalobacter , Desulfitobacterium , and Geobacter ) that are known to contain species capable of reductive dechlorination, confirming groundwater geochemistry evidence of the occurrence of reductive dechlorination. Natural attenuation was not sufficient, however, to reduce total VOC concentrations along upward groundwater flowpaths in the wetland sediments, most likely due to the additional source of contaminants in the upper sediments. In situ microcosms that were unamended except for the addition of 13 C-labeled contaminants in some treatments, confirmed that the native microbial community was able to biodegrade the higher chlorinated benzenes through reductive dechlorination and that 1,2-dichlorobenzene, chlorobenzene, and benzene could be degraded to carbon dioxide through oxidation pathways. Microcosms that were bioaugmented with the anaerobic dechlorinating consortium WBC-2 and deployed in the wetland sediments showed reductive dechlorination of tri-, di-, and monochlorobenzene, and 13 C-chlorobenzene treatments showed complete degradation of chlorobenzene to carbon dioxide under anaerobic conditions. Experiments with a continuous flow, fixed-film bioreactor seeded with native microorganisms in groundwater from the wetland area showed both aerobic and anaerobic biodegradation of dichlorobenzenes, monochlorobenzene, and benzene, although monochlorobenzene and benzene degradation rates decreased under anaerobic conditions compared to aerobic conditions. In two bioreactors with established biofilms of WBC-2, percent removals of all chlorinated benzene compounds (medians of 86 to 94 percent) under anaerobic conditions were as high as those observed for the bioreactors seeded only with native microorganisms from the site groundwater, and benzene removal was greater in the WBC-2 bioaugmented bioreactors. The high percent removals in the WBC-2 bioreactors without the need for an acclimation period indicates that the same dechlorinators are involved in the chlorinated benzene degradation as those for the chlorinated ethanes and ethenes that the culture was developed to degrade. The ability of the WBC-2 culture to completely reduce the chlorinated benzenes and benzene, even in the presence of high sulfate and sulfide concentrations, is unique for known dechlorinating cultures. The availability of the established culture WBC-2, as well as the ability of the native wetland microbial community to degrade the site contaminants under anaerobic and aerobic conditions, provides flexibility in considering bioremediation options for the wetland areas at SCD.

Delaware↗
USGS2012

Groundwater quality and occurrence and distribution of selected constituents in the Aquia and Upper Patapsco aquifers, Naval Air Station Patuxent River, St. Mary's County, Maryland, July 2008

The Naval Air Station Patuxent River in southern Maryland has continued to expand in the first decade of the 21st century, contributing to rapid population growth in the surrounding area. The increase in population has caused State and County water managers and others to be concerned about the impact of population growth on the quantity and quality of groundwater supplies. The U.S. Geological Survey has been investigating the groundwater resources of the air station since 1998. As part of that ongoing investigation, groundwater was sampled in 2008 in six wells in the Aquia aquifer and two wells in the Upper Patapsco aquifer in the vicinity of Naval Air Station Patuxent River and Webster Outlying Field. Groundwater samples were analyzed for basic chemistry (field parameters, major ions, and nutrients) as well as several water-quality issues of concern including the occurrence of arsenic and tungsten, and saltwater intrusion. The results of the 2008 groundwater-quality sampling indicate that the overall quality of groundwater in the Aquia aquifer has not changed since 1943; data are too limited to determine if groundwater quality has changed in the Upper Patapsco aquifer. At one well in the Aquia aquifer, the arsenic concentration exceeded the U.S. Environmental Protection Agency standard for drinking water. Arsenic was not detected in samples from the Upper Patapsco aquifer. Tungsten concentrations were detected at low concentrations near the laboratory reporting level in all eight samples. There was no evidence of saltwater intrusion in any of the wells.

Maryl↗