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Ank Webbers

Publications and source records attributed to Ank Webbers.

6 recordsLinked to original sources

Geologic sources and concentrations of selenium in the West-Central Denver Basin, including the Toll Gate Creek watershed, Aurora, Colorado, 2003-2007

Toll Gate Creek, in the west-central part of the Denver Basin, is a perennial stream in which concentrations of dissolved selenium have consistently exceeded the Colorado aquatic-life standard of 4.6 micrograms per liter. Recent studies of selenium in Toll Gate Creek identified the Denver lignite zone of the non-marine Cretaceous to Tertiary-aged (Paleocene) Denver Formation underlying the watershed as the geologic source of dissolved selenium to shallow ground-water and surface water. Previous work led to this study by the U.S. Geological Survey, in cooperation with the City of Aurora Utilities Department, which investigated geologic sources of selenium and selenium concentrations in the watershed. This report documents the occurrence of selenium-bearing rocks and groundwater within the Cretaceous- to Tertiary-aged Denver Formation in the west-central part of the Denver Basin, including the Toll Gate Creek watershed. The report presents background information on geochemical processes controlling selenium concentrations in the aquatic environment and possible geologic sources of selenium; the hydrogeologic setting of the watershed; selenium results from groundwater-sampling programs; and chemical analyses of solids samples as evidence that weathering of the Denver Formation is a geologic source of selenium to groundwater and surface water in the west-central part of the Denver Basin, including Toll Gate Creek. Analyses of water samples collected from 61 water-table wells in 2003 and from 19 water-table wells in 2007 indicate dissolved selenium concentrations in groundwater in the west-central Denver Basin frequently exceeded the Colorado aquatic-life standard and in some locations exceeded the primary drinking-water standard of 50 micrograms per liter. The greatest selenium concentrations were associated with oxidized groundwater samples from wells completed in bedrock materials. Selenium analysis of geologic core samples indicates that total selenium concentrations were greatest in samples containing indications of reducing conditions and organic matter (dark gray to black claystones and lignite horizons). The Toll Gate Creek watershed is situated in a unique hydrogeologic setting in the west-central part of the Denver Basin such that weathering of Cretaceous- to Tertiary-aged, non-marine, selenium-bearing rocks releases selenium to groundwater and surface water under present-day semi-arid environmental conditions. The Denver Formation contains several known and suspected geologic sources of selenium including: (1) lignite deposits; (2) tonstein partings; (3) organic-rich bentonite claystones; (4) salts formed as secondary weathering products; and possibly (5) the Cretaceous-Tertiary boundary. Organically complexed selenium and/or selenium-bearing pyrite in the enclosing claystones are likely the primary mineral sources of selenium in the Denver Formation, and correlations between concentration of dissolved selenium and dissolved organic carbon in groundwater indicate weathering and dissolution of organically complexed selenium from organic-rich claystone is a primary process mobilizing selenium. Secondary salts accumulated along fractures and bedding planes in the weathered zone are another potential geologic source of selenium, although their composition was not specifically addressed by the solids analyses. Results from this and previous work indicate that shallow groundwater and streams similarly positioned over Denver Formation claystone units at other locations in the Denver Basin also may contain concentrations of dissolved selenium greater than the Colorado aquatic-life standard or the drinking- water standard.

Colorado↗

Digital data and derivative products from a high-resolution aeromagnetic survey of the central San Luis basin, covering parts of Alamosa, Conejos, Costilla, and Rio Grande counties, Colorado, and Taos county, New Mexico

This report describes data collected from a high-resolution aeromagnetic survey flown over the central San Luis basin during October, 2004, by PRJ, Inc., on contract to the U.S. Geological Survey (USGS). The survey extends from just north of Alamosa, Colorado, southward to just northwest of Taos, New Mexico. It covers large parts of the San Luis Valley in Alamosa, Conejos, Costilla, and Rio Grande Counties, southern Colorado, and the Taos Plateau in Taos County, northern New Mexico. The survey was designed to complement two surveys previously acquired along the eastern borders of the San Luis Basin over the vicinities of Taos, New Mexico (Bankey and others, 2004a) and Blanca, Colorado (Bankey and others, 2004b). Our overall objective in conducting these surveys is to improve knowledge of the subsurface geologic framework in order to understand ground-water systems in populated alluvial basins along the Rio Grande. These USGS efforts are conducted in collaboration with other federal, state, and local governmental entities where possible.

Open-File Report↗

Public Water-Supply Systems and Associated Water Use in Tennessee, 2000

Public water-supply systems in Tennessee provide water to meet customer needs for domestic, industrial, and commercial users and municipal services. In 2000, more than 500 public water-supply systems distributed about 890 million gallons per day (Mgal/d) of surface water and ground water to a population of about 5 million in Tennessee. Surface-water sources provided 64 percent (about 569 Mgal/d) of the State?s water supplies, primarily in Middle and East Tennessee. Ground water produced from wells and springs in Middle and East Tennessee and from wells in West Tennessee provided 36 percent (about 321 Mgal/d) of the public water supplies. Springs in Middle and East Tennessee provided about 14 percent (about 42 Mgal/d) of ground-water supplies used in the State. Per capita water use for Tennessee in 2000 was about 136 gallons per day. An additional 146 public water-supply systems provided approximately 84 Mgal/d of water supplies that were purchased from other water systems. Water withdrawals by public water-supply systems in Tennessee have increased by over 250 percent; from 250 Mgal/d in 1955 to 890 Mgal/d in 2000. Although Tennessee public water-supply systems withdraw less ground water than surface water, ground-water withdrawal rates reported by these systems continue to increase. In addition, the number of public water-supply systems reporting ground-water withdrawals of 1 Mgal/d or more in West Tennessee is increasing.

Water-Resources Investigations Report↗

Preliminary conceptual models of the occurrence, fate, and transport of chlorinated solvents in karst regions of Tennessee

Published and unpublished reports and data from 22 contaminated sites in Tennessee were reviewed to develop preliminary conceptual models of the behavior of chlorinated solvents in karst aquifers. Chlorinated solvents are widely used in many industrial operations. High density and volatility, low viscosity, and solubilities that are low in absolute terms but high relative to drinkingwater standards make chlorinated solvents mobile and persistent contaminants that are difficult to find or remove when released into the groundwater system. The major obstacle to the downward migration of chlorinated solvents in the subsurface is the capillary pressure of small openings. In karst aquifers, chemical dissolution has enlarged joints, bedding planes, and other openings that transmit water. Because the resulting karst conduits are commonly too large to develop significant capillary pressures, chlorinated solvents can migrate to considerable depth in karst aquifers as dense nonaqueous-phase liquids (DNAPL's). Once chlorinated DNAPL accumulates in a karst aquifer, it becomes a source for dissolved-phase contamination of ground water. A relatively small amount of chlorinated DNAPL has the potential to contaminate ground water over a significant area for decades or longer. Conceptual models are needed to assist regulators and site managers in characterizing chlorinated-solvent contamination in karst settings and in evaluating clean-up alternatives. Five preliminary conceptual models were developed, emphasizing accumulation sites for chlorinated DNAPL in karst aquifers. The models were developed for the karst regions of Tennessee, but are intended to be transferable to similar karst settings elsewhere. The five models of DNAPL accumulation in karst settings are (1) trapping in regolith, (2) pooling at the top of bedrock, (3) pooling in bedrock diffuse-flow zones, (4) pooling in karst conduits, and (5) pooling in isolation from active ground-water flow. More than one conceptual model of DNAPL accumulation may be applicable to a given site, depending on details of the contaminant release and geologic setting. Trapping in regolith is most likely to occur where the regolith is thick and relatively impermeable with few large cracks, fissures, or macropores. Accumulation at the top of rock is favored by flat-lying strata with few fractures or karst features near the bedrock surface. Fractures or karst features near the bedrock surface encourage migration of chlorinated DNAPL into karst conduits or diffuse-flow zones in bedrock. DNAPL can migrate through one bedrock flow regime into an underlying flow regime with different characteristics or into openings that are isolated from significant ground-water flow. As a general rule, the difficulty of finding and removing DNAPL increases with depth, lateral distance from the source, and complexity of the ground-water flow system. The prospects for mitigation are generally best for DNAPL accumulation in the regolith or at the bedrock surface. However, many such accumulations are likely to be difficult to find or remove. Accumulations in bedrock diffuse-flow zones or in fractures isolated from flow may be possible to find and partially mitigate, but will likely leave significant amounts of contaminant in small fractures or as solute diffused into primary pores.

Tennessee↗

Ground-water quality protection: Why it's important to you

Ground water is a valuable resource often used for industry, commerce, agriculture, and drinking water. In the 19080's, ground water provided 35 percent of the municipal water supplies in the United States and 95 percent of the rural, domestic drinking water. Scientists participating in ground-water studies may determine the potential pathways that contaminants could be transported in aquifers. In karst terrain especially, a contanimant can enter a fracture network in a carbonate aquifer and quickly spread to become a widespread health problem. Although Federal and local funding for ground-water cleanups and treatment may be available, the costs can exceed many millions of dollars each year. Such costly remedial actions could be avoided or minimized by becoming aware that ground water anywhere is vulnerable to contamination, but particularly so in carbonate terrain. Practicing good "out-of-doors" house- keeping is necessary. From the standpoint of economic and environmental responsibility, it is critical that we all work together to protect the quality of ground-water resources so that future generations can continue to have clean water.

Tennessee↗