Geology topics

Aaron L. Mills

Publications and source records attributed to Aaron L. Mills.

5 recordsLinked to original sources

USGS2023

Examining the complex relations between climate and streamflow in the mid-atlantic region of the United States

We explored the complex relations between climate and streamflow in the Mid-Atlantic region of the United States. In 124 watersheds across this region, we quantified spatial and temporal variation in air temperature (AT), precipitation (P), and streamflow (Q) from 1981 through 2020. Upward directional trends in monthly values of AT, P, and Q indicated an increase of 0.27–1.9 degrees Celsius, 0.12–1.9 millimeters day −1 , and 0.01–7.1 cubic meters s −1 day −1 , respectively, over the 40-year period. Comparison of the first 20 years to the last 20 years of data indicated an acceleration in the trend slopes in AT, P, and Q. Changes also were observed in temporal trends in the center of volume (CV) of both P and Q, which generally occurred later in the year; the 7-day mean low flow increased, and the annual day of occurrence of the 7-day mean low flow occurred earlier in the year. Principal components analysis revealed differences in P, Q, CVP, and CVQ trends in watersheds with median elevations greater than and less than 400 meters, as well as by latitude. A seasonal analysis revealed that P increased throughout the study area in spring, summer, and fall but decreased in winter. AT, P, and Q have broadly increased across the region over the 40-year period, and the temporal, spatial, and seasonal changes in P have affected Q. Results highlight the strong couplings between climatic variability and watershed responses.

Maryland, North Carolina, Virginia, West Virginia↗

USGS2017

Riverine discharges to Chesapeake Bay: Analysis of long-term (1927–2014) records and implications for future flows in the Chesapeake Bay basin

The Chesapeake Bay (CB) basin is under a total maximum daily load (TMDL) mandate to reduce nitrogen, phosphorus, and sediment loads to the bay. Identifying shifts in the hydro-climatic regime may help explain observed trends in water quality. To identify potential shifts, hydrologic data (1927–2014) for 27 watersheds in the CB basin were analyzed to determine the relationships among long-term precipitation and stream discharge trends. The amount, frequency, and intensity of precipitation increased from 1910 to 1996 in the eastern U.S., with the observed increases greater in the northeastern U.S. than the southeastern U.S. The CB watershed spans the north-to-south gradient in precipitation increases, and hydrologic differences have been observed in watersheds north relative to watersheds south of the Pennsylvania—Maryland (PA-MD) border. Time series of monthly mean precipitation data specific to each of 27 watersheds were derived from the Precipitation-elevation Regression on Independent Slopes Model (PRISM) dataset, and monthly mean stream-discharge data were obtained from U.S. Geological Survey streamgage records. All annual precipitation trend slopes in the 18 watersheds north of the PA-MD border were greater than or equal to those of the nine south of that border. The magnitude of the trend slopes for 1927–2014 in both precipitation and discharge decreased in a north-to-south pattern. Distributions of the monthly precipitation and discharge datasets were assembled into percentiles for each year for each watershed. Multivariate correlation of precipitation and discharge within percentiles among the groups of northern and southern watersheds indicated only weak associations. Regional-scale average behaviors of trends in the distribution of precipitation and discharge annual percentiles differed between the northern and southern watersheds. In general, the linkage between precipitation and discharge was weak, with the linkage weaker in the northern watersheds compared to those in the south. On the basis of simple linear regression, 26 of the 27 watersheds are projected to have higher annual mean discharge in 2025, the target date for implementation of the TMDL for the CB basin.

Chesapeake Bay Basin↗

USGS2007

Overview of issues in subsurface and landfill microbiology

To date, the majority of evidence indicates that most subsurface environments possess climax ecological communities that are well adapted to the environment in which they live. Like their counterparts on the surface, subsurface ecosystems are characterized by a high degree of microbiological diversity, they possess trophic structure, and they exhibit material cycling and energy transfer. Members of such ecosystems typically possess structural, physiological, or reproductive adaptations that allow them to disperse and survive in such habitats. Current studies argue that microbial activities influence the geochemical processes in both landfills and subsurface environments and that the altered geochemistry, in turn, influences the selection of microorganisms proliferating in the habitat. However, while microbial activity may often be limited by the availability of electron donors in uncontaminated aquifer systems, this is rarely the case with landfills. Sections in this chapter provide investigators with a greater understanding of the experimental approaches needed to study the microbiology of the terrestrial subsurface and an appreciation of interpretational limits imposed by the existing methodologies. The hope is that further study of subsurface microorganisms will provide insights into the process of microbial evolution and possibly into the origins of life itself.

Book chapter↗

USGS2000

Alteration of reactive mineral surfaces by ground water

Two different investigations of shallow sandy aquifers inform our thinking about the role of reactive iron minerals in hydrogeological systems. Ground water in a number of settings has been described as having elevated concentrations of dissolved iron in anoxic portions of contaminant plumes (e.g. Baedecker et al., 1993; Lyngkilde and Christensen, 1992), and the coupling of microbial reduction of Fe(III) to the degradation of organic compounds links the study of the biogeochemistry of iron to our desire to understand processes influencing contaminated aquifers. Questions about the transport and fate of reactive constituents in ground water are linked to the study of iron through recognition of the importance of sorption processes on sesquioxide mineral surfaces common in sedimentary aquifers limiting the migration of metals, anions, and bacteria. We have been grappling with questions related to the stability of iron mineral phases in contaminated aquifers and the role of Fe(III)- bearing minerals and grain coatings as sorption substrates

Conference Paper↗

USGS1987

Aqueous pyrite oxidation by dissolved oxygen and by ferric iron

Rates of aqueous, abiotic pyrite oxidation were measured in oxygen-saturated and anaerobic Fe(III)-saturated solutions with initial pH from 2 to 9. These studies included analyses of sulfite, thiosulfate, polythionates and sulfate and procedures for cleaning oxidation products from pyrite surfaces were evaluated. Pyrite oxidation in oxygen-saturated solutions produced (1) rates that were only slightly dependent on initial pH, (2) linear increases in sulfoxy anions and (3) thiosulfate and polythionates at pH > 3.9. Intermediate sulfoxy anions were observed only at high stirring rates. In anaerobic Fe(III)-saturated solutions, no intermediates were observed except traces of sulfite at pH 9. The faster rate of oxidation in Fe(III)-saturated solutions supports a reaction mechanism in which Fe(III) is the direct oxidant of pyrite in both aerobic and anaerobic systems. The proposal of this mechanism is also supported by theoretical considerations regarding the low probability of a direct reaction between paramagnetic molecular oxygen and diamagnetic pyrite. Results from a study of sphalerite oxidation support the hypothesis that thiosulfate is a key intermediate in sulfate production, regardless of the bonding structure of the sulfide mineral.

Geochimica et Cosmochimica Acta↗