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Allen L. Zack

Publications and source records attributed to Allen L. Zack.

5 recordsLinked to original sources
USGS1988

The geochemical evolution of aqueous sodium in the Black Creek Aquifer, Horry and Georgetown counties, South Carolina

The Black Creek aquifer contains dilute seawater near the North Carolina State line, probably the result of incomplete flushing of ancient seawater. Data do not indicate that the dilute seawater has migrated toward areas of fresh ground-water withdrawals. The concentration of chloride in ground-water samples ranges from 5 to 720 milligrams per liter and that of sodium from 160 to 690 milligrams per liter. Ion-exchange reactions (sodium for calcium and fluoride for hydroxyl) occur with the calcium carbonate dissolution reaction which produces calcium, bicarbonate, and hydroxyl ions. The reaction sequence and stoichiometry result in an aqueous solution in which the sum of bicarbonate and chloride equivalents per liter is equal to the equivalents per liter of sodium. Calcium ions are exchanged for sodium ions derived from sodium-rich clays upgradient of the dilute seawater. The cation-exchange reaction equilibrates at a sodium concentration of 280 milligrams per liter. Amounts of sodium greater than 280 milligrams per liter are contributed from dilute seawater. The cation-exchange reaction approaches an equilibrium which represents a mass-action limit in terms of the ratio of sodium to calcium in solution versus the ratio of exchangeable sodium to calcium on clay surfaces. Where the limit of calcium carbonate solubility is approached and dissolution ceases, some precipitation of calcite probably takes place. The dissolution of calcite exposes fossil shark teeth which release fluoride ions to the ground water through anion exchange with aqueous hydroxyl ions.

South Carolina↗
USGS1988

A well system to recover usable water from a freshwater-saltwater aquifer in Puerto Rico

Aquifers in coastal areas of Puerto Rico commonly contain limited quantities of freshwater that occur as a thin layer at the surface of the water table. Many wells have been abandoned because well screens were inadvertently placed in saltwater parts of the aquifer. A scavenger/production well couple that can be installed in an abandoned well, screened in both freshwater and saltwater parts of the aquifer, provides an effective method for extracting freshwater from the well. Withdrawal of a sufficient quantity of water having low chloride concentrations, by use of a well couple, depends on the upward movement of saltwater within the aquifer when the well is pumped. Upward movement of saltwater depends on the relative concentrations of chloride in the borehole and on the distribution of horizontal and vertical hydraulic conductivity of the aquifer. For any well screened in an aquifer that contains both freshwater and saltwater, a family of curves can be constructed to represent all combinations of pumping rates and corresponding chloride loads when the scavenger well and the production well are being pumped simultaneously. The curves permit estimates of optimal withdrawals of freshwater based on the desired pumping rates and the levels of chloride concentration required for each well.

Water Supply Paper↗
USGS1984

Restoration of freshwater in the Cano Tiburones area, Puerto Rico

Cano Tiburones on the north coast of Puerto Rico originally was a shallow, coastal lagoon, 9 square miles in area. It accumulated freshwater from adjacent rivers and springs and drained to the ocean through unobserved subterranean conduits. Forced drainage by pumping of Cano Tiburones for agriculture was begun in 1949, and resulted in lowering the water level to below sea level. The reversed hydraulic gradient permitted seawater to enter the Cano through the conduits forming seawater "springs". Seawater flooding caused widespread sodium chloride contamination in the canals and laterals and in the soils. Agricultural expectations of the area were not realized. The present investigation into the freshening potential of Cano Tiburones (1979-1982) determined that ground-water discharge does not contribute to salty conditions. On-site experiments were performed to segregate freshwater from seawater using differences in hydraulic head. Dams were constructed on canals and laterals, forcing accumulated saltwater to the ocean. Ring levees were placed around the discharging seawater conduits until sea level was reached and flow to the system stopped. These efforts have succeeded in reducing the amount of seawater in Cano Tiburones to one-third of its original concentration. Most of the water presently in Cano Tiburones is suitable for irrigation.

Cano Tiburones↗
USGS1980

Geochemistry of fluoride in the Black Creek aquifer system of Horry and Georgetown Counties, South Carolina — And its physiological implications

High concentrations of fluoride in ground-water supplies in certain areas of Horry and Georgetown Counties, S.C., have been the cause of dental fluorosis (tooth mottling) among persons who have lived in these areas and have ingested the water as children. Geochemical evidence and laboratory experiments demonstrate that fluorapatite in the form of fossil shark teeth is the source of fluoride, and that the fluoride ions are liberated to the ground-water system through anion exchange, rather than by dissolution. Calcite-cemented quartz sand in the upper third of the Black Creek Formation of Late Cretaceous age contains the fossil shark teeth. As ground water progresses downdip, the calcite matrix dissolves and hydrolyzes, releasing bicarbonate, hydroxyl, and calcium ions. The calcium ions are immediately exchanged for sodium ions adsorbed on sodium-rich clays, and the bicarbonate ions accumulate. As the shark teeth are exposed, the hydroxyl ions in solution exchange with fluoride ions on fluorapatite surfaces. Experiments using fossil shark teeth show that sodium chloride in solution inhibits the rate of exchange of fluoride ions from tooth surfaces for hydroxyl ions in solution. The amount of fluoride removed from water and exchanged for hydroxyl ions in the presence of pure hydroxylapatite (hog teeth) was greater in saline water than in freshwater.

South Carolina↗