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Andreas Stracke

Publications and source records attributed to Andreas Stracke.

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Chemical geodynamics insights from a machine learning approach

The radiogenic isotope heterogeneity of oceanic basalts is often assessed using 2D isotope ratio diagrams. But because the underlying data are at least six dimensional ( 87 Sr/ 86 Sr, 143 Nd/ 144 Nd, 176 Hf/ 177 Hf, and 208,207,206 Pb/ 204 Pb), it is important to examine isotopic affinities in multi-dimensional data space. Here, we apply t-distributed stochastic neighbor embedding (t-SNE), a multi-variate statistical data analysis technique, to a recent compilation of radiogenic isotope data of mid ocean ridge (MORB) and ocean island basalts (OIB). The t-SNE results show that the apparent overlap of MORB-OIB data trends in 2-3D isotope ratios diagrams does not exist in multi-dimensional isotope data space, revealing that there is no discrete “component” that is common to most MORB-OIB mantle sources on a global scale. Rather, MORB-OIB sample stochastically distributed small-scale isotopic heterogeneities. Yet, oceanic basalts with the same isotopic affinity, as identified by t-SNE, delineate several globally distributed regional domains. In the regional geodynamic context, the isotopic affinity of MORB and OIB is caused by capturing of actively upwelling mantle by adjacent ridges, and thus melting of mantle with similar origin in on, near, and off-ridge settings. Moreover, within a given isotopic domain, subsidiary upwellings rising from a common deep mantle root often feed OIB volcanism over large surface areas. Overall, the t-SNE results define a fundamentally new basis for relating isotopic variations in oceanic basalts to mantle geodynamics, and may launch a 21st century era of “chemical geodynamics.”

Geochemistry, Geophysics, Geosystems

Effects of simple acid leaching of crushed and powdered geological materials on high-precision Pb isotope analyses

We present new results of simple acid leaching experiments on the Pb isotope composition of USGS standard reference material powders and on ocean island basalt whole rock splits and powders. Rock samples were leached with cold 6 N HCl in an ultrasonic bath, then on a hot plate, and washed with ultrapure H 2 O before sample digestion in HF‐HNO 3 and chromatographic purification of Pb. Lead isotope analyses were measured by Tl‐doped MC‐ICPMS. Intrasession and intersession analytical reproducibilities of repeated analyses of both synthetic Pb solutions and Pb from single digests of chemically processed natural samples were generally better than 100 ppm (2 SD). The comparison of leached and unleached samples shows that leaching consistently removes variable amounts of contaminants that differ in Pb isotopic composition for different starting materials. For repeated digests of a single sample, analyses of leached samples reproduce better than those of unleached ones, confirming that leaching effectively removes most of the heterogeneously distributed extraneous Pb. Nevertheless, the external reproducibility of leached samples is still up to an order of magnitude worse than that of Pb solution standards (∼100 ppm). More complex leaching methods employed by earlier studies yield Pb isotope ratios within error of those produced by our method and at similar levels of reproducibility, demonstrating that our simple leaching method is as effective as more complex leaching techniques. Therefore, any Pb isotope heterogeneity among multiple leached digests of samples in excess of the external reproducibility is attributed to inherent isotopic heterogeneity of the sample. The external precision of ∼100 ppm (2 SD) achieved for Pb isotope ratio determination by Tl‐doped MC‐ICPMS is thus sufficient for most rocks. The full advantage of the most precise Pb isotope analytical methods is only realized in cases where the natural isotopic heterogeneity among samples in a studied suite is substantially below 100 ppm.

Geochemistry, Geophysics, Geosystems