Geology topics

Amy Gartman

Publications and source records attributed to Amy Gartman.

At least 19 recordsLinked to original sources

USGS2026

Spontaneous combustion of metal sulfide minerals and implications for seafloor massive sulfide mining

Metal sulfide minerals are abundant phases in many environments on earth, including seafloor massive sulfide (SMS) deposits, which occur at hydrothermal vents throughout the global ocean. These deep-sea settings are currently undergoing exploration for potential future mining. Here, we describe rocks from Escanaba Trough on the southern Gorda Ridge that underwent spontaneous combustion during laboratory processing. We compared the mineralogy, composition, and thermogravimetric behavior of the combusting samples to rocks from the same location that did not combust. We then used thermodynamic analyses to evaluate the exothermic nature of different metal sulfide oxidation reactions. The combusting rocks are primarily composed of nanocrystalline marcasite pseudomorphing blades of primary pyrrhotite. These altered, nanocrystalline rocks are less stable than their primary predecessors. Typically, recrystallization decreases reactivity as minerals trend towards steady state; however, both of the combusting samples we characterized are secondary, and demonstrate the instability of this metastable intermediate phase. Further, thermodynamic calculations indicate that metal sulfide oxidation is more exothermic when oxygen serves as the oxidant, as occurs in seawater or air. The distinct mineralogy, texture, and setting of SMS deposits in the modern oceans thus suggests a greater potential for self-heating in comparison to their ancient analogues.

Scientific Reports↗

USGS2026

Hydrothermal manganese-oxide mineralization of a carbonate ooze, Samoan hotspot region, South Pacific Ocean

Low-temperature hydrothermal manganese oxides occur throughout the global oceans. However, the hydrothermal replacement of a carbonate ooze by manganese oxides is described here for the first time. The 24 samples dredged from three locations around the Territory of American Samoa in the South Pacific Ocean include six samples with remnant carbonate and volcaniclastic sediments, which we refer to as “low Mn,” and 18 samples in which the mineralization is pervasive and has replaced most original sediment, termed “high Mn.” The 18 high-Mn samples exhibit a mean Mn content of 51 wt.%. Higher Li and Mn contents and lower Fe contents in the high-Mn samples indicate a hydrothermal origin and distinguish these samples from hydrogenetic ferromanganese crusts. Mn-oxide layers are up to 90 mm thick, some with columns to 44 mm long and 10 mm wide, the magnitude of which has not been described previously. Samples are composed of birnessite and 10 Å phyllomanganate minerals. Textures of the thickest Mn layers indicate mineralization below the seabed from ascending fluids during multiple hydrothermal pulses. Mineralization took place by complete to partial replacement and cementation of foraminiferal sediments intermixed with volcaniclastic sediments in varying amounts. Our results highlight the production of carbonate sediment-hosted hydrothermal Mn oxides from multiple hydrothermal sources within the Samoan volcanic chain. The potential extensive distribution on the regional scale of this newly described mineralization process and unique element enrichments raise questions about its broader distribution globally and potential importance to hydrothermal processes, element mass balance, and seabed mineral resources.

Geochemistry, Geophysics, Geosystems↗

USGS2026

Cruise summary—Samoa Basin abyssal mapping—Box coring leg, Pago Pago, Territory of American Samoa to Pago Pago, American Samoa, April 11– May 1, 2026

Expedition Summary U.S. Geological Survey scientists led a box coring effort to the Samoa Basin to characterize minerals and the surrounding abyssal sediments and fauna. Thirty-eight box cores were deployed between April 13, 2026, and April 28, 2026. Thirty-six box cores recovered sufficient material to determine nodule density, and 35 recovered sufficient material for subcores to be collected. The purpose of this Data Report is to provide a summary of samples collected, initial results that were obtained shipboard, and briefly mention planned future analyses from this expedition.

Data Report↗

USGS2026

Tectonic controls on volcanism and associated hydrothermal activity in a sediment-dominated mid-ocean ridge; Escanaba Trough

Mid-ocean ridges, the Earth's most extensive volcanic system, exhibit unique characteristics in sediment-dominant environments. Thick sediment cover insulates the crust and channels fluid along pathways that can lead to the formation of distinct crustal alteration patterns, exceptionally large mineral deposits, and specialized chemosynthetic ecosystems. This study presents an interdisciplinary investigation into the tectonics of the Escanaba Trough, a heavily sedimented axial valley at the southern Gorda Ridge in the Northeast Pacific Ocean. A primary challenge in such environments is overcoming the masking effect of thick sediments on basement structures that control magmatic and hydrothermal activity. We address this by employing three-dimensional (3D) magnetic modeling of high-resolution near-seafloor magnetic data collected by an autonomous underwater vehicle (AUV). The 2022 surveys with AUV Sentry provided data for 3D magnetic susceptibility models, refining our understanding of the geometry of sub-sediment laccoliths/saucer-shaped sills and hydrothermal alteration. In conjunction with a new 1:100,000 scale lithostratigraphic map, we outline the tectonic controls on the emplacement of Escanaba Trough's three main volcanic centers, characterize the geometry of its spreading segments, and provide volumetric data on the distribution of sub-sediment volcanism in the southern Gorda Ridge.

Escanaba Trough, Pacific Ocean↗

USGS2026

Samoa basin abyssal mapping: Box coring leg

This cruise report describes work from leg three of the NOAA American Samoa Abyssal Mapping effort, OPR-T900-KR-26. Leg one preceded this effort and collected ship-based acoustic data. Leg two collected autonomous underwater vehicle (AUV) data and began before, continued contemporaneously, and finished subsequently to leg three. The USGS field activity number assigned to this expedition is 2026-604-FA. The objective of this expedition was to collect representative box cores to inform prospectivity analyses through the region, and co-located interdisciplinary datasets as practical. USGS personnel directed the sampling locations and took custody of the box cores once recovered shipboard. USGS personnel then photographed and described the cores, subsampled, conducted analyses including wet weights and time sensitive measurements, and preserved subsamples and additional components for future work. Data releases co-released with this report are listed in the section “paired data releases.” NOAA released data from all legs of this effort in near-real time. Details of the preceding legs, the data, and NOAA’s project summary available from NOAA, (2026). This report is an expedition summary with preliminary datasets; remaining data releases and publications will be forthcoming.

EarthArXiv↗

USGS2025

Kiloyear cycles of carbonate and Mg-silicate replacement at Von Damm hydrothermal vent field

The Von Damm vent field (VDVF) on the Mid-Cayman Rise in the Caribbean Sea is unique among modern hydrothermal systems in that the chimneys and mounds are almost entirely composed of talc. We analyzed samples collected in 2020 and report that in addition to disordered talc of variable crystallinity, carbonates are a major class of mineral at VDVF. The carbonate minerals include aragonite, calcite, magnesium-rich calcite, and dolomite. Talc and carbonate mineral textures indicate that, rather than replacing volcanic host rock, they precipitate from the mixing of hydrothermal fluids and seawater at the seafloor, occurring in chimneys and surrounding rubble. Alternating precipitation of this mineral assemblage is pervasive, with carbonate minerals typically being succeeded by talc, and with indications that in some cases talc and carbonate minerals replace one another. Stable carbon isotopic data indicate the carbonate minerals originate from the mixing of seawater and hydrothermal fluid, which is supported by U-Th data. Radiocarbon calcite ages and talc 234 U- 230 Th isochron ages indicate mineral ages spanning over thousands to tens of thousands of years. Analyses of these samples illustrate a dynamic system that transitions from carbonate-dominated to Mg-silicate−dominated precipitation over time scales of thousands of years. Our observations raise questions regarding the eventual fate of seafloor precipitates and whether carbonate and silicate minerals in such settings are sequestered and represented in the rock record.

Geology↗

USGS2025

Characterizing sedimentary organic carbon in a hydrothermal spreading center, the Escanaba Trough

Sediments in critical marine mineral environments are of wide importance due to their preservation of both marine minerals and organic carbon (OC) stocks. However, OC storage and cycling is often overlooked in mineral system studies. This work characterizes sedimentary OC within the Escanaba Trough, a hydrothermal sulfide system off the coast of northern California. By utilizing ROV-based push coring, we collected sediments near and far from high temperature, low temperature, and inactive vents. We applied a multipronged organic geochemical approach, measuring bulk sediment, OC fractions of varying labilities, and biomarkers to tease apart the storage, source, and cycling of OC within this complex system. In contrast to past work indicating a primarily terrestrial source to deeper, Pleistocene sediments, our results suggest a primarily marine source in surface sediments at least 50 m away from active venting. Near active venting, we see evidence of locally produced chemosynthetic OC in addition to the background marine source. This chemosynthetic OC appears to be rapidly remineralized and supports more complex deep-sea food webs compared to hemipelagic sites. Still, the greatest contribution of labile OC was observed at inactive vent sites, which we suggest is due to hydrothermal fluid alteration of more labile OC at actively venting sites. Depending on fluid temperature, hydrothermally altered OC is either preserved in the sediments as petroleum or migrated with fluid flow. Considering inactive sites are those most likely to be targeted by potential mining, we suggest additional studies could verify if these results apply at other sedimented seafloor massive sulfide systems.

California↗

USGS2025

Mineralization processes at Escanaba Trough

Escanaba Trough off northern California is the southernmost and only sediment covered segment of the Gorda Ridge. Hydrothermal mineralization was first discovered in Escanaba Trough in 1985, and subsequent investigations included the delineation of the NESCA (northern Escanaba) and SESCA (southern Escanaba) sections of Escanaba Trough, as well as drilling by Ocean Drilling Program (ODP) Leg 169 in 1996. Preliminary research conducted in the 1980s distinguished two classes of sulfide mineral assemblages within the Escanaba Trough: one dominated by pyrrhotite (Fe 1-x S) and one containing ‘mixed sulfides’ including chalcopyrite (CuFeS 2 ) and sphalerite (ZnS). In 2022, we conducted a research expedition to the Escanaba Trough to more thoroughly characterize mineralization processes and consider preservation of precipitated minerals throughout hydrothermally active and inactive sections of Escanaba Trough, with the specific objective of characterizing the host minerals, and processes of enrichment for specific elements which are currently listed as critical elements and can also be toxic under certain conditions (Sb, As, Ba, Co, Ga, Ge, Te). The following will include initial results from that work.

California↗

USGS2025

The influence of nodule versus crust morphology on the composition of seamount-hosted ferromanganese minerals

Ferromanganese mineral precipitation in the global oceans is ubiquitous, occurring in the form of both crusts and nodules at a broad range of depths and seafloor terrains. Although ferromanganese crusts and nodules are both composed of ferromanganese minerals, mineralogy and mean element concentrations compiled for regional crust versus nodule occurrences differ. Notably, most published compilations compare nodules from abyssal plain sediments to crusts forming on seamounts, and do not address the question as to whether mineral morphology may affect the composition of crusts and nodules in addition to environmental factors. To address this, we have compiled a dataset of co-located hydrogenetic (seawater sourced) open-ocean ferromanganese crusts and seamount-hosted nodules. The preliminary data presented here support our hypothesis that co-located crusts and nodules exhibit similar compositions, both in terms of their mineralogy and mean element concentrations, as well as overall variance in concentrations for any given element. These data indicate that local processes influence sample-to-sample variation in both crusts and nodules, in contrast to broader ferromanganese variation reported between open-ocean seamounts- hosted crusts and abyssal plain-hosted nodules.

Conference Paper↗

USGS2024

Neogene hydrothermal Fe- and Mn-oxide mineralization of Paleozoic continental rocks, Amerasia Basin, Arctic Ocean

Rocks dredged from water depths of 1,605, 2,500, 3,300, and 3,400 m in the Arctic Ocean included Paleozoic continental rocks pervasively mineralized during the Neogene by hydrothermal Fe and Mn oxides. Samples were recovered in three dredge hauls from the Chukchi Borderland and one from Mendeleev Ridge north of Alaska and eastern Siberia, respectively. Many of the rocks were so pervasively altered that the protolith could not be identified, while others had volcanic, plutonic, and metamorphic protoliths. The mineralized rocks were cemented and partly to wholly replaced by the hydrothermal oxides. The Amerasia Basin, where the Chukchi Borderland and Mendeleev Ridge occur, supports a series of faults and fractures that serve as major zones of crustal weakness. We propose that the stratabound hydrothermal deposits formed through the flux of hydrothermal fluids along Paleozoic and Mesozoic faults related to block faulting along a rifted margin during minor episodes of Neogene tectonism and were later exposed at the seafloor through slumping or other gravity processes. Tectonically driven hydrothermal circulation most likely facilitated the pervasive mineralization along fault surfaces via frictional heating, hydrofracturing brecciation, and low- to moderate temperature Fe- and Mn-rich hydrothermal fluids, which mineralized the crushed, altered, and brecciated rocks.

Geochemistry, Geophysics, Geosystems↗

USGS2024

Metal release from manganese nodules in anoxic seawater and implications for deep-sea mining dewatering operations

The potential mining of deep-sea polymetallic nodules has been gaining increasing attention due to their enrichment in metals essential for a low-carbon future. To date, there have been few scientific studies concerning the geochemical consequences of dewatered mining waste discharge into the pelagic water column, which can inform best practices in future mining operations. Here, we report the results of laboratory incubation experiments that simulate mining discharge into anoxic waters such as those that overlie potential mining sites in the North Pacific Ocean. We find that manganese nodules are reductively dissolved, with an apparent activation energy of 42.8 kJ mol –1 , leading to the release of associated metals in the order manganese > nickel > copper > cobalt > cadmium > lead. The composition of trace metals released during the incubation allows us to estimate a likely trace metal budget from the simulated dewatering waste plume. These estimates suggest that released cobalt and copper are the most enriched trace metals within the plume, up to ∼15 times more elevated than the background seawater. High copper concentrations can be toxic to marine organisms. Future work on metal toxicity to mesopelagic communities could help us better understand the ecological effects of these fluxes of trace metals.

ACS ES&T Water↗

USGS2024

Iron oxyhydroxide-rich hydrothermal deposits at the high-temperature Fåvne vent field, Mohns Ridge

The recently discovered Fåvne vent field, located at 3,040 m depth on the slow-spreading Mohns mid-ocean ridge between Greenland and Norway, is a high-temperature (≥250°C) vent field that is characterized by Fe oxyhydroxide-rich and S-poor chimneys and mounds. The vent field is located on both the hanging wall and footwall of a normal fault with a ∼1.5 km throw that forms the western edge of the ∼20 km wide ridge axial valley. Data collected during exploration of the site using a remotely operated vehicle as well as mineralogical and geochemical analyses of rock samples and sediments are used to characterize the geological setting of the vent field and composition of the hydrothermal deposits. The chimney walls are highly porous and lack defined chalcopyrite lined conduits, typical of high-temperature chimneys. Overall, abundant Fe oxyhydroxide precipitation at high-temperature vents at Fåvne reflects an excess of Fe over reduced S in the fluid, leading to precipitation of Fe oxide and oxyhydroxide minerals at high to moderate temperature vents (>100°C), and as microbially mediated and abiotic precipitation of Fe oxyhydroxide minerals at low-temperature diffuse vents (<100°C). The mounds and chimneys exhibit low base metal and reduced S concentrations relative to globally averaged seafloor deposits and suggest subseafloor mixing of hydrothermal fluid with seawater, causing metal sulfide precipitation. Cobalt enrichment at Fåvne may reflect a subsurface influence of an ultramafic substrate on circulating fluids, although ultramafic rocks are absent on the seafloor and no other elements typical of ultramafic deposits are present.

Geochemistry, Geophysics, Geosystems↗

USGS2024

Hydrothermal plume fallout, mass wasting, and volcanic eruptions contribute to sediments at Loki’s Castle vent field, Mohns Ridge

Sediments surrounding hydrothermal vents are important transition spaces between hydrothermal and pelagic environments. These sediments accumulate through diverse processes that include water column plume fallout, volcanic ash deposition, and mass wasting of hydrothermal chimneys and mounds superimposed upon background sedimentation which may originate from pelagic, terrestrial, and volcanic sources. In addition to being a sink for elements discharged from hydrothermal vents, elements may also be scavenged from seawater onto oxidized hydrothermal material. Preservation of these hydrothermal sediments may occur depending on the extent of oxidative and/or reductive dissolution processes after burial. Sediments remaining adjacent to active venting may also be hydrothermally altered after emplacement. To better understand these processes, here we evaluate sediment push cores collected from the Loki's Castle vent field at the intersection of the slow-ultraslow spreading Mohns and Knipovich mid-ocean ridges. All samples were collected within ∼225 m of current high-temperature (299–316°C) “black smoker” fluid discharge. These sediment cores are highly heterogeneous and lack stratigraphic correlation, even for samples taken within meters of each other. Most sediment cores are dominated by either pelagic sediments or mass wasted hydrothermal material, with hydrothermal plume fallout contributing a low proportion of material, and only a single volcanic ash layer occurring in one of the 13 cores. Dominant hydrothermal minerals found include talc, goethite, pyrite, pyrrhotite, and sphalerite. We find that even after several thousand years, most mass wasted hydrothermal material remains minimally altered, with sedimentation rates indistinguishable from background rates within several hundred meters of the hydrothermal vent source.

Geochemistry, Geophysics, Geosystems↗

USGS2022

Marine minerals in Alaska — A review of coastal and deep-ocean regions

Minerals occurring in marine environments span the globe and encompass a broad range of mineral categories, forming within varied geologic and oceanographic settings. They occur in coastal regions, either from the continuation or mechanical reworking of terrestrial mineralization, as well as in the deep ocean, from diagenetic, hydrogenetic, and hydrothermal processes. The oceans cover most of the Earth’s surface and as a result, any inventory of global resources is incomplete without the inclusion of marine minerals. This study by the U.S. Geological Survey reviews current knowledge regarding deep-ocean and coastal marine minerals within the marine areas surrounding Alaska, including the Alaska Outer Continental Shelf (OCS). For the purposes of this study, we have divided these areas in to eight regions: (1) Gulf of Alaska seamounts, (2) Chukchi Borderland, (3) Canada Basin, (4) Aleutian Arc, (5) Seward Peninsula, (6) Goodnews Bay, (7) Bristol Bay and Alaska Peninsula, and (8) southern and southeastern Alaska. The Alaska OCS encompasses several areas broadly conducive to marine mineral formation, including extensional basins resulting from an active subduction zone where massive sulfide deposits may form, deep abyssal plains with conditions that may lead to manganese nodule formation, seamounts that can provide substrate for the growth of ferromanganese crusts, and erosional settings and submerged continental crust where placer deposits are found. For deep-ocean hydrothermal minerals and manganese nodules, the Alaska OCS contains prospective regions, including the Canada Basin and the Aleutian Arc; however, no such minerals have yet been identified. We explore the probability that these minerals occur based on reviews of existing geologic and oceanographic data within the relevant sections. In regions far from shore data are limited. Deep-ocean ferromanganese crusts are known to occur in two regions: (1) the Gulf of Alaska seamounts and (2) the Chukchi Borderland in the Arctic Ocean. Limited sampling has occurred in both regions, and along the Chukchi Borderland the sampling was outside of the OCS and the U.S. Exclusive Economic Zone. Data relevant to coastal minerals is more extensive, and in some places fairly systematic sampling was conducted. Several nearshore placer deposits have been exploited for decades; however, the potential for nearshore extension of terrestrial ore deposits is less well considered. This contribution considers the state of knowledge regarding marine mineral occurrences within the Alaska regions and identifies the data gaps in order to help inform future marine mineral related research efforts around Alaska.

Alaska↗

USGS2022

Estimates of metals contained in abyssal manganese nodules and ferromanganese crusts in the global ocean based on regional variations and genetic types of nodules

Deep-ocean ferromanganese crusts and manganese nodules are important marine repositories for global metals. Interest in these minerals as potential resources has led to detailed sampling in many regions of the global ocean, allowing for updated estimates of their global extent. Here, we present global estimates of total tonnage as well as contained metal concentrations and tonnages for ferromanganese crusts and manganese nodules using the most extensive compilation of geochemical data collected to date, along with updated boundaries of regions of interest for these minerals. We present results from mean composition calculated in two ways: first, a global flat average of regional mean compositions, and second, a regionally weighted average that considers differences in chemistry among genetic types and/or oceanographic and geologic settings for these mineral occurrences. For nodules, we use the three genetic types: (1) hydrogenetic, typified by nodules from the West Pacific Nodule Field and Penrhyn Basin; (2) diagenetic, typified by nodules from the Peru Basin; (3) mixed hydrogenetic-diagenetic, typified by nodules from the Clarion–Clipperton Zone and the Central Indian Ocean Basin, and Atlantic Ocean regional type hydrogenetic nodules. All crusts considered here are of hydrogenetic origin, which we divide into seven regional types that reflect a combination of ocean basin and other source inputs. Crust types include Arctic Ocean, Atlantic Ocean, Indian Ocean, Continental Margin, Prime Crust Zone (PCZ), North Pacific (non PCZ), and South Pacific. Based on our areal estimates, we find that abyssal regions likely to contain hydrogenetic-type nodules are by far the most widespread in the global ocean (47% of total area), Atlantic Ocean (28%) are next, followed by mixed diagenetic-hydrogenetic (22%) and diagenetic (3%) types. For crusts, the Prime Crust Zone is the most extensive global region (27% of total area) followed by South Pacific (20%), Indian Ocean (18%), North Pacific (12%), Continental Margins (11%), Atlantic Ocean (10%), and Arctic Ocean (2%) types. The global total tonnage estimates that we calculated from this method are 21 × 10 10 dry tons for manganese nodules, within the range of previous estimates, and 93 × 10 10 dry tons for ferromanganese crusts, which is 4.5 times higher than the 20 × 10 10 dry tons reported by Hein et al. (2003). This geology and oceanography driven approach to marine mineral quantification contrasts with estimates typically carried out for terrestrial mineral resource deposits. Nevertheless, these estimates and the data that support them demonstrate that marine minerals are an impressive repository for global metals.

Book chapter↗

USGS2021

Extent of impact of deep-sea nodule mining midwater plumes is influenced by sediment loading, turbulence and thresholds

Deep-sea polymetallic nodule mining research activity has substantially increased in recent years, but the expected level of environmental impact is still being established. One environmental concern is the discharge of a sediment plume into the midwater column. We performed a dedicated field study using sediment from the Clarion Clipperton Fracture Zone. The plume was monitored and tracked using both established and novel instrumentation, including acoustic and turbulence measurements. Our field studies reveal that modeling can reliably predict the properties of a midwater plume in the vicinity of the discharge and that sediment aggregation effects are not significant. The plume model is used to drive a numerical simulation of a commercial-scale operation in the Clarion Clipperton Fracture Zone. Key takeaways are that the scale of impact of the plume is notably influenced by the values of environmentally acceptable threshold levels, the quantity of discharged sediment, and the turbulent diffusivity in the Clarion Clipperton Fracture Zone.

Communications Earth & Environment↗

USGS2021

Carbonate-hosted microbial communities are prolific and pervasive methane oxidizers at geologically diverse marine methane seep sites

At marine methane seeps, vast quantities of methane move through the shallow subseafloor, where it is largely consumed by microbial communities. This process plays an important role in global methane dynamics, but we have yet to identify all of the methane sinks in the deep sea. Here, we conducted a continental-scale survey of seven geologically diverse seafloor seeps and found that carbonate rocks from all sites host methane-oxidizing microbial communities with substantial methanotrophic potential. In laboratory-based mesocosm incubations, chimney-like carbonates from the newly described Point Dume seep off the coast of Southern California exhibited the highest rates of anaerobic methane oxidation measured to date. After a thorough analysis of physicochemical, electrical, and biological factors, we attribute this substantial metabolic activity largely to higher cell density, mineral composition, kinetic parameters including an elevated V max , and the presence of specific microbial lineages. Our data also suggest that other features, such as electrical conductance, rock particle size, and microbial community alpha diversity, may influence a sample’s methanotrophic potential, but these factors did not demonstrate clear patterns with respect to methane oxidation rates. Based on the apparent pervasiveness within seep carbonates of microbial communities capable of performing anaerobic oxidation of methane, as well as the frequent occurrence of carbonates at seeps, we suggest that rock-hosted methanotrophy may be an important contributor to marine methane consumption.

Proceedings of the National Academy of Sciences (P↗

USGS2020

Sphalerite oxidation in seawater with covellite: Implications for seafloor massive sulfide deposits and mine waste

Metal sulfide minerals exist in several marine environments and are in thermodynamic disequilibrium with oxygenated seawater from the time of their formation. Oxidation is both ubiquitous and heterogeneous, as observational and experimental evidence demonstrates that sulfide minerals may oxidize completely on decadal timescales (hydrothermal plumes) or incompletely in billions of years (mineral deposits); however, the processes, rates, and interactions among minerals as oxidative dissolution occurs are not well understood. Added impetus to understanding these processes exists due to the potential for mining of seafloor massive sulfide deposits and potential environmental impacts of that activity. Here, we present a laboratory-based experimental study on the galvanic oxidation of sphalerite and synthesized zinc sulfide and coupled to covellite. We find that, in contrast to single-mineral reactions, coupled mineral reactions are at least 2 orders of magnitude more rapid, light independent, and have a lower apparent activation energy for oxidation. These results begin to provide insight into observed differences between laboratory and environmentally observed oxidation rates and are a step in the direction of more accurately predicting environmental rates as well as any changes to those rates from anthropogenic disturbances.

ACS Earth and Space Chemistry↗