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A.G. Hunt

Publications and source records attributed to A.G. Hunt.

8 recordsLinked to original sources
USGS2013

Chemistry and age of groundwater in bedrock aquifers of the Piceance and Yellow Creek watersheds, Rio Blanco County, Colorado, 2010-12

Fourteen monitoring wells completed in the Uinta and Green River Formations in the Piceance Creek and Yellow Creek watersheds in Rio Blanco County, Colorado, were sampled for chemical, isotopic, and groundwater-age tracers to provide information on the overall groundwater quality, the occurrence and distribution of chemicals that could be related to the development of underlying natural-gas reservoirs, and to better understand groundwater residence times in the flow system. Methane concentrations in groundwater ranged from less than 0.0005 to 387 milligrams per liter. The methane was predominantly biogenic in origin, although the biogenic methane was mixed with thermogenic methane in water from seven wells. Three BTEX compounds (benzene, toluene, and ethylbenzene) were detected in water from six of the wells, but none of the concentrations exceeded Federal drinking-water standards. The presence of thermogenic methane in the aquifers indicates a connection and vulnerability to chemicals in deeper geologic units. Helium-4 data indicate that groundwater had ages ranging from less than 1,000 years to greater than 50,000 years. The presence of old groundwater in parts of the aquifers indicates that these aquifers may not be useful for large-scale water supply because of low recharge rates.

Colorado↗
USGS2011

Use of diverse geochemical data sets to determine sources and sinks of nitrate and methane in groundwater, Garfield County, Colorado, 2009

Previous water-quality assessments reported elevated concentrations of nitrate and methane in water from domestic wells screened in shallow zones of the Wasatch Formation, Garfield County, Colorado. In 2009, the U.S. Geological Survey, in cooperation with the Colorado Department of Public Health and Environment, analyzed samples collected from 26 domestic wells for a diverse set of geochemical tracers for the purpose of determining sources and sinks of nitrate and methane in groundwater from the Wasatch Formation. Nitrate concentrations ranged from less than 0.04 to 6.74 milligrams per liter as nitrogen (mg/L as N) and were significantly lower in water samples with dissolved-oxygen concentrations less than 0.5 mg/L than in samples with dissolved-oxygen concentrations greater than or equal to 0.5 mg/L. Chloride/bromide mass ratios and tracers of groundwater age (tritium, chlorofluorocarbons, and sulfur hexafluoride) indicate that septic-system effluent or animal waste was a source of nitrate in some young groundwater (less than 50 years), although other sources such as fertilizer also may have contributed nitrate to the groundwater. Nitrate and nitrogen gas (N2) concentrations indicate that denitrification was the primary sink for nitrate in anoxic groundwater, removing 99 percent of the original nitrate content in some samples that had nitrate concentrations greater than 10 mg/L as N at the time of recharge. Methane concentrations ranged from less than 0.0005 to 32.5 mg/L and were significantly higher in water samples with dissolved-oxygen concentrations less than 0.5 mg/L than in samples with dissolved-oxygen concentrations greater than or equal to 0.5 mg/L. High methane concentrations (greater than 1 mg/L) in some samples were biogenic in origin and appeared to be derived from a relatively deep source on the basis of helium concentrations and isotopic data. One such sample had water-isotopic and major-ion compositions similar to that of produced water from the underlying Mesaverde Group, which was the primary natural-gas producing interval in the study area. Methane in the Mesaverde Group was largely thermogenic in origin so biogenic methane in the sample probably was derived from deeper zones in the Wasatch Formation. The primary methane sink in the aquifer appeared to be methane oxidation on the basis of dissolved-oxygen and methane concentrations and methane isotopic data. The diverse data sets used in this study enhance previous water-quality assessments by providing new and more complete insights into the sources and sinks of nitrate and methane in groundwater. Field measurements of dissolved oxygen in groundwater were useful indicators of the Wasatch Formation's vulnerability to nitrate and methane contamination or enrichment. Results from this study also provide new evidence for the movement of water, ions, and gases into the shallow Wasatch Formation from sources such as the Mesaverde Group and deeper Wasatch Formation.

Scientific Investigations Report↗
USGS2009

Vulnerability of a public supply well in a karstic aquifer to contamination

To assess the vulnerability of ground water to contamination in the karstic Upper Floridan aquifer (UFA), age-dating tracers and selected anthropogenic and naturally occurring compounds were analyzed in multiple water samples from a public supply well (PSW) near Tampa, Florida. Samples also were collected from 28 monitoring wells in the UFA and the overlying surficial aquifer system (SAS) and intermediate confining unit located within the contributing recharge area to the PSW. Age tracer and geochemical data from the earlier stage of the study (2003 through 2005) were combined with new data (2006) on concentrations of sulfur hexafluoride (SF 6 ), tritium ( 3 H), and helium-3, which were consistent with binary mixtures of water for the PSW dominated by young water (less than 7 years). Water samples from the SAS also indicated mostly young water (less than 7 years); however, most water samples from monitoring wells in the UFA had lower SF 6 and 3 H concentrations than the PSW and SAS, indicating mixtures containing high proportions of older water (more than 60 years). Vulnerability of the PSW to contamination was indicated by predominantly young water and elevated nitrate-N and volatile organic compound concentrations that were similar to those in the SAS. Elevated arsenic (As) concentrations (3 to 19 ??g/L) and higher As(V)/As(III) ratios in the PSW than in water from UFA monitoring wells indicate that oxic water from the SAS likely mobilizes As from pyrite in the UFA matrix. Young water found in the PSW also was present in UFA monitoring wells that tap a highly transmissive zone (43- to 53-m depth) in the UFA. ?? 2008 National Ground Water Association.

Ground Water↗
USGS2009

Diffuse gas emissions at the Ukinrek Maars, Alaska: Implications for magmatic degassing and volcanic monitoring

Diffuse CO2 efflux near the Ukinrek Maars, two small volcanic craters that formed in 1977 in a remote part of the Alaska Peninsula, was investigated using accumulation chamber measurements. High CO2 efflux, in many places exceeding 1000 g m−2 d−1, was found in conspicuous zones of plant damage or kill that cover 30,000–50,000 m2 in area. Total diffuse CO2 emission was estimated at 21–44 t d−1. Gas vents 3-km away at The Gas Rocks produce 0.5 t d−1 of CO2 that probably derives from the Ukinrek Maars basalt based on similar δ13C values (∼−6‰), 3He/4He ratios (5.9–7.2 RA), and CO2/3He ratios (1–2 × 109) in the two areas. A lower 3He/4He ratio (2.7 RA) and much higher CO2/3He ratio (9 × 1010) in gas from the nearest arc-front volcanic center (Mount Peulik/Ugashik) provide a useful comparison. The large diffuse CO2 emission at Ukinrek has important implications for magmatic degassing, subsurface gas transport, and local toxicity hazards. Gas–water–rock interactions play a major role in the location, magnitude and chemistry of the emissions.

Alaska↗
USGS2008

A landslide in Tertiary marine shale with superheated fumaroles, Coast Ranges, California

In August 2004, a National Forest fire crew extinguished a 1.2 ha fire in a wilderness area ~40 km northeast of Santa Barbara, California. Examination revealed that the fire originated on a landslide dotted with superheated fumaroles. A 4 m borehole punched near the hottest (262 °C) fumarole had a maximum temperature of 307 °C. Temperatures in this borehole have been decreasing by ~0.1 °C/d, although the cooling rate is higher when the slide is dry. Gas from the fumaroles and boreholes is mostly air with 3–8 vol% carbon dioxide and trace amounts of carbon monoxide, methane, ethane, and propane. The carbon dioxide is 14 C-dead. The ratios of methane to ethane plus propane [C 1 /(C 2 + C 3 )] range from 3.6 to 14. Carbon isotope values for the CO 2 range from −14‰ to −23‰ δ 13 C. 3 He/ 4 He values range from 0.96 to 0.97 times that of air. The anomalous heat is interpreted to be due to rapid oxidation of iron sulfide augmented by combustion of carbonaceous matter within the formation.

Geology↗
USGS2008

Isotope and Chemical Methods in Support of the U.S. Geological Survey Science Strategy, 2003-2008

Principal functions of the Mineral Resources Program are providing information to decision-makers related to mineral deposits on federal lands and predicting the environmental consequences of the mining or natural weathering of those deposits. Performing these functions requires that predictions be made of the likelihood of undiscovered deposits. The predictions are based on geologic and geoenvironmental models that are constructed for the various types of mineral deposits from detailed descriptions of actual deposits and detailed understanding of the processes that formed them. Over the past three decades the understanding of ore-forming processes has benefitted greatly from the integration of laboratory-based geochemical tools with field observations and other data sources. Under the aegis of the Evolution of Ore Deposits and Technology Transfer Project (EODTTP), a five-year effort that terminated in 2008, the Mineral Resources Program provided state-of-the-art analytical capabilities to support applications of several related geochemical tools.

Fact Sheet↗
USGS2004

The helium isotopic chemistry of Lake Bonney, Taylor Valley, Antarctica: Timing of late holocene climate change in Antarctica

To better understand the long-term climate history of Antarctica, we studied Lake Bonney in Taylor Valley, Southern Victoria Land (78?? S). Helium isotope ratios and He, Ne, Ar and N2 concentration data, obtained from hydrocasts in the East (ELB) and West (WLB) Lobesof Lake Bonney, provided important constraints on the lake's Holocene evolution. Based on very low concentrations of Ar and N2 in the ELB bottom waters, ELB was free of ice until 200 ?? 50 years ago. After which, low salinity water flowing over the sill from WLB to ELB, covered ELB and formed a perennial ice cover, inhibiting the exchange of gases with the atmosphere. In contrast to the ELB, the WLB retained an ice cover through the Holocene. The brine in the WLB bottom waters has meteoric N2 and Ar gas concentrations indicating that it has not been significantly modified by atmospheric exchange or ice formation. The helium concentrations in the deep water of WLB are the highest measured in non-thermal surface water. By fitting a diffusional loss to the 3He/4He, helium, and Cl profiles, we calculate a time of ???3000 years for the initiation of flow over the sill separating the East and West Lobes. To supply this flux of helium to the lake, a helium-rich sediment beneath the lake must be providing the helium by diffusion. If at any time during the last million years the ice cover left WLB, there would be insufficient helium available to provide the current flux to WLB. The variations in water levels in Lake Bonney can be related to climatic events that have been documented within the Southern Victoria Land region and indicate that the lakes respond significantly to regional and, perhaps, global climate forcing. ?? 2004 Kluwer Academic Publishers.

Aquatic Geochemistry↗