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Amy Ryan

Publications and source records attributed to Amy Ryan.

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Porosity, strength, and alteration – Towards a new volcano stability assessment tool using VNIR-SWIR reflectance spectroscopy

Volcano slope stability analysis is a critical component of volcanic hazard assessments and monitoring. However, traditional methods for assessing rock strength require physical samples of rock which may be difficult to obtain or characterize in bulk. Here, visible to shortwave infrared (350–2500 nm; VNIR–SWIR) reflected light spectroscopy on laboratory-tested rock samples from Ruapehu, Ohakuri, Whakaari, and Banks Peninsula (New Zealand), Merapi (Indonesia), Chaos Crags (USA), Styrian Basin (Austria) and La Soufrière de Guadeloupe (Eastern Caribbean) volcanoes was used to design a novel rapid chemometric-based method to estimate uniaxial compressive strength (UCS) and porosity. Our Partial Least Squares Regression models return moderate accuracies for both UCS and porosity, with R 2 of 0.43–0.49 and Mean Absolute Percentage Error (MAPE) of 0.2–0.4. When laboratory-measured porosity is included with spectral data, UCS prediction reaches an R 2 of 0.82 and MAPE of 0.11. Our models highlight that the observed changes in the UCS are coupled with subtle mineralogical changes due to hydrothermal alteration at wavelengths of 360–438, 532–597, 1405–1455, 2179–2272, 2332–2386, and 2460–2490 nm. These mineralogical changes include mineral replacement, precipitation hydrothermal alteration processes which impact the strength of volcanic rocks, such as mineral replacement, precipitation, and/or silicification. Our approach highlights that spectroscopy can provide a first order assessment of rock strength and/or porosity or be used to complement laboratory porosity-based predictive models. VNIR-SWIR spectroscopy therefore provides an accurate non-destructive way of assessing rock strength and alteration mineralogy, even from remote sensing platforms.

Earth and Planetary Science Letters

Hydrothermal alteration can result in pore pressurization and volcano instability

The collapse of a volcanic flank can be destructive and deadly. Hydrothermal alteration is common to volcanoes worldwide and is thought to promote volcano instability by decreasing rock strength. However, some laboratory studies have shown that not all alteration reduces rock strength. Our new laboratory data for altered rhyodacites from Chaos Crags (Lassen volcanic center, California, USA) show that pore- and crack-filling mineral precipitation can reduce porosity and permeability and increase strength, Young's modulus, and cohesion. A significant reduction in permeability, by as much as four orders of magnitude, will inhibit fluid circulation and create zones of high pore fluid pressure. We explored the consequences of pore fluid pressurization on volcano stability using large-scale numerical modeling. Upscaled physical and mechanical properties for hydrothermally altered rocks were used as input parameters in our modeling. Results show that a high-pore-pressure zone within a volcano increases volcano deformation and that increasing the size of this zone increases the observed deformation. Hydrothermal alteration associated with mineral precipitation, and increases to rock strength, can therefore promote pore pressurization and volcano deformation, increasing the likelihood of volcano spreading, flank collapses, and phreatic/phreatomagmatic explosions. We conclude that porosity-decreasing alteration, explored here, and porosity-increasing alteration can both promote volcano instability and collapse, but by different mechanisms. Hydrothermal alteration should therefore be monitored at volcanoes worldwide and incorporated into hazard assessments.

Geology

Cyclic shear zone cataclasis and sintering during lava dome extrusion: Insights from Chaos Crags, Lassen Volcanic Center (USA)

The ascent and extrusion of crystal-rich magma is commonly facilitated by deformation partitioned within annular, conduit-parallel shear zones. The physical properties and textures of the shear zone materials, where exposed at surface, provide a record of ascent and eruption dynamics. We describe the shear zone developed in Dome C, part of Chaos Crags in the Lassen Volcanic Center (California, USA). The extruded shear zone comprises volcanic fault gouge and variably densified cataclasites. The competent cataclasites evidence deep-seated gouge production followed by gouge densification within the conduit on the timescale of lava dome ascent. Textural, geochemical and mineralogical data identify solid-state sintering as the densification mechanism. At the temperatures and pressures in the volcanic conduit, solid-state sintering causes rapid porosity and permeability loss within the gouge and concomitant material strengthening. Longer dwell times (i.e., slower ascent) allow for more sintering, producing stronger, denser and less permeable cataclasites. At Chaos Crags, we use the extent of sintering, quantified by residual porosity, to recover minimum in-conduit dwell times necessary to produce the observed cataclasites. Our analysis of the Dome C cataclasites suggests a maximum linear ascent rate of 10 m/day and a minimum ascent time of 100 days. We evaluate the consequences of shear zone lithification by solid-state sintering for the eruption of other crystal-rich, glass-poor magmas. Chaos Crags cataclasites preserve evidence of multiple cycles of fracturing, cataclasis and (re-)sintering suggesting a mechanism for transitions between effusive and explosive phases of dome-building eruptions.

California