A. Foster | Geology Reports

USGS2004

Speciation and characterization of arsenic in gold ores and cyanidation tailings using X-ray absorption spectroscopy

The knowledge of mineralogy and molecular structure of As is needed to better understand the stability of As in wastes resulting from processing of gold ores. In this study, optical microscopy, scanning electron microscopy, electron microprobe, X-ray diffraction and X-ray absorption fine structure (XAFS) spectroscopy (including both XANES and EXAFS regimes) were employed to determine the mineralogical composition and local coordination environment of As in gold ores and process tailings from bench-scale tests designed to mimic a common plant practice. Arsenic-bearing minerals identified in the ores and tailings include iron (III) oxyhydroxides, scorodite (FeAsO4??2H2O), ferric arsenates, arseniosiderite (Ca2Fe3 (AsO4)3O2??3H2O), Ca-Fe arsenates, pharmacosiderite (KFe4 (AsO4)3(OH)4??6-7H2O), jarosite (K2Fe6(SO4)4 (OH)12) and arsenopyrite (FeAsS). Iron (III) oxyhydroxides contain variable levels of As from trace to about 22 wt% and Ca up to approximately 9 wt%. Finely ground ore and tailings samples were examined by bulk XAFS and selected mineral grains were analyzed by microfocused XAFS (micro-EXAFS) spectroscopy to reconcile the ambiguities of multiple As sources in the complex bulk EXAFS spectra. XANES spectra indicated that As occurs as As5+in all the samples. Micro-EXAFS spectra of individual iron (III) oxyhydroxide grains with varying As concentrations point to inner-sphere bidentate-binuclear arsenate complexes as the predominant form of As. There are indications for the presence of a second Fe shell corresponding to bidentate-mononuclear arrangement. Iron (III) oxyhydroxides with high As concentrations corresponding to maximum adsorption densities probably occur as nanoparticles. The discovery of Ca atoms around As in iron (III) oxyhydroxides at interatomic distances of 4.14-4.17 A?? and the coordination numbers suggest the formation of arseniosiderite-like nanoclusters by coprecipitation rather than simple adsorption of Ca onto iron (III) oxyhydroxides. Correlation of Ca with As in iron (III) oxyhydroxides as determined by electron microprobe analysis supports the coprecipitate origin for the presence of Ca in iron (III) oxyhydroxides. The samples containing higher abundances of ferric arsenates released higher As concentrations during the cyanidation tests. The presence of highly soluble ferric arsenates and Ca-Fe arsenates, and relatively unstable iron (III) oxyhydroxides with Fe/As molar ratios of less than 4 in the ore and process tailings suggests that not only the tailings in the impoundment will continue to release As, but also there is the potential for mobilization of As from the natural sources such as the unmined ore. ?? 2004 Elsevier Ltd.

Geochimica et Cosmochimica Acta↗

USGS1999

Physical, chemical, and isotopic data for samples from the Anderson Springs area, Lake County, California, 1998-1999

Anderson Springs is located about 90 miles (145 kilometers) north of San Francisco, California, in the southwestern part of Lake County. The area was first developed in the late 1800s as a health resort, which was active until the 1930s. In the rugged hills to the south of the resort were four small mercury mines of the eastern Mayacmas quicksilver district. About 1,260 flasks of mercury were produced from these mines between 1909 and 1943. In the 1970s, the high-elevation areas surrounding Anderson Springs became part of The Geysers geothermal field. Today, several electric powerplants are located on the ridges above Anderson Springs, utilizing steam produced from a 240°C vapor-dominated reservoir. The primary purpose of this report is to provide physical, chemical, and isotopic data on samples collected in the Anderson Springs area during 1998 and 1999, in response to a Freedom of Information Act request. In July 1998, drainage from the Schwartz adit of the abandoned Anderson mercury mine increased substantially over a 2-day period, transporting a slurry of water and precipitates down a tributary and into Anderson Creek. In August 1998, J.J. Rytuba and coworkers sampled the Schwartz adit drainage and water from the Anderson Springs Hot Spring for base metal and methylmercury analysis. They measured a maximum temperature (Tm) of 85°C in the Hot Spring. Published records show that the temperature of the Anderson Springs Hot Spring (main spring) was 63°C in 1889, 42–52°C from 1974 through 1991, and 77°C in March 1995. To investigate possible changes in thermal spring activity and to collect additional samples for geochemical analysis, C.J. Janik and coworkers returned to the area in September and December 1998. They determined that a cluster of springs adjacent to the main spring had Tm=98°C, and they observed that a new area of boiling vents and small fumaroles (Tm=99.3°C) had formed in an adjacent gully about 20 meters to the north of the main spring. During August–October 1999, several field trips were conducted in the vicinity of Anderson Springs to continue monitoring and sampling the thermal manifestations. The new fumarolic area had increased in temperature and in discharge intensity since 1998, and a zone of dead trees had developed on the steep bank directly west of the fumaroles. Ground temperatures and diffuse flow of CO2 flow through soils were measured in the area surrounding the main spring and new fumaroles and in the zone of tree-kill.

California↗